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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 徐治平 | |
dc.contributor.author | Shu-Tuan Yang | en |
dc.contributor.author | 楊淑端 | zh_TW |
dc.date.accessioned | 2021-05-13T06:40:10Z | - |
dc.date.available | 2018-07-31 | |
dc.date.available | 2021-05-13T06:40:10Z | - |
dc.date.copyright | 2017-07-31 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-07-27 | |
dc.identifier.citation | 1. Sa, N. Y.; Lan, W. J.; Shi, W. Q.; Baker, L. A., Rectification of Ion Current in Nanopipettes by External Substrates. Acs Nano 2013, 7, 11272-11282.
2. Haywood, D. G.; Saha-Shah, A.; Baker, L. A.; Jacobson, S. C., Fundamental Studies of Nanofluidics: Nanopores, Nanochannels, and Nanopipets. Anal Chem 2015, 87, 172-187. 3. Mei, L. J.; Yeh, L. H.; Qian, S. Z., Gate Modulation of Proton Transport in a Nanopore. Phys Chem Chem Phys 2016, 18, 7449-7458. 4. Mei, L. J.; Yeh, L. H.; Qian, S. Z., Buffer Effect on the Ionic Conductance in a pH-Regulated Nanochannel. Electrochem Commun 2015, 51, 129-132. 5. Gao, J.; Guo, W.; Feng, D.; Wang, H. T.; Zhao, D. Y.; Jiang, L., High-Performance Ionic Diode Membrane for Salinity Gradient Power Generation. J Am Chem Soc 2014, 136, 12265-12272. 6. Xiao, K.; Xie, G. H.; Li, P.; Liu, Q.; Hou, G. L.; Zhang, Z.; Ma, J.; Tian, Y.; Wen, L. P.; Jiang, L., A Biomimetic Multi-Stimuli-Response Ionic Gate Using a Hydroxypyrene Derivation-Functionalized Asymmetric Single Nanochannel. Adv Mater 2014, 26, 6560-6565. 7. Liu, Q.; Xiao, K.; Wen, L. P.; Lu, H.; Liu, Y. H.; Kong, X. Y.; Xie, G. H.; Zhang, Z.; Bo, Z. S.; Jiang, L., Engineered Ionic Gates for Ion Conduction Based on Sodium and Potassium Activated Nanochannels. J Am Chem Soc 2015, 137, 11976-11983. 8. Zhang, H. C.; Hou, X.; Hou, J.; Zeng, L.; Tian, Y.; Li, L.; Jiang, L., Synthetic Asymmetric-Shaped Nanodevices with Symmetric pH-Gating Characteristics. Adv Funct Mater 2015, 25, 1102-1110. 9. Qiu, Y.; Vlassiouk, I.; Chen, Y.; Siwy, Z. S., Direction Dependence of Resistive-Pulse Amplitude in Conically Shaped Mesopores. Anal Chem 2016, 88, 4917-25. 10. Plett, T.; Shi, W. Q.; Zeng, Y. H.; Mann, W.; Vlassiouk, I.; Baker, L. A.; Siwy, Z. S., Rectification of Nanopores in Aprotic Solvents - Transport Properties of Nanopores with Surface Dipoles. Nanoscale 2015, 7, 19080-19091. 11. Venkatesan, B. M.; Bashir, R., Nanopore Sensors for Nucleic Acid Analysis. Nat Nanotechnol 2011, 6, 615-624. 12. Kowalczyk, S. W.; Wells, D. B.; Aksimentiev, A.; Dekker, C., Slowing Down DNA Translocation through a Nanopore in Lithium Chloride. Nano Lett 2012, 12, 1038-1044. 13. Steinbock, L. J.; Lucas, A.; Otto, O.; Keyser, U. F., Voltage-Driven Transport of Ions and DNA through Nanocapillaries. Electrophoresis 2012, 33, 3480-3487. 14. Lan, W. J.; Kubeil, C.; Xiong, J. W.; Bund, A.; White, H. S., Effect of Surface Charge on the Resistive Pulse Waveshape During Particle Translocation through Glass Nanopores. J Phys Chem C 2014, 118, 2726-2734. 15. Bell, N. A. W.; Keyser, U. F., Specific Protein Detection Using Designed DNA Carriers and Nanopores. J Am Chem Soc 2015, 137, 2035-2041. 16. Lan, W. J.; Holden, D. A.; White, H. S., Pressure-Dependent Ion Current Rectification in Conical-Shaped Glass Nanopores. J Am Chem Soc 2011, 133, 13300-13303. 17. Perera, R. T.; Johnson, R. P.; Edwards, M. A.; White, H. S., Effect of the Electric Double Layer on the Activation Energy of Ion Transport in Conical Nanopores. J Phys Chem C 2015, 119, 24299-24306. 18. Qiu, Y.; Lin, C. Y.; Hinkle, P.; Plett, T. S.; Yang, C.; Chacko, J. 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Z., Polarization Effect of a Dielectric Membrane on the Ionic Current Rectification in a Conical Nanopore. J Phys Chem C 2011, 115, 24951-24959. 3. Lin, D. H.; Lin, C. Y.; Tseng, S.; Hsu, J. P., Influence of Electroosmotic Flow on the Ionic Current Rectification in a Ph-Regulated, Conical Nanopore. Nanoscale 2015, 7, 14023-14031. 4. Lin, C. Y.; Yeh, L. H.; Hsu, J. P.; Tseng, S., Regulating Current Rectification and Nanoparticle Transport through a Salt Gradient in Bipolar Nanopores. Small 2015, 11, 4594-4602. 5. Sparreboom, W.; van den Berg, A.; Eijkel, J. C. T., Principles and Applications of Nanofluidic Transport. Nat Nanotechnol 2009, 4, 713-720. 6. He, Y.; Gillespie, D.; Boda, D.; Vlassiouk, I.; Eisenberg, R. S.; Siwy, Z. S., Tuning Transport Properties of Nanofluidic Devices with Local Charge Inversion. J Am Chem Soc 2009, 131, 5194-5202. 7. Guo, W., et al., Current Rectification in Temperature-Responsive Single Nanopores. Chemphyschem 2010, 11, 859-864. 8. 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J Phys D Appl Phys 2007, 40, 7077-7084. 13. Kubeil, C.; Bund, A., The Role of Nanopore Geometry for the Rectification of Ionic Currents. J Phys Chem C 2011, 115, 7866-7873. 14. Cervera, J.; Ramirez, P.; Mafe, S.; Stroeve, P., Asymmetric Nanopore Rectification for Ion Pumping, Electrical Power Generation, and Information Processing Applications. Electrochim Acta 2011, 56, 4504-4511. 15. Wang, J. T.; Zhang, M. H.; Zhai, J.; Jiang, L., Theoretical Simulation of the Ion Current Rectification (Icr) in Nano-Pores Based on the Poisson-Nernst-Planck (Pnp) Model. Phys Chem Chem Phys 2014, 16, 23-32. 16. Daiguji, H.; Yang, P. D.; Majumdar, A., Ion Transport in Nanofluidic Channels. Nano Lett 2004, 4, 137-142. 17. Ai, Y.; Zhang, M. K.; Joo, S. W.; Cheney, M. A.; Qian, S. Z., Effects of Electroosmotic Flow on Ionic Current Rectification in Conical Nanopores. J Phys Chem C 2010, 114, 3883-3890. 18. 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P.; Wang, S. T.; Tian, Y.; Jiang, L., A Bio-Inspired Potassium and Ph Responsive Double-Gated Nanochannel. Adv Funct Mater 2015, 25, 421-426. 35. Zeng, Z. P.; Ai, Y.; Qian, S. Z., Ph-Regulated Ionic Current Rectification in Conical Nanopores Functionalized with Polyelectrolyte Brushes. Phys Chem Chem Phys 2014, 16, 2465-2474. 36. Lin, J. Y.; Lin, C. Y.; Hsu, J. P.; Tseng, S., Ionic Current Rectification in a Ph-Tunable Polyelectrolyte Brushes Functionalized Conical Nanopore: Effect of Salt Gradient. Anal Chem 2016, 88, 1176-1187. 37. Zeng, Z. P.; Yeh, L. H.; Zhang, M. K.; Qian, S. Z., Ion Transport and Selectivity in Biomimetic Nanopores with Ph-Tunable Zwitterionic Polyelectrolyte Brushes. Nanoscale 2015, 7, 17020-17029. 38. Dudev, T.; Lim, C., Factors Governing the Na+ Vs K+ Selectivity in Sodium Ion Channels. J Am Chem Soc 2010, 132, 2321-2332. 39. Vlassiouk, I.; Smirnov, S.; Siwy, Z., Ionic Selectivity of Single Nanochannels. Nano Lett 2008, 8, 1978-1985. 40. Yeh, L. H.; Hughes, C.; Zeng, Z. P.; Qian, S. Z., Tuning Ion Transport and Selectivity by a Salt Gradient in a Charged Nanopore. Anal Chem 2014, 86, 2681-2686. 41. Tagliazucchi, M.; Rabin, Y.; Szleifer, I., Ion Transport and Molecular Organization Are Coupled in Polyelectrolyte-Modified Nanopores. J Am Chem Soc 2011, 133, 17753-17763. 42. Duval, J. F. L.; Gaboriaud, F., Progress in Electrohydrodynamics of Soft Microbial Particle Interphases. Curr Opin Colloid In 2010, 15, 184-195. 43. Ma, Y.; Xue, S.; Hsu, S. C.; Yeh, L. H.; Qian, S. Z.; Tan, H. P., Programmable Ionic Conductance in a Ph-Regulated Gated Nanochannel. Phys Chem Chem Phys 2014, 16, 20138-20146. 1. Liu, J.; Kvetny, M.; Feng, J.; Wang, D.; Wu, B.; Brown, W.; Wang, G., Surface Charge Density Determination of Single Conical Nanopores Based on Normalized Ion Current Rectification. Langmuir 2012, 28, 1588-95. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/2433 | - |
dc.description.abstract | 圓錐奈米孔道有不對稱的幾何形狀,加上若孔道開口與電雙層厚度相當時,會引起許多特別的電動力學現象,像是離子電流整流效應(ICR)。首先我們考慮不同電解質溶液LiCl、NaCl、KCl,並研究電滲透流(EOF)對整流效應的影響。我們發現有無考慮電滲透流對整流效應係數(Rf)的程度有很大的影響。如果沒有考慮電滲透流,LiCl水溶液在不同外加電壓下的整流效果是三者中最好的。若考慮電滲透流,則不同溶液的整流效果與外加電壓大小相關。
接著,我們討論一合成圓錐狀奈米孔道,其表面塗佈一層pH可調節之聚電解質。考慮在外加電場下,溶液酸鹼值pH、溶液鹽濃度、施加電壓不同對離子傳輸行為及離子選擇性之影響。我們發現溶液導電度會因pH、溶液鹽濃度不同有很大的影響,而離子選擇性則同時受pH、溶液鹽濃度及施加電壓的影響。 | zh_TW |
dc.description.abstract | The influence of electroosmotic flow (EOF) on the behavior of the ionic current rectification (ICR) in a conical nanopore connecting two large identical reservoirs is investigated. In particular, the effect of the type of salt is examined by considering LiCl, NaCl, and KCl. We show that neglecting EOF is capable of influencing ICR both quantitatively and qualitatively. If EOF is neglected, the rectification factor at each level of the applied electric potential bias across the two reservoirs for the case of LiCl (KCl) is always the largest (smallest). However, if EOF is taken into account, the relative magnitude of the rectification factors for various salts depends upon the level of the applied electric potential bias. This behavior is consistent with the experimental observation in the literature and can be explained by the degree of ion enrichment / depletion in a nanopore.
Furthermore, the behaviors of the nanopore conductance and ion selectivity of a conical nanopore surface modified by a polyelectrolyte (PE) layer are studied by adjusting the pH, the bulk salt concentration, and the level of an applied potential bias, and the underlying mechanisms investigated in detail. We show that the conductance is sensitive to the variation in the solution pH, and the conical nanopore has ion current rectification (ICR) behavior. The ion selectivity of the nanopore is influenced significantly by both the solution pH and the level of the applied potential bias. We show that the transport behavior of ions can be tuned easily by adjusting the level of pH, salt concentration, and applied potential bias, thereby providing useful information for future designing of conical nanopores. | en |
dc.description.provenance | Made available in DSpace on 2021-05-13T06:40:10Z (GMT). No. of bitstreams: 1 ntu-106-R04524038-1.pdf: 1913439 bytes, checksum: 1d92e0b5b8c475acfe6a5ec3f170ab13 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 中文摘要…………………………………………………………………...…………….I
ABSTRACT……………………………………….…………………………………….II TABLE OF CONTENTS…………………………………………...……………….….IV LIST OF FIGURES…………………………………………………………...…………V LIST OF TABLES………………….……………………………………………….….IX CHAPTER 1: Effect of type of salts ...……..…………………………....……………... 1 References……………………………………………………………………………...14 CHAPTER 2: Effect of polyelectrolyte functionalized surface ……..……………....... 28 References……………………………………………………………………………...46 CHAPTER 3: Conclusions…………...…………………...………………………….... 63 APPENDIX A…………..………………………………………………………….... 65 Reference…………………………………………………………………………….....69 | |
dc.language.iso | en | |
dc.title | 錐狀奈米孔道內離子種類及聚電解質改質表面對離子傳輸行為之影響 | zh_TW |
dc.title | Ion Transport Properties in Conical Nanopores: Effect of Type of Salts and Polyelectrolyte Brushes Functionalized Surface | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 曾琇瑱,張有義,葉禮賢,郭勇志 | |
dc.subject.keyword | 圓錐狀奈米孔道,離子電流整流效應,電滲透流,離子種類,電荷可調節之聚電解質層,電雙層, | zh_TW |
dc.subject.keyword | conical nanopore,ion current rectification,electroosmotic flow,type of salts,pH-tunable polyelectrolyte brushes,electric double layer, | en |
dc.relation.page | 69 | |
dc.identifier.doi | 10.6342/NTU201701156 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2017-07-28 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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