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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 劉如熹(Ru-Shi Liu) | |
dc.contributor.author | Hong-Chang Wong | en |
dc.contributor.author | 翁弘昌 | zh_TW |
dc.date.accessioned | 2021-06-08T05:10:52Z | - |
dc.date.copyright | 2011-07-25 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-07-07 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/23839 | - |
dc.description.abstract | 科技日新月異進步,人們對於電子類產品依賴漸漸增加。儲能電池角色為極其重要之一環,著眼於單位體積/重量上儲存之能量密度、功率密度與穩定性,可撓式全固態薄膜鋰離子二次電池被視為具發展潛力指標。此電池具可彎曲、無電解液滲漏、輕量化、壽命長等特性。此應用範圍包括生物機電系統、智慧卡、實驗室晶片、醫學晶
片等。 本研究主要為製作與分析可撓式全固態二次鋰離子電池與新穎氮化釩 (VN) 陽極材料,先以射頻 (RF) 磁控濺鍍陰極鋰鈷氧於具白金薄膜之雲母片上,再濺鍍固態電解質LiPON與以直流 (DC) 磁控濺鍍陽極氮化釩,最終以直流濺鍍鉑金屬作為電流收集器。並以第一 原理計算氮化物之物理特性 (軌域電子能階資訊)。 本研究將探討不同濺鍍條件 (濺鍍功率、濺鍍氣體壓力與濺鍍氣體分率) 與快速退火條件 (退火溫度與退火時間) 對於薄膜組成與結構影響,以X光繞射與電子顯微鏡分別檢測晶體結構與薄膜表面型態,且藉由X光吸收光譜分析薄膜之電子結構。以電化學方面以循環伏安法得知不同電壓下其反應機構,利用交流阻抗測試計算導電度 並另進行電容量測試。 | zh_TW |
dc.description.abstract | Lithium ion batteries (LIBs) are recognized as new power supplier because of their high energy density, long cycle life, high voltage and safety. With the growth of microelectronic devices, the development of flexible all solid-state thin film batteries (TFBs) is quite important. TFBs has no potentially leak electrolyte which can improve the cycle life significantly and can be integrated into lab-on-chip based devices or smart cards.
The purpose of this research is to fabricate the TFBs with the novel vanadium nitride (VN) anode material, lithium phosphorus oxynitride (LiPON) solid electrolyte and lithium cobalt oxide (LiCoO2). The different sputtering parameters were revealed to improve the electrochemical properties of materials and the electronic structure of VN were demonstrated by density functional theory (DFT) which based on first principle calculation. Mica was selected as the substrate due to their flexible, lightweight and excellent chemical stability. The crystal structure and morphology were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The ion conductivity of LiPON was calculated by performing the electrochemical impedance spectroscopy (EIS). The X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) were used to approach the electronic structure of VN. We utilize the cyclic voltammetry (CV) and capacity tester to estimate the electrochemical performance of active materials. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T05:10:52Z (GMT). No. of bitstreams: 1 ntu-100-R98223111-1.pdf: 6276294 bytes, checksum: 3a97866e9f10090b9afb120179cc9f39 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 總目錄.....................................................I
圖目錄....................................................VI 表目錄..................................................XIII 第一章 緒論 .............................................. 1 1.1 鋰離子二次電池運作機制與結構.......................... 2 1.2 電極與電解質之能帶結構 (Band Structure)............... 4 1.3 電解液與固態電解質介面 (Solid Electrolyte Interface, SEI)...................................................... 6 1.4 常用陰、陽極材料電位與電解液操作分布圖................ 7 1.4.1 陰極材料-鋰鈷氧化物 (LiCoO2)........................ 8 1.4.2 陰極材料-鋰錳氧化物 (LiMn2O4)....................... 9 1.4.3 陰極材料-鋰鎳氧化物 (LiNiO2)....................... 10 1.4.4 陰極材料-磷酸鋰鐵 (LiFePO4)........................ 11 1.4.5 陽極材料-石墨碳材.................................. 14 1.4.6 陽極材料-金屬氧化物................................ 15 1.4.7 陽極材料-鋰合金.................................... 17 1.4.8 陽極材料-金屬氮化物................................ 18 1.5 第一原理理論計算 (First Principle Calculation)....... 20 1.5.1 絕熱近似 (Adiabatic Approximation)................. 20 1.5.2 Hartre 近似 (Hartree Approximation)................ 20 1.5.3 Hartree-Fork 自洽場近似 (Hartree-Fork Approximation).. ......................................................... 21 1.5.4 密度泛函理論 (Density Functional Theory) ......................................................... 22 1.5.5 廣義梯度近似法 (Generalized Gradient Approximation, GGA) .................................................... 24 1.5.6 布里淵區與態密度 (Brillouin Zone and Density of State) ......................................................... 25 1.6 全固態薄膜電池文獻回顧............................... 29 1.6.1 LiCoO2 陰極薄膜.................................... 35 1.6.2 LiPON 電解質薄膜................................... 37 1.6.3 VN 陽極薄膜........................................ 40 1.7 薄膜電池文獻回顧..................................... 41 1.8 本研究動機與新穎性................................... 45 第二章 實驗步驟與儀器分析原理............................ 46 2.1 化學藥品與部件....................................... 46 2.2 基材處理............................................. 47 2.3 濺鍍機台............................................. 48 2.4 電漿濺鍍原理......................................... 49 2.5 磁控濺鍍 (Magnetron Sputtering Deposition)........... 50 2.6 射頻與直流濺鍍 (RF & DC Sputtering Deposition)....... 51 2.6.1 LiCoO2 薄膜濺鍍.................................... 51 2.6.2 LiPON 薄膜濺鍍..................................... 52 2.6.3 VN 薄膜濺鍍........................................ 53 2.7 鈕釦電池組裝程序..................................... 54 2.8 可撓式全固態鋰離子二次電池組裝程序................... 55 2.9 薄膜鑑定與分析....................................... 57 2.9.1 X 光繞射儀 (X-ray Diffractometer, XRD )............ 57 2.9.2 X 射線光電子能譜儀 (X-ray Photoelectron Spectroscopy, XPS ).................................................... 60 2.9.3 掃描式電子顯微鏡 (Scanning Electron Microscope, SEM ).................................................... 61 2.9.4 X 光吸收光譜 (X-ray Absorption Spectroscopy, XAS ). 62 2.9.5 表面輪廓儀 (Alpha step, α-step ).................. 63 2.9.6 電化學交流阻抗光譜法 (Electrochemical impedance spectroscopy, EIS )...................................... 63 2.9.7 循環伏安法 (Cyclic Voltammetry, CV )............... 64 2.9.8 充放電測試 (Capacity test)......................... 65 第三章 結果與討論........................................ 66 3.1 LiCoO2 薄膜特性分析.................................. 66 3.1.1 LiCoO2 濺鍍氬氣分率於濺鍍速率影響測試.............. 66 3.1.2 LiCoO2 濺鍍氬氣分率於晶格結構影響測試.............. 67 3.1.3 快速退火溫度與時間於LiCoO2 晶格結構影響測試.........69 3.1.3.1 快速退火時間於LiCoO2 薄膜表面形態影響測試.........71 3.1.3.2 濺鍍氣體分率與退火時間於LiCoO2 薄膜電子結構試.... 74 3.1.3.3 快速退火時間於LiCoO2 薄膜電容量影響測試.......... 77 3.2 LiPON 薄膜分析....................................... 81 3.2.1 濺鍍功率於LiPON 薄膜鍍率影響測試................... 81 3.2.2 濺鍍功率於LiPON 薄膜晶格結構影響測試............... 82 3.2.3 濺鍍功率於LiPON 薄膜氮化學鍵結影響測試..............83 3.2.4 LiPON 薄膜離子導電度與活化能測試................... 87 3.2.4 LiPON 薄膜之表面形貌測試........................... 92 3.3 VN 薄膜分析.......................................... 93 3.3.1 濺鍍功率於VN 晶格結構影響.......................... 93 3.3.2 濺鍍氣體壓力於VN 晶格結構影響...................... 93 3.3.2.1 濺鍍氣體壓力於VN 薄膜化學鍵結影響測試............ 97 3.3.3 濺鍍基板溫度於VN 晶格結構影響..................... 102 3.3.4 快速退火溫度與時間於VN 晶格結構影響............... 103 3.3.4.1 快速退火溫度與時間於VN 薄膜化學鍵結影響測試..... 105 3.3.5 VN 薄膜之表面形貌測試............................. 107 3.3.6 能帶計算 (Band Structure)......................... 109 3.3.7 濺鍍氣體壓力於VN 薄膜電子結構測試................. 111 3.3.7.1 濺鍍氣體壓力於VN 薄膜交流阻抗影響............... 113 3.3.7.2 VN 薄膜之循環伏安儀測試......................... 115 3.3.7.3 濺鍍氣體壓力於VN 薄膜電容量影響................. 116 第四章 結論............................................. 119 參考文獻................................................ 120 | |
dc.language.iso | zh-TW | |
dc.title | 可撓式全固態鋰離子二次電池製作及其特性分析 | zh_TW |
dc.title | Fabrication and Investigation of Flexible Solid State Lithium Ion Battery | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 鄭淑芬(Soo-Fin Cheng),張家欽(Chia-Chin Chang),施得旭(Der-Shiuh Shy),何麗貞(Li-Jane Her) | |
dc.subject.keyword | 薄膜電池,氮化釩,X光吸收光譜,阻抗分析,循環伏安法, | zh_TW |
dc.subject.keyword | TFBs,VN,XAS,AC Impedance,CV, | en |
dc.relation.page | 126 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2011-07-07 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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