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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢 | |
| dc.contributor.author | Mei-Chun Tzeng | en |
| dc.contributor.author | 曾美純 | zh_TW |
| dc.date.accessioned | 2021-06-08T04:20:08Z | - |
| dc.date.copyright | 2010-07-21 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22534 | - |
| dc.description.abstract | 我們利用大環分子可以辨識胍鹽（guanidinium）及聯吡啶（bipyridine）衍生物的特性，合成一個具有胍鹽和聯吡啶兩種辨識中心的車輪烷分子，並成功地藉由加入/移除金屬陽離子來加以控制大環分子與胍鹽辨識端間的錯合與解離，進而操作分子開關的移動異構化（translational isomerization）。 | zh_TW |
| dc.description.abstract | Based on the knowledge that a macrocycle is capable of complexing guanidinium and bipyridinium ions, we synthesize a [2]rotaxane incorporating both recognition sites. The translational isomerization of the macrocyclic component between the two stations can be controlled through the addition and removal of metal ions. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T04:20:08Z (GMT). No. of bitstreams: 1 ntu-99-R97223176-1.pdf: 4305782 bytes, checksum: 027af9a7423cb5ce01441f759c0a9b36 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 謝誌 i
摘要 iii Abstract iv 目次 v 圖表 vi 流程 viii 壹、導論 1 1.1 前言 1 1.2內鎖型分子 2 1.3 超分子系統的發展與應用 4 貳、結果與討論 17 2.1 研究動機 17 2.2分子開關的設計 18 2.3 車輪烷分子的製備 21 2.4 分子開關之研究 28 参、結論 32 肆、實驗部分 33 伍、參考文獻 43 | |
| dc.language.iso | zh-TW | |
| dc.subject | 超分子 | zh_TW |
| dc.subject | supramolecular | en |
| dc.title | 以胍基為基礎之陽離子控制分子開關的合成研究 | zh_TW |
| dc.title | A Guanidinium Ion-Based Cation Controllable Molecular Switch | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福,賴建成 | |
| dc.subject.keyword | 超分子, | zh_TW |
| dc.subject.keyword | supramolecular, | en |
| dc.relation.page | 47 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2010-07-20 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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