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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/29496完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳立仁(Li-Jen Chen) | |
| dc.contributor.author | Cheng-Hao Su | en |
| dc.contributor.author | 蘇晟豪 | zh_TW |
| dc.date.accessioned | 2021-06-13T01:08:36Z | - |
| dc.date.available | 2016-08-09 | |
| dc.date.copyright | 2011-08-09 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-08-03 | |
| dc.identifier.citation | Adamson, A. W., Physical Chemistry of Surfaces; 5th ed.; John Wiley & Sons, Inc., New York, 1990.
Andreas, J. M., E. A. Hauser, and W. R. Tucker, “Boundary Tension by Pendant Drops,” J. Phys. Chem. 42, 1001, 1938. Aratono, M. and M. Kahlweit, “Wetting in Water-Oil-Nonionic Amphiphile Mixtures,” J. Chem. Phys. 95, 8578, 1991. Bonn, D., H. Kellay, and G. H. Wegdam, “Experimental Observation of Hysteresis in a Wetting Transition,” Phys. Rev. Lett. 69, 1975, 1992. Buff, F. P. and H. Saltsburg, “Curved Fluid Interfaces. II. The Generalized Neumann Formula,” J. Chem. Phys. 26, 23, 1957. Cahn, J. W., “Critical Point Wetting.” J. Chem. Phys. 66, 3667, 1977. Chen, L.-J., C.-D. Chiu, F.-S. Shau, W.-J. Cheng, and J. G. Wu, “Oil Chain-Length Effect on Wetting Transitions in Ternary Water + Oil + Surfactant Mixtures,” J. Phys. Chem. B 106, 12782, 2002. Chen, L.-J. and H.-C. Hsu, “Effect of Salt Concentration on Interfacial Behavior in the Surfactant System Water + n-Octadecane + Diethylene glycol monohexyl ether,” J. Chem. Phys. 97, 690, 1992. Chen, L.-J., M.-C. Hsu, S.-T. Lin, and S.-Y. Lin, and S.-Y. Yang, “Salt Effect on Wetting/Nonwetting Behaviors,” J. Phys. Chem. 99, 4687, 1995. Chen, L.-J. and W.-J. Yan, “Novel Interfacial Phenomena at Liquid-Liquid Interfaces of the Three-Component Surfactant System Water + n-Tetradecane + C6E2,” J. Chem. Phys. 98, 4830,1993. Christensen, S. P., F. A. Donate, T. C. Frank, R. J. LaTulip, and L. D. Wilson, “Mutual Solution and Lower Critical Solution Temperature for Water + Glycol Ether Systems,” J. Chem. Eng. Data 50, 869, 2005. CRC Handbook of Chemistry and Physics; 61st ed.; Weast, R. C., ed.; CRC Press: Boca Raton, Florida, 1980-1981. Davison, R. R., W. H. Smith, and D. W. Hood, “Mutual Solubility of Water and Glycerol and Glycol Ethers,” J. Chem. Eng. Data 11, 404, 1966. Ebner, C. and W. F. Saam, “New Phase-Transition Phenomena in Thin Argon Films,” Phys. Rev. Lett. 38, 1486, 1977. Fleming, P. D. III and J. E. Vinatieri, “The Role of Critical Phenomena in Oil Recovery Systems Employing Surfactants,” J. Colloid Interface Sci. 81, 319, 1981. Gullickson, N. D., J. F. Scamehorn, and Harwell, J. F., Surfactant-Based Separation Processes; Scamehorn, J. F., Harwell, J. F., Eds.; Surfactant Science Series 33; Marcel Dekker: New York, 1989; Chapter 6. Herrmann, C. U., G. Klar, and M. Kahlweit, “On the Phase Inversion in H2O-Oil-Nonionic Surfactant Systems and Related Phenomena,” J. Colloid Interface Sci. 82, 6, 1980. Hu, H., C.-D. Chiu, and L.-J. Chen, “Liquid-Liquid Equilibria for the Ternary System Water + n-Dodecane + 2-(2-n-Hexyloxyethoxy)-ethanol,” Fluid Phase Equilib. 164, 187, 1999. Hu, H. and L.-J. Chen, “Liquid-Liquid Equilibria for the Ternary System Water + n-Tetradecane + 2-(2-n-Hexyloxyethoxy)ethanol at 293.15 K and 303.15 K,” J. Chem. Eng. Data 45, 304, 2000. Jho, C. and M. Carreras, “The Effect of Viscosity on the Drop Weight Technique for the Measurement of Dynamic Surface Tension,” J. Colloid Interface Sci. 99, 543, 1984. Kahlweit, M., “The Phase Behavior of Systems of the Type H2O-Oil-Nonionic Surfactant-Electrolyte,” J. Colloid Interface Sci. 90, 197, 1982. Kahlweit, M. and G. Busse, “Wetting in Mixture of Water, Nonionic Amphiphile, and Nonpolar Solvent,” J. Chem. Phys. 91, 1339, 1989. Kahlweit, M. and G. Busse, “Tricritical Points and Wetting | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/29496 | - |
| dc.description.abstract | 在本研究中針對水+油+非離子型界面活性劑三成份系統探討其相行為及濕透行為，所使用的油皆為正烷類，非離子型界面活性劑為CiPj。CiPj為醇醚類化合物，是CH3(CH2)i-1(OCH2CH(CH3))jOH之縮寫，其中i代表非極性碳氫鏈長度，而j代表的是丙烯氧基的長度。我們在水+正十烷+C3P1、水+正十二烷+C3P1、水+正十四烷+C3P1、水+正十六烷+C3P1、水+正十二烷+C3P2、水+正十四烷+C3P2及水+正十六烷+C3P2七個系統中，發現三液相共存區的存在。配製水與油的重量比為1:1的水+油+CiPj三成分溶液，透過改變CiPj的重量分率及溫度，觀察系統平衡時的液相數目，可將結果繪製成魚形相圖。透過比較七個系統的魚形相圖，可以清楚地知道當油的碳數增加時，三液相共存區的上、下臨界溫度都會上升；另外增加CiPj中j的數目，則會使上、下臨界溫度下降。接著我們使用氣相層析儀，對水+正十二烷+C3P1、水+正十四烷+C3P1、水+正十六烷+C3P1、水+正十二烷+C3P2、水+正十四烷+C3P2及水+正十六烷+C3P2六個系統在進行液-液相平衡量測，並將結果繪製成三角相圖。根據相圖的結果，在水+油+CiPj三成分系統中，隨著溫度的上升，可以觀察到從兩液相轉變為三液相再轉變成兩液相的相行為，其中低溫時的兩液相，下層相的界面活性劑重量分率較上層相高，高溫時的兩液相則是相反的情況，此現象和文獻中水+油+非離子型界面活性劑的相行為相符。此外，我們利用NRTL模型對各系統三角相圖的數據結果進行迴歸分析及理論計算，發現NRTL模型可有效地描述水+油+CiPj三成分系統的相行為。對一三液相系統，可藉由測量上層相對中間相、上層相對下層相及中間相對下層相三種界面張力，判斷其濕透行為。在本研究中，利用懸垂液滴法測量界面張力，輔以觀察法，對水+正十二烷+C3P1、水+正十四烷+C3P1、水+正十六烷+C3P1及水+正十六烷+C3P2四個系統探討其濕透行為，發現這四個系統在三液相的溫度區間，都是呈現中間相的完全濕透行為。 | zh_TW |
| dc.description.abstract | In this study, we investigate the phase behavior and the wetting behavior of the ternary water + oil + nonionic surfactant system. The oils are n-alkanes and the nonionic surfactants are CiPj. The symbol CiPj is the abbreviation of a propylene glycol ether CH3(CH2)i-1(OCH2CH(CH3))jOH. There are three-liquid-phase- coexisting regions in water + decane + C3P1, water + dodecane + C3P1, water + tetradecane + C3P1, water + hexadecane + C3P1, water + dodecane + C3P2, water + tetradecane + C3P2, and water + hexadecane + C3P2 systems. Experiments of fish-shaped phase diagrams for these seven systems under atmospheric pressure were performed at constant water/n-alkane weight ratio (1/1) to locate the critical end points. The ternary system of the alkane with the longer carbon chain length has the higher upper and lower critical solution temperatures and the larger three-liquid-coexisting temperature window in the fish-shaped phase diagram. The upper and lower critical solution temperatures are lower in these systems with larger j number of C3Pj. Precise liquid-liquid equilibrium data of mixtures for six ternary systems water + alkane (dodecane, tetradencane, and hexadecane) + C3Pj (j=1 or 2) under atmospheric pressure were determined by using gas chromatography. The evolution of phase behavior of the ternary water + n-alkane + C3Pj system as a function of temperature is qualitatively consistent with that of the water + oil + CiEj system. The experimental liquid-liquid equilibrium data were successfully correlated with the NRTL model. We use pedant drop method to measure the interfacial tensions and investigate the wetting behavior of four ternary systems, water + dodecane + C3P1, water + tetradecane + C3P1, water + hexadecane + C3P1, and water + hexadecane + C3P2 system. In these ternary systems, the middle surfactant-rich phase exhibits complete wetting in the temperature window of the three-liquid-phase-coexisting region. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T01:08:36Z (GMT). No. of bitstreams: 1 ntu-100-D94524016-1.pdf: 6113522 bytes, checksum: 3bd56b4c7064c5d0617b0df28ce78738 (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 摘要 I
英文摘要 II 目錄 III 表目錄 V 圖目錄 IX 第一章 緒論 1 第二章 相行為與濕透行為 11 2-1 水+油+非離子型界面活性劑三成份系統之相行為 11 2-2 三流體相系統之濕透行為 16 第三章 實驗藥品、設備與實驗方法 27 3-1 實驗藥品 27 3-2 實驗設備 28 3-3 實驗方法 38 第四章 水+油+CiPj三成份系統的相行為 54 4-1 水+油+CiPj三成份系統的魚形相圖 54 4-2 水+油+CiPj三成份系統的三角相圖 58 4-3 迴歸與計算 63 第五章 水+油+CiPj三成份系統的濕透行為 118 5-1 水+油+C3P1三成份系統的濕透行為 118 5-2 水+油+C3P2三成份系統的濕透行為 121 第六章 結論 138 參考文獻 140 附錄 146 | |
| dc.language.iso | zh-TW | |
| dc.subject | 相行為 | zh_TW |
| dc.subject | 濕透行為 | zh_TW |
| dc.subject | 界面活性劑 | zh_TW |
| dc.subject | 懸附液滴法 | zh_TW |
| dc.subject | 丙烯氧基 | zh_TW |
| dc.subject | phase behavior | en |
| dc.subject | propylene glycol ether | en |
| dc.subject | pendant drop method | en |
| dc.subject | surfactant | en |
| dc.subject | wetting behavior | en |
| dc.title | 水+油+CiPj三成份系統之相行為及濕透行為研究 | zh_TW |
| dc.title | A Study on Phase Behavior and Wetting Behavior of the Ternary Water + Oil + CiPj System | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 李亮三,李明哲,李夢輝,陳延平,林祥泰 | |
| dc.subject.keyword | 相行為,濕透行為,界面活性劑,懸附液滴法,丙烯氧基, | zh_TW |
| dc.subject.keyword | phase behavior,wetting behavior,surfactant,pendant drop method,propylene glycol ether, | en |
| dc.relation.page | 159 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-08-03 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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