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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳永芳 | |
| dc.contributor.author | Chun-Ping Yang | en |
| dc.contributor.author | 楊君平 | zh_TW |
| dc.date.accessioned | 2021-06-08T06:10:49Z | - |
| dc.date.copyright | 2007-07-25 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2007-07-07 | |
| dc.identifier.citation | 1. Iijima S 1991 Nature 354 56
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However, in the presence of formamide, the spontaneous atmospheric oxidation process can be accelerated at room temperature to release zinc ions into reaction solution through the formation of zinc-formamide complexes. More zincformamide complexes can be supplied continuously at an elevated temperature. At an optimized temperature of 65 °C in 5% formamide aqueous solution, high-quality ZnO nanoarrays can be produced readily by this simple chemical-liquid-deposition approach during a period of 24 h of reaction. In the temporal evolution of zinc oxidation, zinc concentration increased proportionally with reaction time due to the continuous release of zinc ions into solution, and Zn complexes can be accumulated up to 0.46 mM gradually after 24 h in our preparation system. Freshly produced Zn ions can be supplied continuously for the subsequent crystal growth of nanorods on the seed particles through the thermal decomposition of the resulting zinc-formamide complexes. 45. Bakkers, E. P. A. M.; Verheijen, M. A. J. Am. Chem. Soc. 2003, 125. 3440. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/25371 | - |
| dc.description.abstract | In this thesis, several methods in fabricating well-aligned ZnO nanorods as well as their optical properties will be reported. Firstly, the fabrication of Cu-doped ZnO nanorods via VLS mechanism or electrodeposition method using AAO as templates will be demonstrated. The redshift of the band-gap emission will be illustrated by the measurement of CL spectra and its relation with the doping of Cu will also be discussed. In the second part, AAO membranes are used in the seeded-growth of well-aligned single-crystalline ZnO nanorod arrays as the seeded substrates. The formation of highly-oriented ZnO nanorod arrays will be discussed, hoping to contribute to further research in field-emission or photonic crystal. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T06:10:49Z (GMT). No. of bitstreams: 1 ntu-95-R93222039-1.pdf: 1613715 bytes, checksum: 3ea9db0218942d6b968de05c909c5a39 (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | Chapter 1 Introduction ............................................................................................ 1
Chapter 2 Experimental Bacground ………………................................................ 5 2.1 Cathodoluminescence(CL) .............................................................................. 5 2.1.1 Introduction of luminescence ..………………………………………… 5 2.1.2 Direct and indirect band gap …………………………………………... 7 2.1.3 Recombination processes ……………………………………………… 10 2.1.4 Cathodoluminescence (CL) …...………………………………………. 13 2.2 Scanning Electron Microscopy (SEM) ......................................................... 15 2.3 Anodic Aluminum Oxide …………………………………………………... 22 2.3.1 Introduction ………………………………………................................. 22 2.3.2 The structure and fabrication of AAO films ......................................... 23 Chapter 3 The fabrication of ZnCuO nanorods ………………………………… 31 3.1 Introduction ………………………………………………………………… 31 3.2 Fabrication of ZnCuO nanorods via VLS mechanism …………………... 34 3.2.1 Experimental details …………………………………………………... 34 3.2.2 Experimental Results ………………………………………………….. 38 3.2.3 Discussion ………………………………………………………………. 44 3.3 Fabrication of ZnCuO nanorods based on AAO templates ……………... 45 3.3.1 Experimental details …………………………………………………... 45 3.3.2 Experimental results and discussion ……………………………………. 48 Chapter 4 Fabrication of well-aligned ZnO nanorods at ow temperature ……… 53 4.1 Introduction …………………………………………………………………… 53 4.2 Experemental details …………………………………………………………. 55 4.3 Results and discussion ………………………………………………………... 58 Chapter 5 Conclusion ……………………………………………………………….. 67 | |
| dc.language.iso | en | |
| dc.title | 參雜銅之氧化鋅奈米柱之製備/規則排列氧化鋅奈米柱之製備 | zh_TW |
| dc.title | Fabrication of well-aligned ZnCuO/ZnO nanorods | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 95-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 張顏暉,林泰源 | |
| dc.subject.keyword | 氧化鋅,奈米柱,氧化銅,規則排列,陽極氧化鋁,陰極發光, | zh_TW |
| dc.subject.keyword | ZnO,ZnCuO,nanorod,AAO,well-aligned,cathodoluminescence, | en |
| dc.relation.page | 67 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2007-07-10 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 物理研究所 | zh_TW |
| 顯示於系所單位： | 物理學系 | |
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