請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24345完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝國煌 | |
| dc.contributor.author | Nan-Chang Lee | en |
| dc.contributor.author | 李南漳 | zh_TW |
| dc.date.accessioned | 2021-06-08T05:22:41Z | - |
| dc.date.copyright | 2005-07-26 | |
| dc.date.issued | 2005 | |
| dc.date.submitted | 2005-07-26 | |
| dc.identifier.citation | 1. Edward F. Cassidy, Han X. Xiao, Kurt C. Frisch and Harry L. Frisch, Journal of Polymer Science, 22,1851(1984).
2. Edward F. Cassidy, Han X. Xiao, Kurt C. Frisch and Harry L. Frisch, Journal of Polymer Science, 22,2667(1984). 3. Joseph J. Matous, Michael Kallaur, Annu., Conf., RP/C, SPI, 18-A (1986). 4. Robert R, Hussey, Annu, Conf., RP/C, SPI, 2-B(1987). 5. John Delmonte, ibid, 3-C. 6. Greg Bjumer, Annu., Conf., RP/C, SPI, 4-B(1985). 7. John Greenzwing and Tom Moulson, Annu., Conf. RP/C,SPI, 4-D (1982). 8. E.J. Kerle, T.H.Grentzer, Annu., Conf., RP/C, SPI,5-D(1986). 9. Michanel J.Rich, ibid, 2-F(1986). 10.Bruce B.Fitts, Advances in Polymer Technology, Vol.6, No.2, p.213-223 (1986). 11. Jack Travis and Catherine Baird, Annu. Conf., RP/C,SPI, 15-D (1983). 12. Richard Venger, Annu., Conf., RP/C, SPI, 9-D(1981). 13. V. Brandt Goldworthy, Plastics World, August, pp.56-58(1981). 14. James E. O'Connor and Villiam H. Beever, 42nd Annu.Conf., RP/C, SPI, I-D(1987). 15.D.C.Prevorsek, Polymer Liquid Crystals, (A.Ciferri et al. ,eds.) , Academic Press New York ,Chapter 12(1982). 16.L. Mascia, J. Dhillon and J. F. Harper, Journal of Applied Polymer Science, 47, 487 (1993). 17.M. S. Silverstein, O. Breuer and H. Dodiuk, Journal of Applied Polymer Science, 52,1785(1994). 18. M. S. Silverstein, J.Sadovsky, D. Alon and V.Wahad, Journal of Applied Polymer Science, 72,405(1999). 19.陳自力, 應用紡織品, 4,7(1998). 20.陳自力, 應用紡織品, 4,10(1998). 21.張宇峰, 合成紡織工藝, 18,24(1995). 22.Tohru Yoshikawa, Shigeru Machida, Takaaki Ikegami,Anuntasin Techagumpuch and Seizo Miyata,Polymer Journal, 22,1(1990). 23.Hsien-Tang Chiu and Jeng-Shyong Lin, Journal of Materials Science, 27,319(1992). 24.A.A.Cenna, S. Allen, N.W.Page and P. Dastoor, Wear, 254,581(2003). 25.Sung In Moon and Jyongsik Jang, “Composites Science and Technology”, 59(1999)487. 26.M. S. Silverstein, O. Breuer, Composites Science and Technology, 48,151(1993). 27.M. S. Silverstein and J. Sadovsky, J. Adhesion Sci. Technol, 9,1193(1995). 28. You-Lo Hsieh, Shanqing Xu and Michelle Hartzell, “J. Adhesion Sci. Technol” , 5,1023(1991). 29. Jpn, Kokai Tokyo Koho, Jp 58,206,579. 30. M. Munro, “Review of Manufacturing of Fiber Composite Components by Filament Winding”, Polymer Composites, Vol.9, Ho.5, pp.352-359 (1988). 31. D.V. Rosato, Encyclopedia of Polymer Science, Vol.6,pp.713-740, Interscience Company,NewYork,N.K. (1964). 32. A.M. Shibley, Handbook of Fiberglass and advanced Plastics Composites, McGrav-Hill Company, New York,N.K. Chap.18, 1969. 33. Ashok K. Munjal, “Use of Filament Winding in Manufa-cturing High Quality Aerospace Composite Components”, 31st Internatianal SAHPE Symposium, Spril 7-10, pp.1504-1518 (1986). 34. 江金龍, “熱塑性聚胺基甲酸脂預浸材料加工方法及性質研究”, 國立清華大學化學工程研究所碩士論文(1990). 35. Edward J.Morrisey, “Fire Retardant Epoxy Systems for the Vet Filament Winding Process”, 24th Annual Technical Conference, RP/C, 16-F-1-6, SPI (1969). 36. Dauksys, R.J., Pagano, N.J., and Spain, R.G., “Grap-hite Fiber/Epoxy Resin Matrix Composites”, 12th National SAMPE Symposium, Anaheim, Calf., October,AC-9 (1967) 37.Davis, J.G., Jr., and Zerder, G.V., “Mechanical Behavior of Composites”, ibid, AC-10. 38. T.R. Bolt, LD. Valford, “Model Filament Uound Epoxy Composites”, Plastics & Polymers, April, pp.79-83,(1973). 39. Stan Lehmann, “Recent Resin Developments for Filament Winding”, 28th National SAMPE Symposium, April 12-14, pp. 347-358 (1983). 40. Manoj K. Gupta and Timothy A. Meterko, “Phenol ics-Fro Molding Compound To Filament Winding”, Polymer Material Science Engineering, 57, 64-8 (1987). 41. Morton Thiokol, “Composites Tubes Will Launch B-1B Weapons”, Machine Design, p.2,(April 11, 1985). 42.T.P. Murtha, C.C. Ma, A.South, J.H. Walker and D.G. Brady, “High Performance Composites Based on Polyphenylene Sulfide”, 29th National SAMPE Symposium, April 3-5, pp.870-879(1984) 43.A.S.Wood, “The Filament Wound Car Frame and Other Practical Miracles”, Modern Plastics, pp.62-65 (July 1984) . 44.J.F. Kober, “Automated Fiber Placement-Process Creativity”, 30th National SAMPE Symposium, pp.1238-1245 (1985) . 45.M.W. Egerton, M.B. Gruber, “Thermoplastic filament Winding Demonstrating Economics and Properties via In-situ Consolidation”, 33rd International SAMPE Symposium,pp.35-46, March 7-10 (1988). 46. N.Chand, S. Kreuzberger and G. Hinrichsen, Composites, V25,N.O.9, 1994. 47.張文吉，“熱塑性複合材料”，塑膠資訊，NO.13,1997.9. 48.Muzzy, J.D., ASME Sympo. “Manufacturing Science of Composites”, pp.27-93,1988. 49.Iyer, S.R. and Drzal, L.T., “Manufacture of Powder-Impregnated Thermoplastic Compositess”, J.Thermoplastic Comp. Mater., 3. pp.325-355,1990. 50.C.Hepburn, Polyurethane Elastomers, Applied Science Publishers,London and New York , 1982. 51.J.H.Saunders and k.C. Frisch, Polyurethane：Chemistry and Technology Part I. Chemistry, Interscience Publishers, New York ,1977. 52.J. H.Saunders and k.C. Frisch, Polyurethane：Chemistry and Technology Part II. Chemistry, Interscience Publishers, New York ,1977. 53.D.J. David and H.B. Staley, Analytical Chemistry of The Polyurethanes Patr III, Wiley-Interscience, New York , 1969. 54.S.L. Cooper, et. al. , Polym. Mater. Sci. Eng. , 49, p.53,(1983). 55.G. Oertel, Polyurethane Handbook, Hanser Publishers,NewYork ,1985 56.Breathable Fabrics and Comfort in clothing., J. of coated fabrics., Vol.15 ,NO 10, P.89, 1985. 57.N.S.Schneider and C.S.Paik Sung, Transition behavior and phase segregation in TDI polyurethanes, Polym. Eng. Sci., 17,(2), p.73,(1977). 58.M.V.Pandya, D.D.Seshpande, D.G.Hundiwale, “Thermal behavior of cast polyurethane elastomers”, J. Appl. Polym. Sci.,35,p.1803,(1988). 59.C.S. Schollenberger and Kornelius Dinbergs, Advances in Urethane Sci. and Technol., 3, p.36-65, (1974). 60.C.S. Schollenberger and Kornelius Dinbergs, Advances in Urethane Sci. and Technol., 7, p.1-34, (1974). 61.林志榮, “聚胺脂形狀記憶材料及其機械黏彈模型”, 國立台灣大學材料科學與工程學研究所博士論文(1997). 62.JIN LIU,1,2 DEZHU MA1., Journal of Applied Polymer Science, Vol. 84, 2206–2215(2002). 63.CHEN-CHI M. MA, CHANG –LUN LEE, MIN-JONG CHANG, and NYAN-HWA TAI., “Effect of Physical Aging on the Toughness of Carbon Fiber-Reinforced Poly(ether ether ketone) and Poly(phenylene sulfide)”, Composites, V13, NO.6, 1992. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/24345 | - |
| dc.description.abstract | 本研究引入熱塑性聚胺基甲酸酯及低密度聚乙烯為基材，並以深具市場潛力的超高分子量聚乙烯纖維為補強材，並分別以溶液含浸法及總體含浸法對不同的樹脂系統加工，利用纏繞成型法將原料加工成預浸材料，再以熱壓成型法二次加工後，製成複合材料，並對其熱性質、纖維重量分率、機械性質、形態學分析討論。
熱性質方面，以LDPE為基材的複合材料其熱烈解溫度較高；並可以由TGA圖及DSC圖計算纖維重量分率。 纖維重量分率可由熱洗法、TGA圖、DSC圖分別求得並比較，以求準確性，複合材料纖維重量分率最高可達50%以上。 機械性質可由單層預浸布量測出，最高可達到598MPa；落鎚式耐衝擊測試可達儀器測試高度極限，複材中纖維完全無斷裂現象，展現出優越耐衝擊性質；本研究製成的複合材料性質良好，未來如能商業化，潛力可期。 關鍵字: 超高分子量聚乙烯纖維、低密度聚乙烯、聚胺基甲酸酯、纖維重量分率、機械性質 | zh_TW |
| dc.description.abstract | The aim of this Research is to prepare the LDPE (low density polyethylene), PU (polyurethane) and UHMWPE fiber composites for improving the mechanical properties of the LDPE/UHMWPE fiber and PU/UHMWPE fiber composites. In the matrix, several types of LDPE and PU are employed to improve the adhesion between the UHMWPE fiber and the matrix.
The LDPE/UHMWPE fiber composites and PU/ UHMWPE fiber composites were prepared by filament winding. The types of impregnation were used in different resin types included solution impregnation and bulk impregnation. Fiber weight content could be calculated by TGA analysis, DSC analysis, and solvent etching. The fiber weight content of the composite is more than 50%. The tensile strength could achieve 598MPa. Crack initiation energy, crack propagation energy, and ductility index (D.I=Ep/Ei) of PU/UHMWPE fiber composites could be obtained by falling weight impact test. The thermal properties, mechanical properties, and morphology of the different composites were investigated through the TGA measurement and DSC measurement , Tensile strength test ,Falling weight impact test and the scanning electron microscope(SEM), respectively. Keywords：UHMWPE fiber, LDPE, PU, fiber weight content, falling weight test, and mechanical properties | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T05:22:41Z (GMT). No. of bitstreams: 1 ntu-94-R92549003-1.pdf: 7880806 bytes, checksum: 5ea3391e459b589a9ac8bd0931614bc8 (MD5) Previous issue date: 2005 | en |
| dc.description.tableofcontents | 目錄
摘要………………………………………………………………….…I 英文摘要（Abstract）…………………………………..……... Ⅱ 目錄…...………………………………………………………….....III 表目錄…………………………………………………………………..VI 圖目錄………………………………………………………..……VIII 第一章：緒論……………………………………………………………1 第二章：文獻回顧……..………………………………………………5 2-1超高分子量聚乙烯簡介……………………………………………5 2-2 複合材料纏繞法簡介…...……………………..….…………11 2-3聚胺酯彈性體簡介……………………………………...…...16 2-4研究動機與目的…………..…………….……………………..20 第三章：實驗方法……………………………………………………..22 3-1 實驗藥品…………………………….………………………...22 3-2 實驗儀器………………………...…………………………..25 3-3 實驗流程...…... ...…………….………………………..28 3-3-1基材為LDPE之複合材料製備………..…………………28 3-3-2基材為PU(鏈延長劑為1,4-BD) 之複合材料製備 總體含浸法(bulk impregnation) ……………………….29 3-3-2-1含異氰酸酯基之聚胺酯預聚物合成……..…….…….29 3-3-2-2製備預浸材料及試片……..…………...…..…….30 3-3-3基材為PU(鏈延長劑為1,4-BD及TMP) 之複合材料製備 總體含浸法(bulk impregnation)……………….……...31 3-3-3-1含異氰酸酯基之聚胺酯預聚物合成………...…….31 3-3-3-2製備預浸材料及試片…………………...…..…….32 3-3-4基材為PU(鏈延長劑為1,4-BD) 之複合材料製備 溶液含浸法(soultion impregnation)………………………..33 3-3-4-1含異氰酸酯基之聚胺酯預聚物合成………….…….33 3-3-4-2製備預浸材料及試片…………………...…..…….35 3-4 實驗步驟………………………………….……………………36 3-4-1基材為LDPE之複合材料製備………………………….36 3-4-2基材為PU(鏈延長劑為1,4-BD) 之複合材料製備 總體含浸法(bulk impregnation)………………………..37 3-4-3基材為PU(鏈延長劑為1,4-BD及TMP) 之複合材料製備 總體含浸法(bulk impregnation)………………………..38 3-4-2基材為PU(鏈延長劑為1,4-BD) 之複合材料製備 溶液含浸法(solution impregnation)………………....39 3-5 性質分析……………………………….………….……..……41 3-5-1凝膠滲透色層分析儀分析….……………….…………..41 3-5-2 微差熱分析掃描卡計儀分析……………..……………..41 3-5-3 熱重量損失儀分析……………………………………….42 3-5-4拉伸性質分析……………….………..…………………..42 3-5-5落鎚式耐衝擊試驗分析……..……..…………………..42 3-5-6掃描式電子顯微鏡分析………...…..…………………..43 第四章：結果與討論…………………………………………………49 4-1 PU-prepolymer鑑定分析(FTIR).………………….……..49 4-2熱裂解溫度(TGA)分析..………….…….…….……..……….49 4-3微差掃瞄卡計儀(DSC)分析……...………….62 4-4纖維重量分率分析………………………………...………….68 4-5機械性質分析..…………….……….…….……..………….73 4-5-1抗張強度分析……………..………………………….…..73 4-5-2落鎚式耐衝擊試驗分析..…………………………….…..76 4-6形態學分析..…………….……….…….………..………….79 4-7聚胺酯分子量分析(GPC)….……….…….………..………….79 第五章：結論…………………………………………………81 第六章：參考文獻……….….………………………………………83 | |
| dc.language.iso | zh-TW | |
| dc.title | 熱塑性超高分子量聚乙烯纖維複合材料之研究 | zh_TW |
| dc.title | Studies on thermalplastic ultra high molecular weight polyethylene fiber composites | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 93-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李雅榮,韓錦鈴,王怡仁 | |
| dc.subject.keyword | 超高分子量聚乙烯纖維,低密度聚乙烯,聚胺基甲酸酯,纖維重量分率,機械性質, | zh_TW |
| dc.subject.keyword | UHMWPE fiber,LDPE,PU,fiber weight content,falling weight test,and mechanical properties, | en |
| dc.relation.page | 105 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2005-07-26 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-94-1.pdf 目前未授權公開取用 | 7.7 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。