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  1. NTU Theses and Dissertations Repository
  2. 電機資訊學院
  3. 電子工程學研究所
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/28186
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor鄭鴻祥(Henry H. Cheng)
dc.contributor.authorTzung-Hsian Wuen
dc.contributor.author吳宗憲zh_TW
dc.date.accessioned2021-06-13T00:02:20Z-
dc.date.available2011-08-08
dc.date.copyright2011-08-08
dc.date.issued2011
dc.date.submitted2011-08-08
dc.identifier.citationBibliography
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/28186-
dc.description.abstract我們的實驗研究內容為利用分子束磊晶技術,成長厚度超過臨界厚度之鍺錫薄
膜。一系列鍺錫薄膜樣品是於接近錫熔點之低溫條件下,成長於鍺緩衝層之上,
內含最高可達百分之十四之相異的錫成份。特別的是,一層低溫鍺緩衝層被成長
於鍺錫薄膜與鍺基板之間,用以捕捉晶格缺陷。數個量測分析展現了在穿透式電
子顯微鏡橫截面影像裡,鍺錫薄膜幾無缺陷,而且在錫成份低於百分之九點三的
樣品裡錫非常均勻地分布在鍺錫薄膜當中。我們所成長的鍺錫合金內含之錫成分,
超過了理論預測裡鍺可由非直接能隙轉變為直接能隙的錫成分。因此,此份研究
目的為提供一個可成長出直接能隙鍺錫薄膜的方法,亦可被應用於光電元件技術
之中。
zh_TW
dc.description.abstractWe report on experimental investigations of the growth of Ge1-xSnx film with thickness above the critical thickness using Molecular Beam Epitaxy. A series of Ge1-xSnx films with various Sn compositions up to 14% are deposited on a Ge buffer layer for growth at low temperatures close to the melting point of Sn. Especially, a low temperature Ge buffer layer was grown between GeSn film and Ge substrate for
trapping defects. Analysis of various measurements shows that the Ge1-xSnx film is defect free in the XTEM image and that Sn is distributed almost uniformly in the film for Sn compositions up to 9.3%. The Sn composition of the films is higher than the Sn composition that is theoretically predicted to cause the energy band of Ge to change from an indirect to a direct bandgap; thus, the present nvestigation provides a method for growing direct bandgap GeSn film, which is desired for use in applications involving optoelectronic devices.
en
dc.description.provenanceMade available in DSpace on 2021-06-13T00:02:20Z (GMT). No. of bitstreams: 1
ntu-100-R98943113-1.pdf: 2434516 bytes, checksum: 067b9d294129e2884626f0a8a468bd08 (MD5)
Previous issue date: 2011
en
dc.description.tableofcontentsContents
口試委員會審定書 #
誌謝 i
中文摘要 ii
Abstract ……………………………………………………..………………………….iii
Contents………….……………………….......................................................................iv
List of Figures……………………………………..………………………………….vii
List of Table…….…………………………….………………………………………….x
CHAP1 Introduction……………………………………………………...1
1.1 Motivation…………………………………………………………...1
1.2 Ge…………………………………………………………………..3
1.3 GeSn Alloy…………………………………………………………..…7
1.3.1 Material Properties…………………………………………………………...7
1.3.2 Growth Challenges………………………………………………………….10
CHAP 2 Growth Equipments and Charaterization Techniques……...13
2.1 Molecular Beam Epitaxy……………………………………………...13
2.2 Reflection High-Energy Electron Diffraction………………………...15
2.3 Transmission Electron Microscopy…………………………………...16
2.4 Energy-Dispersive X-ray Spectroscopy………………………………17
2.5 Scanning Electron Microscope………………………………………..18
2.6 X-Ray Diffraction……………………………………………………..20
2.7 Fourier Transform Infra-Red spectroscopy…………………………...21
2.8 Raman Scattering……………………………………………………..22
CHAP 3 MBE Growth of GeSn Alloys…………………………………24
3.1 Sample Growth of GeSn Alloys………………………………………24
3.2 Material Quality Characterization…………………………………….28
3.2.1 Transmission Electron Microscopy…………………………………………28
3.2.2 Energy-Dispersive X-ray Spectroscopy…………………………………….32
3.2.3 Scanning Electron Microscope……………………………………………...33
CHAP 4 Physical properties of GeSn Alloys…………………………...36
4.1 Strain Analysis………………………………………………………...36
4.1.1 Experimental Results………………………………………………………..36
4.1.2 Theoretical Calculations…………………………………………………….38
4.1.3 Results and discussion………………………………………………………40
4.2 Optical Characterization………………………………………………42
4.2.1 Fourier Transform Infra-Red spectroscopy…………………………………42
4.2.2 Raman Scattering……………………………………………………………46
CHAP 5 Conclusions and Future Work………………………………..48
5.1 Conclusions…………………………………………………………...48
5.2 Future work…………………………………………………………...49
Bibliography……………………………………………………………...50
dc.language.isoen
dc.subject穿透式電子顯微鏡zh_TW
dc.subject分子束磊晶zh_TW
dc.subject鍺錫合金zh_TW
dc.subject直接能隙zh_TW
dc.subjectGeSn alloyen
dc.subjectMBEen
dc.subjectdirect bandgapen
dc.subjectTEMen
dc.title低溫下高成分錫之鍺錫成長研究zh_TW
dc.titleInvestigation of Ge1-xSnx/Ge with high Sn composition grown at low temperatureen
dc.typeThesis
dc.date.schoolyear99-2
dc.description.degree碩士
dc.contributor.oralexamcommittee孫剛(Greg Sun),洪冠明(K. M. Hung),賈至達(C. T. Chia),張國恩(Guo-En Chang)
dc.subject.keyword分子束磊晶,鍺錫合金,直接能隙,穿透式電子顯微鏡,zh_TW
dc.subject.keywordMBE,GeSn alloy,direct bandgap,TEM,en
dc.relation.page52
dc.rights.note有償授權
dc.date.accepted2011-08-08
dc.contributor.author-college電機資訊學院zh_TW
dc.contributor.author-dept電子工程學研究所zh_TW
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