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  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 物理學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/26192
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor林敏聰
dc.contributor.authorJang-Chang Huangen
dc.contributor.author黃仁璋zh_TW
dc.date.accessioned2021-06-08T07:02:30Z-
dc.date.copyright2009-02-12
dc.date.issued2009
dc.date.submitted2009-02-02
dc.identifier.citation[1] J. R. Petta, S. K. Slater, and D. C. Ralph, Phys. Rev. Lett. 93,
136601(2004)
[2] Alexandre R. Rocha, V´ıctor M. Garc´ıa-Su´arez, Steve W. Bailey, Colin
J. Lambert, Jaime Ferrer, and Stefano Sanvito, Nat. Mat. 4, 335(2005)
[3] R. Vollmer, Th. Gutjahr-Loser, and J. Kirschner, S. van Dijken and B.
Poelsema, Phys. Rev. B, 60, 6277(1998)
[4] T. C. Kreutz, E. G. Gwinn, R. Artzi, R. Naaman, H. Pizem and C. N.
Sukenik, Appl. Phys. Lett. 83, 4211(2003)
[5] C. Pernechele, M. Solzi, M. Ghidini, E. Arisi, I. Bergenti, and V. Dediu,
J. Phys. D: Appl. Phys. 41, 134013(2008)
[6] I. Bergenti, A Riminucci, E. Arisi, M. Murgia, M. Cavallini, M. Solzi,
F. Casoli and V. Dediu, J. Magn. Mag. Mat. 316, e987(2007)
[7] S. N. Ahmad, S. G. Rao, S. A. Shaheen, D. Magana, and G. F. Strouse,
Appl. Phys. Lett. 92, 112511(2008)
[8] Lei Fu, Vinayak P. Dravid, D. Lynn Johnson, Appl. Surf. Sci. 181,
173(2001)
[9] Wonbae Bang and Kimin Hong, Electrochem. Solid-State Lett. 10,
J86(2007)
[10] Abraham Ulman, An Introduction to Ultrathin Organic Films from
Langmuir-Blodgett to Self-Assembly(1991)
[11] Y. Pennec, W Auw¨arter, A. Schiffrin, A. Weber Bargioni, A. Riemann,
and J. V. Barth, Nat. Nano Tech. 2, 99(2007)
[12] M. F. Calhoun, J. Sanchez, D. Olaya, M. E. Gershenson, and V. Podzorov,
Nat. Mat. 7, 84(2008)
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/26192-
dc.description.abstractWe demonstrate the tuning of magnetic properties of ferromagnetic (FM)
thin films by reversing the functional groups of a molecular mono-underlayer.
We construct a bilayer thin film system which consists of a FM material and
an organic mono-layer by applying organic molecules to form a molecular
mono-layer on the glass substrate, then depositing the FM thin film onto
the organic molecules by sputtering. We design the experiment to use only
one kind of molecule to create two different kinds of surfaces by reversing
the functional groups of the molecular mono-layer. By simply reversing the
functional groups of the mono-layer in direct contact with the FM thin films,
two kinds of surfaces have been designed to be hydrophilic or hydrophobic.
Two FM materials are studied. One is CoFe, and the other is permalloy (Py).
In the system of CoFe thin films we found the coercivity of hydrophobic
molecular mono-layer covered with CoFe films is enhanced. On the other
hand, in the system of Py thin films we found the FM behavior disappears
at room temperature when the hydrophobic molecular mono-layer is covered
with Py films, and this phenomenon is correlated to the surface morphology.
The study in this thesis is helpful to organic spintronics and could be used
to fabricate organic spintronics, which is a frontier of spintronics.
en
dc.description.provenanceMade available in DSpace on 2021-06-08T07:02:30Z (GMT). No. of bitstreams: 1
ntu-98-P95222002-1.pdf: 23063712 bytes, checksum: 88254bfa05dc4b3133ba1936afcc98a0 (MD5)
Previous issue date: 2009
en
dc.description.tableofcontents1 Introduction and Motivation 10
2 Apparatuses and Chemicals 14
2.1 Preparation and Fabrication . . . . . . . . . . . . . . . . . . . 14
2.1.1 Preparation System of Langmuir-Blodgett Films . . . . 14
2.1.2 Sputtering System . . . . . . . . . . . . . . . . . . . . 18
2.2 Analysis of Film Properties . . . . . . . . . . . . . . . . . . . 21
2.2.1 Magnetic Properties . . . . . . . . . . . . . . . . . . . 21
2.2.2 Morphology . . . . . . . . . . . . . . . . . . . . . . . . 22
2.2.3 Surface Properties . . . . . . . . . . . . . . . . . . . . 24
2.3 Chemicals and Materials . . . . . . . . . . . . . . . . . . . . . 24
2.3.1 Ferromagnetic Materials . . . . . . . . . . . . . . . . . 24
2.3.2 Amphibious Molecules . . . . . . . . . . . . . . . . . . 24
3 Experimental Processes 24
3.1 Flow chart of experiments . . . . . . . . . . . . . . . . . . . . 24
3.2 Preparation of Organic Langmuir-Blodgett Films . . . . . . . 26
3.3 Preparation of Ferromagnetic Thin Films . . . . . . . . . . . . 27
3.4 Measurement and Analysis of Samples . . . . . . . . . . . . . 27
3.4.1 Magnetic properties . . . . . . . . . . . . . . . . . . . . 27
3.4.2 Thickness . . . . . . . . . . . . . . . . . . . . . . . . . 27
3.4.3 Morphology . . . . . . . . . . . . . . . . . . . . . . . . 28
3.4.4 Surface Properties . . . . . . . . . . . . . . . . . . . . 28
4 Results and Discussion 28
4.1 Surface Properties of Stearic Acid . . . . . . . . . . . . . . . . 28
4.2 Ferromagnetic Properties of CoFe Thin Films System . . . . . 29
4.3 Ferromagnetic Properties of Permalloy Thin Films System . . 41
5 Summary 49
6 References 50
dc.language.isoen
dc.subject鐵磁性薄膜zh_TW
dc.subject單分子層官能基zh_TW
dc.subjectmolecular mono-layeren
dc.subjectferromagnetic thin-filmen
dc.title單分子層官能基對鐵磁性薄膜磁性質改變之研究zh_TW
dc.titleTuning of Magnetic Properties of Ferromagnetic Thin-film by Reversing the Functional Group of Molecular Mono-underlayeren
dc.typeThesis
dc.date.schoolyear97-1
dc.description.degree碩士
dc.contributor.oralexamcommittee林寬鋸,陳銘堯,戴龑
dc.subject.keyword單分子層官能基,鐵磁性薄膜,zh_TW
dc.subject.keywordferromagnetic thin-film,molecular mono-layer,en
dc.relation.page50
dc.rights.note未授權
dc.date.accepted2009-02-03
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept物理研究所zh_TW
顯示於系所單位:物理學系

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