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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 蘇南維 | |
dc.contributor.author | Wei-Ju Lee | en |
dc.contributor.author | 李偉如 | zh_TW |
dc.date.accessioned | 2021-06-08T05:10:34Z | - |
dc.date.copyright | 2011-08-23 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-19 | |
dc.identifier.citation | Adlercreutz, H., Mousavi, Y., Clark, J., Hockerstedt, K., Hamalainen, E., Wahala, K., Makela, T., & Hase, T. (1992). Dietary Phytoestrogens and Cancer - Invitro and Invivo Studies. Journal of Steroid Biochemistry and Molecular Biology, 41(3-8), 331-337.
Andrikopoulos, N. K. (2002). Chromatographic and spectroscopic methods in the analysis of triacylglycerol species and regiospecific isomers of oils and fats. Crit Rev Food Sci Nutr, 42(5), 473-505. Brezmes, J., Llobet, E., Vilanova, X., Saiz, G., & Correig, X. (2000). Fruit ripeness monitoring using an Electronic Nose. Sensors and Actuators B-Chemical, 69(3), 223-229. Brouns, F. (2002). Soya isoflavones: a new and promising ingredient for the health foods sector. Food Research International, 35(2-3), 187-193. Buchgraber, M., Ulberth, F., & Anklam, E. (2004). Method validation for detection and quantification of cocoa butter equivalents in cocoa butter and plain chocolate. Journal of Aoac International, 87(5), 1164-1172. Buchgraber, M., Ullberth, F., Emons, H., & Anklam, E. (2004). Triacylglycerol profiling by using chromatographic techniques. European Journal of Lipid Science and Technology, 106(9), 621-648. Christie, W. W. (1992). In advances in lipid methodology. Ayr, UK: The Oily Press, 239-271. Cserhati, T., Forgacs, E., Deyl, Z., & Miksik, I. (2005). Chromatography in authenticity and traceability tests of vegetable oils and dairy products: a review. Biomed Chromatogr, 19(3), 183-190. Cunha, S. C., & Oliveira, M. B. P. P. (2006). Discrimination of vegetable oils by triacylglycerols evaluation of profile using HPLC/ELSD. Food Chemistry, 95(3), 518-524. Gan, H. L., Man, Y. B. C., Tan, C. P., NorAini, I., & Nazimah, S. A. H. (2005). Characterisation of vegetable oils by surface acoustic wave sensing electronic nose. Food Chemistry, 89(4), 507-518. Guadarrama, A., Rodriguez-Mendez, M. L., Sanz, C., Rios, J. L., & de Saja, J. A. (2001). Electronic nose based on conducting polymers for the quality control of the olive oil aroma - Discrimination of quality, variety of olive and geographic origin. Analytica Chimica Acta, 432(2), 283-292. Hai, Z., & Wang, J. (2006). Detection of adulteration in camellia seed oil and sesame oil using an electronic nose. European Journal of Lipid Science and Technology, 108(2), 116-124. Hansen, T., Petersen, M. A., & Byrne, D. V. (2005). Sensory based quality control utilising an electronic nose and GC-MS analyses to predict end-product quality from raw materials. Meat Science, 69(4), 621-634. Hirose, N., Inoue, T., Nishihara, K., Sugano, M., Akimoto, K., Shimizu, S., & Yamada, H. (1991). Inhibition of Cholesterol Absorption and Synthesis in Rats by Sesamin. Journal of Lipid Research, 32(4), 629-638. Jakab, A., Heberger, K., & Forgacs, E. (2002). Comparative analysis of different plant oils by high-performance liquid chromatography-atmospheric pressure chemical ionization mass spectrometry. J Chromatogr A, 976(1-2), 255-263. Kamm, W., Dionisi, F., Hischenhuber, C., & Engel, K. H. (2001). Authenticity assessment of fats and oils. Food Reviews International, 17(3), 249-290. Kapadia, G. J., Azuine, M. A., Tokuda, H., Takasaki, M., Mukainaka, T., Konoshima, T., & Nishino, H. (2002). Chemopreventive effect of resveratrol, sesamol, sesame oil and sunflower oil in the Epstein-Barr virus early antigen activation assay and the mouse skin two-stage carcinogenesis. Pharmacological Research, 45(6), 499-505. Koropchak, J. A., Magnusson, L. E., Heybroek, M., Sadain, S., Yang, X. H., & Anisimov, M. P. (2000). Fundamental aspects of aerosol-based light-scattering detectors for separations. Advances in Chromatography, Vol 40, 40, 275-314. Lee, D. S., Lee, E. S., Kim, H. J., Kim, S. O., & Kim, K. (2001). Reversed phase liquid chromatographic determination of triacylglycerol composition in sesame oils and the chemometric detection of adulteration. Analytica Chimica Acta, 429(2), 321-330. Lee, J. S., Kim, J., Yu, Y. U., & Kim, Y. C. (2004). Inhibition of phospholipase C gamma 1 and cancer cell proliferation by lignans and flavans from Machilus thunbergii. Archives of Pharmacal Research, 27(10), 1043-1047. Letter, W. S. (1993). A Qualitative Method for Triglyceride Analysis by Hplc Using an Evaporative Light-Scattering Detector. Journal of Liquid Chromatography, 16(1), 225-239. Lipp, M. (1995). Review of Methods for the Analysis of Triglycerides in Milk-Fat - Application for Studies of Milk Quality and Adulteration. Food Chemistry, 54(2), 213-221. Liu, K. S. (1999). Soybeans. Aspen publishers. Loynes, R. M. (1980). Methods for Statistical-Data Analysis of Multivariate Observations - Gnanadesikan,R. International Statistical Review, 48(2), 237-237. Messina, M., & Barnes, S. (1991). The role of soy products in reducing risk of cancer. J Natl Cancer Inst, 83(8), 541-546. Namiki, M. (1995). The Chemistry and Physiological Functions of Sesame. Food Reviews International, 11(2), 281-329. Nikolova-Damyanova, B., Velikova, R. & Kuleva, L. (2002). Quantitative TLC for determination of the triacylglycerol composition of sesame seeds. Journal of Liquid Chromatography & Related Technologies, 25(10-11), 1623-1632. Noh, M. J., Jeong, J. I., Min, S. S., Park, Y. S., & Kim, S. J. (2004). A study on the determination of adulteration of sesame oil by near infrared spectroscopy. Korean Journal of Food Science Technology, 36, 527–530. Ollivier, D. (2003). Determination of virgin vegetable adulteration: application to the quality of virgin oils, particularly virgin olive oil. Ocl-Oleagineux Corps Gras Lipides, 10(4), 315-320. Olsson, J., Borjesson, T., Lundstedt, T., & Schnurer, J. (2002). Detection and quantification of ochratoxin A and deoxynivalenol in barley grains by GC-MS and electronic nose. International Journal of Food Microbiology, 72(3), 203-214. Onken, J., & Berger, R. G. (1998). Evaporative light scattering detector (ELSD) for the analysis in food chemistry. Deutsche Lebensmittel-Rundschau, 94(9), 287-292. Parcerisa, J., Boatella, J., Codony, R., Rafecas, M., Castellote, A. I., Garcia, J., Lopez, A., & Romero, A. (1995). Comparison of Fatty-Acid and Triacylglycerol Compositions of Different Hazelnut Varieties (Corylus-Avellana L) Cultivated in Catalonia (Spain). Journal of Agricultural and Food Chemistry, 43(1), 13-16. Park, Y. W., Chang, P. S., & Lee, J. (2010). Application of triacylglycerol and fatty acid analyses to discriminate blended sesame oil with soybean oil. Food Chemistry, 123(2), 377-383. Rencher, A. C., & Larson, S. F. (1980). Bias in Wilks-Lambda in Stepwise Discriminant-Analysis. Technometrics, 22(3), 349-356. Rohman, A., & Man, Y. B. C. (2011). Palm oil analysis in adulterated sesame oil using chromatography and FTIR spectroscopy. European Journal of Lipid Science and Technology, 113(4), 522-527. Rombaut, R., De Clercq, N., Foubert, I., & Dewettinck, K. (2009). Triacylglycerol Analysis of Fats and Oils by Evaporative Light Scattering Detection. Journal of the American Oil Chemists Society, 86(1), 19-25. Saevels, S., Lammertyn, J., Berna, A. Z., Veraverbeke, E. A., Di Natale, C., & Nicolai, B. M. (2004). An electronic nose and a mass spectrometry-based electronic nose for assessing apple quality during shelf life. Postharvest Biology and Technology, 31(1), 9-19. Seo, H. Y., Ha, J., Shin, D. B., Shim, S. L., No, K. M., Kim, K. S., Lee, K. B., & Han, S. B. (2010). Detection of Corn Oil in Adulterated Sesame Oil by Chromatography and Carbon Isotope Analysis. Journal of the American Oil Chemists Society, 87(6), 621-626. Shyu, Y. S., & Hwang, L. S. (2002). Antioxidative activity of the crude extract of lignan glycosides from unroasted Burma black sesame meal. Food Research International, 35(4), 357-365. Stolyhwo, A., Colin, H., Martin, M., & Guiochon, G. (1987). Study of the Qualitative and Quantitative Properties of the Light-Scattering Detector. Abstracts of Papers of the American Chemical Society, 193, 123-123. Tashiro, T., Fukuda, Y., Osawa, T., & Namiki, M. (1990). Oil and Minor Components of Sesame (Sesamum-Indicum L) Strains. Journal of the American Oil Chemists Society, 67(8), 508-511. Tokusoglu, O., Unal, M. K., & Alakir, I. (2004). Proximate chemical composition, amino acid and fatty acid profiles of sesame seed flours. Journal of Food Science and Technology-Mysore, 41(4), 409-412. Ulberth, F., & Buchgraber, M. (2000). Authenticity of fats and oils. European Journal of Lipid Science and Technology, 102(11), 687-694. Van Ruth, S. M., Villegas, B., Akkermans, W., Rozijn, M., van der Kamp, H., & Koot, A. (2010). Prediction of the identity of fats and oils by their fatty acid, triacylglycerol and volatile compositions using PLS-DA. Food Chemistry, 118(4), 948-955. Yoo, Y. C., Chung, H. S., Lim, M. A., Jin, Y. B., Lee, H. S., & Park, Y. S. (1992). Determination of the adulteration of sesame oils sold in markets by gas chromatography. Korean Journal of Food Hygiene, 7, 29-36. Zheng, H., & Jun, W. (2006). Electronic nose and data analysis for detection of maize oil adulteration in sesame oil. Sensors and Actuators B-Chemical, 119(2), 449-455. 沈明來 (1998). 多變量分析. 九州出版社. 張嘉鴻 (1987). 判別分析法於水稻之探討. 碩士論文. 曾富生 (1996). 農藝. 三民書局. 戴蔭方,劉成軍,張超良,曹慶榮及李保真 (1995). 藥用蔬果. 度假出版社. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/23819 | - |
dc.description.abstract | 本研究主要目的是建立芝麻油混摻大豆油或芥花油的定性、定量方法。分兩大部分進行,第一部分,先利用高效液相層析搭配蒸發光散射檢測器(HPLC-ELSD)建立三酸甘油酯分析方法,探討最適條件,再用於分析多種來源之芝麻油、大豆油及芥花油。此外,也分析不同油脂的脂肪酸組成,並比較油脂的脂肪酸組成和三酸甘油酯組成的關係。結果顯示,三酸甘油酯組成較脂肪酸多元且差異度大,大豆油中含有芝麻油所沒有的三酸甘油酯組成,LLnL、OLnL、PLnL,可作為判斷是否有混摻大豆油的指標(key factor),同理,芥花油含有特有的OLnL、OLnO,也可用來判別有無混摻芥花油。第二部分,將芝麻油依比例混摻大豆油或芥花油(0%、10%、20%...100%),同樣分析三酸甘油酯組成。可觀察到混摻比例上升,三酸甘油酯組成含量會隨之有線性變化;在含量較低的波峰的極端值,混摻比例和變量間有微弱的指數關係(sigmoid response),R2仍有超過0.9,而混摻油中較高含量的OLL、OOO作出檢量線較具代表性,R2皆大於0.99,可適用於調和油成分比例的鑑定上。除了單一變量的定性定量方法,我們也將上述結果套用在多變量的統計模式中,利用主成分判別分析(Discriminant analysis of principal components, DAPC),可萃取出兩個變數,將三種植物油正確分群 (錯分率為0)。最後,我們將七種市售芝麻油樣品同樣進行上述分析,發現其中有4種有混摻大豆油,混摻比例保守估計約31-44%。 | zh_TW |
dc.description.abstract | The aim of this study is to develop an analytical approach for discriminating sesame oil blended with soybean oil or canola oil. Firstly we established a promising HPLC-ELSD chromatographic condition for the detection of triacylglycerol (TAG) species of oil samples. TAG species of all oil samples were then determined under the conditions. Based on the composition of TAG species of oil samples, three unique peaks assigned as LLnL, OLnL and PLnL which did not appear on the chromatogram of any sesame oil samples represented that the characteristic components of soybean oil could be employed as judging the adulteration of sesame oil with soybean oil. Similarly, the unique components, OLnL and OLnO of canola oil could be used for judging the adulteration of sesame oil with canola oil. Additionally, a statistical method, namely discriminant analysis of principal components (DAPC), using TAG species of oil sample as parameters was employed for qualitative analysis of sesame oil blended with soybean oil or canola oil. The results showed that this statistical method was feasible and promising to judge the adulteration of sesame oils with soybean oils or canola oils. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T05:10:34Z (GMT). No. of bitstreams: 1 ntu-100-R98623026-1.pdf: 18911289 bytes, checksum: f43e10f40246108cbf817d1b047680ff (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 目錄 I
圖目錄 III 表目錄 V 縮寫表 VI 第一章 前言 1 第二章 文獻整理 3 第一節、混摻與檢測方法 3 1-1 混摻 3 1-2 檢測方法 3 1-3 三酸甘油酯分析方法 16 第二節、食用油介紹 24 2-1 全球食用油生產概況 24 2-2 芝麻油(sesame oil) 26 2-3 大豆油(soybean oil) 29 2-4 芥花油(Canola oil) 32 第三節、統計方法 34 3-1 判別分析 34 3-2 主成分分析 36 第三章 材料與方法 37 第一節、實驗大綱 37 第二節、實驗材料 38 2-1 油脂樣品 38 2-2 藥品與試劑 38 第三節、實驗儀器 40 第四節、實驗方法 41 4-1 油脂萃取 41 4-2 矽膠管柱純化 41 4-3 三酸甘油酯組成分析 41 4-3.1 方法建立 41 4-3.2 樣品分析 42 4-4 脂肪酸組成分析 43 4-5 製備混摻芝麻油 43 4-6 統計分析 43 第四章 結果與討論 44 第一節、建立三酸甘油酯組成分析方法 44 第二節、油脂之脂肪酸及三酸甘油酯組成 54 第三節、芝麻油混摻大豆油或芥花油 62 第四節、市售芝麻油樣品混摻定性定量分析 67 第五節、多變量統計分析應用 69 第五章 結論 72 第六章 參考文獻 73 | |
dc.language.iso | zh-TW | |
dc.title | 芝麻油混摻其他食用油檢測方法之研究 | zh_TW |
dc.title | Studies on the Method for Discriminating Sesame Oil Blended with Other Edible Vegetable Oil | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 劉麗雲,林麗雲,鍾玉明,李敏雄 | |
dc.subject.keyword | 芝麻油,三酸甘油酯,混摻,模式系統,HPLC-ELSD, | zh_TW |
dc.subject.keyword | Sesame oil,triacylglycerol,adulteration,HPLC-ELSD,PCA, | en |
dc.relation.page | 78 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2011-08-20 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 農業化學研究所 | zh_TW |
顯示於系所單位: | 農業化學系 |
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