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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張尊國(Tsun-Kuo Chang) | |
| dc.contributor.author | Wei-Chin Chen | en |
| dc.contributor.author | 陳威智 | zh_TW |
| dc.date.accessioned | 2021-06-13T01:07:25Z | - |
| dc.date.available | 2007-07-26 | |
| dc.date.copyright | 2007-07-26 | |
| dc.date.issued | 2007 | |
| dc.date.submitted | 2007-07-20 | |
| dc.identifier.citation | 參考文獻
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Almodovar, 2003,“Beudantite: A Natural Sink For As and Pb in Sulphide Oxidation Processes”, Applied Earth Science, 112, B293 42. Nimick, D.A., Moore, J.N., Dalby, C.E., Savka, M.W., 1998, “The Fate of Geothermal Arsenic in The Madison and Missouri River, Montana and Wyoming”, Water Resour. Res, 34, pp.3051-3067. 43. Ondra Sracek, Prosun Bhattacharya,Gunnar Jacks, 2004,“Behavior of Arsenic and Geochemical Modeling of Arsenic Enrichment in Aqueous Environments”, Applied Geochemistry, 19, pp.169-180. 44. Palache C., Berman H., 1951, Frondelthe C,System of Mineralogy [M], Seven edition,001-1 002. 45. Pradosh Roy, Anupama saha, 2002,“Metabolism And Toxicity of Arsenic: A Human Carcinogen”, Current Science, 82 46. Qiao, J., X-Q Shan, Z-j Wang and Qiang Tu., 1996, “Distribution and plant availability of heavy metals in different particle-size fractions of soil”, The Science of the total Environment. 187, pp.131-141. 47. 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Waslenchuk, D.G., 1979,“The Geochemical Controls on Arsenic Concentrations in Southeastern United States Rivers”, Chem. Geol, 24, pp.315-325. 60. Wang S., Catherine N. Mulligan, 2006,“Natural Attenuation Processes for Remediation of Arsenic Contamination Soils and Groundwater”, Journal of Hazardous Materials, B138, pp.459-470. 61. Webster J.G., 1998, “The Source of Arsenic (and other elements) in The Marbel-Matingao River Catchment, Mindanao, Philippines”, Geothermics 28, pp.95-111. 62. Wedepohl, K. H., 1995, “The Composition of The Continental Crust”, Geochim. Cosmochim. Acta, 59, pp.217-1232. 63. Wilkie J.A., J.G. Hering, 1996,“Adsorption of Arsenic onto Hydrous Ferric oxide: Effects of Adsorbate/Adsorbent ratios and Co-occurring Solutes”, Colloid Surf, A 107, pp.7-110. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/29450 | - |
| dc.description.abstract | 2006年11月台大生態工程研究中心於北投關渡平原發現面積達百餘公頃農地土壤砷含量異常的現象，並認為其砷來源肇因於地熱谷含砷之溫泉水隨灌溉系統擴散於農田，並同時於北投溪(磺港溪的支流)河岸與河床中首次在台灣發現含有砷鉛鐵礬礦物。本研究目的為探討磺港溪底泥不同粒徑中的砷、鉛濃度之分佈關係。本研究方法係將磺港溪(地熱谷-磺港溪下游)的河川底泥通過五種不同尺寸的篩號，分別為16號(1.19 mm)、20號(0.84 mm)、100號(0.15 mm)、200號(0.075 mm)、300號(0.05 mm)，利用X射線螢光分析儀(XRF)檢測河川底泥重金屬(砷、鉛)含量。研究結果發現磺港溪底泥中的砷、鉛濃度皆會隨著顆粒細粒化而明顯地增加。河川底泥粒徑介於0.84-1.19 mm之平均砷濃度為229 (中位數136) mg kg-1，平均鉛濃度為182 (中位數119) mg kg-1；粒徑小於0.05 mm之平均砷濃度增加至790 (中位數601) mg kg-1，平均鉛濃度則上升至807 (中位數636) mg kg-1。由本研究結果得知底泥中砷濃度大於鉛濃度，兩者重量比(砷/鉛)介於1.29~1.40之間，莫耳數比(砷/鉛)介於3.58~3.88之間，與砷鉛鐵礬理想化學式之莫耳數比(砷/鉛) (1：1)有很大的差異。同時比較粒徑小於0.05 mm的農田土壤與河川底泥中的砷濃度，結果顯示農田土壤最高砷濃度值為444 mg kg-1仍低於河川底泥之平均砷濃度，因此本研究認為北投地區的農田砷汙染由底泥顆粒帶入所造成的機率極低 | zh_TW |
| dc.description.abstract | Over 100 hectare paddy soils were found heavily polluted by arsenic through long-term irrigation with the water mixed with hot spring, in 2006 at Beitou, Taiwan. Moreover, in Taiwan it is the first time the beudantite was found on the bank and streambed of a nearby Huang Gang creek. The objective of this study is to investigate the distribution of arsenic and lead concentrations in the sediments of Huang Gang creek. 49 samples were collected along the creek about 4.6 km long. All samples were sieved to fine-grained fractions: 1.19-0.84 mm, 0.84-0.15 mm, 0.15-0.075 mm, 0.075-0.05 mm and<0.05 mm, prior to analysis. The results show that finer grained sediment samples tend to have higher concentrations of As and Pb. Samples were sieved to 1.19-0.84 mm had the mean concentrations of As and Pb 229 (with median 136) mg kg-1, and 182 (with median 119) mg kg-1 respectively; while the samples sieved to 0.05 mm had the mean concentrations of As and Pb 790 (601) mg kg-1, and 807 (636) mg kg-1. In general, the concentration of arsenic is higher than that of lead in all sediment samples, and the ratio is in the range between 1.29-1.4; the molar ratio is between 3.58-3.88. It is apparently different from the molar ratio (ratio=1) of beaudantite. The samples from paddy soils and stream sediments with the same particle size, <0.05mm, are compared with the As and Pb content, and it shows that the difference is marked. Therefore, the major cause of the As and Pb pollution of paddy soils seems to be not from sediments | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T01:07:25Z (GMT). No. of bitstreams: 1 ntu-96-R94622007-1.pdf: 5849612 bytes, checksum: 12d99a728a371b105c2369b81fde0c04 (MD5) Previous issue date: 2007 | en |
| dc.description.tableofcontents | 摘要 III
英文摘要 VI 目錄 V 圖目錄 VIII 表目錄 XI 第一章 前言 1.1 研究動機 ..1 1.2 研究目的 3 1.3 研究流程 4 第二章 文獻回顧 2.1 砷鉛鐵礬介紹 5 2.2 砷在地殼中的分佈 7 2.3 砷與溫泉之關係 8 2.4 重金屬砷鉛與底泥之關係 9 2.4.1 底泥形成與粒徑分佈 9 2.4.2 重金屬砷鉛在底泥中的結合型態 12 2.4.3 河川底泥中粒徑與重金屬濃度分佈 15 第三章 研究材料與實驗設計方法 3.1 研究區域之環境資料 17 3.1.1 地熱谷環境資料 17 3.1.2 磺港溪水文資料 20 3.2 磺港溪河床質調查方法 24 3.2.1 採樣設備與規劃 24 3.2.2 採樣原則與步驟 28 3.2.3 紀錄與樣本處理 30 3.3 河床底泥粒徑篩分析實驗 32 3.3.1 篩分析儀器 33 3.3.2 篩分析方法與步驟 35 3.4 儀器設備與原理 37 3.4.1 X-ray螢光光譜儀分析原理 38 3.4.2 手持式X-ray螢光光譜儀設備 40 3.4.3 X光繞射原理 42 3.4.4 X光繞射儀器 44 第四章 結果與討論 4.1 河川底泥之土壤分類與粒徑分析 49 4.2 河川底泥中粒徑與重金屬濃度之關係 52 4.2.1 北投溪至磺港溪下游底泥中不同粒徑與砷濃度之關係 52 4.2.2 北投溪至磺港溪下游底泥中不同粒徑與鉛濃度之關係 58 4.2.3 北投溪-磺港溪河川底泥中粒徑與砷/鉛比值之關係 64 4.2.4 磺港溪上游支流底泥中粒徑與砷濃度之關係 64 4.2.5 磺港溪上游支流底泥中粒徑與鉛濃度之關係 67 4.2.6 磺港溪上游支流底泥中粒徑與砷/鉛比值之關係 68 4.3 農地土壤中粒徑與重金屬濃度之關係 69 4.3.1 農地土壤中粒徑與砷濃度之關係 69 4.3.2 農地土壤中粒徑與鉛濃度之關係 72 4.3.3 農地土壤中砷/鉛濃度比值關係 74 4.4 河川底泥X光繞射實驗結果 75 第五章 結論與建議 82 參考文獻 83 附錄 附錄A 北投溪-磺港溪底泥砷、鉛濃度原始數據 89 附錄B 磺港溪上游支流底泥砷、鉛濃度原始數據 95 附錄C 農田土壤砷鉛濃度數值 96 附錄D 磺港溪底泥採樣記錄表 97 | |
| dc.language.iso | zh-TW | |
| dc.subject | 砷 | zh_TW |
| dc.subject | 鉛 | zh_TW |
| dc.subject | 底泥 | zh_TW |
| dc.subject | 粒徑 | zh_TW |
| dc.subject | 溫泉 | zh_TW |
| dc.subject | hot spring | en |
| dc.subject | lead | en |
| dc.subject | Arsenic | en |
| dc.subject | sediment | en |
| dc.subject | particle-size | en |
| dc.title | 北投溫泉地區磺港溪底泥中重金屬砷鉛濃度分佈之探討 | zh_TW |
| dc.title | Distribution of Arsenic and Lead in the Sediments in Hot Spring Area of Huang Gang Creek, Beitou | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 95-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 范正成(Jen-chen Fan),張文亮(Wen-lian Chang),王明光(Ming-Kuang Wang) | |
| dc.subject.keyword | 砷,鉛,底泥,粒徑,溫泉, | zh_TW |
| dc.subject.keyword | Arsenic,lead,sediment,particle-size,hot spring, | en |
| dc.relation.page | 105 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2007-07-23 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物環境系統工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物環境系統工程學系 | |
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