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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 汪根欉(Ken-Tsung Wong) | |
| dc.contributor.author | Li-Chi Lee | en |
| dc.contributor.author | 李立棋 | zh_TW |
| dc.date.accessioned | 2021-06-08T04:17:27Z | - |
| dc.date.copyright | 2010-07-30 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-29 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22422 | - |
| dc.description.abstract | 本論文中，我們設計出以芴基衍生物為發光中心之四種可熱聚合單體 (VB-DTACN、VB-DFBTA、VB-FNPD與VB-T3)，並以陽極氧化鋁 (anodized aluminum oxide, AAO) 模板輔助法製備一維奈米物件，包含紅、藍、綠三色螢光奈米管、紅藍兩截式螢光奈米管與藍色螢光奈米陣列。我們先使用模板浸潤法 (wetting template method) 將單體溶液藉由毛細作用力引入模板孔洞後，再透過單體原位聚合法 (in situ polymerization method) 使單體經熱聚合過程於模板的一維通道中形成交鏈高分子奈米管。我們利用所設計分子之光致發光特性，將這些一維奈米物件進行螢光特性之分析，以及奈米管間和兩截式奈米管內之能量轉移行為之討論。利用本論文單體設計概念，不僅可用於轉化含有其他光學或電學特性之分子成為一維奈米物件，且本論文已製備出之材料擁有的發光特性與半導特性，也可在將來直接轉移到光電元件中應用。 | zh_TW |
| dc.description.abstract | We report here four polymerizable monomers VB-DTACN, VB-DFBTA, VB-FNPD and VB-T3 to prepare one dimensional (1-D) nano-objects. By means of the AAO (anodized aluminum oxide) template assisted fabricaton, elongated nano-objects, including red, green, and blue (RGB) emissive nanotubes, segmental nanotubes, and blue emissive nano-array, were obtained. Combining the wetting template method with in situ polymerization method, the monomer solution penetrated into the AAO pores and transformed to cross-linked polymeric nanotubes after thermal annealing. Based on the photoluminescence property of our materials, we conducted some fluorescence characterizations and energy transfer observations both between red and blue nanotubes, and within segmental nanotubes. Ultilizing the idea of monomer design in this thesis, other electroactive, or photoactive organic molecules can possibly also be applied to transform in to the dispersed 1-D nanostructure or nanoarray morphology. Moreover, the inherent semiconducting property of the fluorene-based molecular skeleton makes our nanotubes possible to be applied in nanoscale photo-electronic devices in the future. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T04:17:27Z (GMT). No. of bitstreams: 1 ntu-99-R97223101-1.pdf: 124569475 bytes, checksum: f291b245774921dbfbff166fdba76912 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 中文摘要i
英文摘要ii 目錄iii 圖目錄v 表目錄viii 第一章 緒論1 1-1 一維奈米材料之特殊性質與應用3 1-2 陽極氧化鋁模板輔助有機一維奈米材料之合成7 第二章 可交鏈式有機螢光單體之設計12 2.1 螢光中心13 2.2 聚合基團14 2.3 螢光單體及其熱聚合性質15 第三章 有機螢光高分子奈米管19 3-1 紅、藍、綠有機螢光高分子奈米管20 3-1-1 奈米管之合成20 3-1-2 奈米管性質鑑定22 3-2 兩截式有機螢光高分子奈米管27 3-2-1 奈米管之合成29 3-2-2 奈米管性質鑑定30 3-3 有機螢光高分子奈米管之能量轉移現象34 3-3-1 奈米管間之能量轉移37 3-3-2 兩截式奈米管內之能量轉移39 第四章 有機螢光高分子一維奈米陣列43 4-1 陣列之合成44 4-2 陣列性質之鑑定50 第五章 實驗部分53 5-1 測式儀器與樣品製備53 5-2 化合物VB-DFBTA合成步驟55 5-3 樣品製備條件58 參考文獻62 附錄67 | |
| dc.language.iso | zh-TW | |
| dc.subject | 螢光奈米管 | zh_TW |
| dc.subject | 陽極氧化鋁模板輔助合成 | zh_TW |
| dc.subject | AAO template-assisted synthesis | en |
| dc.subject | Fluorescent Nanotubes | en |
| dc.title | 以芴基衍生物為單體之模板輔助螢光高分子奈米管合成與鑑定 | zh_TW |
| dc.title | Template-Assisted Synthesis of Organic-Fluorescent Polymeric Nanotubes Using Fluorene Derived Monomers | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳忠幟(Chung-chih Wu),薛景中(Jing-Jong Shyue) | |
| dc.subject.keyword | 螢光奈米管,陽極氧化鋁模板輔助合成, | zh_TW |
| dc.subject.keyword | Fluorescent Nanotubes,AAO template-assisted synthesis, | en |
| dc.relation.page | 71 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2010-07-29 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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