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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳力騏(Richie L. C. Chen) | |
| dc.contributor.author | Yi Kung | en |
| dc.contributor.author | 龔毅 | zh_TW |
| dc.date.accessioned | 2021-06-08T04:17:00Z | - |
| dc.date.copyright | 2010-08-05 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-30 | |
| dc.identifier.citation | [1] 丁旺賢。環境荷爾蒙 - 壬基苯酚類持久性有機汙染物在臺灣水環境中之分析 與流布調。NSC91-2113-M-008-022。
[2] 王建民。苯酚類環境荷爾蒙物質之微生物可降解性及吸附性研究。NSC93-2211-E-241-009。 [3] 陳柏中。2009。酚類感測之電化學法的研究。博士論文。台北：台灣大學生物產業機電工程學研究所。 [4] 陳美連。國人壬基苯酚類暴露之生物偵測研究。NSC90-2621-Z-010-002。 [5] 陳健民。建立環境荷爾蒙物質之魚類毒性測試系統。 NSC91-2313-B-041-008。 [6] 陳家揚。自來水與廢水處理過程去除動情激素類環境荷爾蒙的效率以及淡水河本流雌激素污染現況。NSC93-2320-B-002-089。 [7] 經濟部工業局。2003。廢水三級處理相關技術與實務介紹。台北：經濟部工業局。 [8] 謝博全。2008。和尚蟹幾丁質皮膜於生物感測的應用。博士論文。台北：台灣大學生物產業機電工程學研究所。 [9] Andreescu, S. and O. A. Sadik. 2004. Correlation of analyte structures with biosensor responses using the detection of phenolic estrogens as a model. Analytical Chemistry 76:552-560. [10] Birkett, J. W., and J. N. Lester. 2003. Endocrine disrupters in wastewater and sludge treatment processes, Boca Raton: Lewis Publishers. [11] Comninellis, C. and C. Pulgarin. 1993. Electrochemical oxidation of phenol for waste-water treatment using SnO2 anodes. Journal of Applied Electrochemistry 23:108-112. [12] Gaido, K. W., L. S. Leonard, S. Lovell, J. C. Gould, D. Babai, C. J. Portier and D. P. McDonnell. 1997. Evaluation of chemicals with endocrine modulating activity in a yeast-based steroid hormone receptor gene transcription assay. Toxicology and Applied Pharmacology 143:205-212. [13] Iniesta, J., E. Exposito, J. Gonzalez-Garcia, V. Montiel and A. Aldaz. 2002. Electrochemical treatment of industrial wastewater containing phenols. Journal of the Electrochemical Society 149:D57-D62. [14] Korbahti, B. K. and A. Tanyolac. 2003. Continuous electrochemical treatment of phenolic wastewater in a tubular reactor. Water Research 37:1505-1514. [15] Korner, W., V. Hanf, W. Schuller, C. Kempter, J. Metzger and H. Hagenmaier. 1999. Development of a sensitive E-screen assay for quantitative analysis of estrogenic activity in municipal sewage plant effluents. Science of the Total Environment 225:33-48. [16] Kuramitz, H., Y. Nakata, M. Kawasaki and S. Tanaka. 2001. Electrochemical oxidation of bisphenol A. Application to the removal of bisphenol A using a carbon fiber electrode. Chemosphere 45:37-43. [17] Larsson, D. G. J., M. Adolfsson-Erici, J. Parkkonen, M. Pettersson, A. H. Berg, P. E. Olsson and L. Forlin. 1999. Ethinyloestradiol - an undesired fish contraceptive? Aquat. Toxicol. 45:91-97. [18] Ma, H., X. Zhang, Q. Ma and B. Wang. 2009. Electrochemical catalytic treatment of phenol wastewater. Journal of Hazardous Materials 165:475-480. [19] Martinez-Huitle, C. A. and S. Ferro. 2006. Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes. Chemical Society Reviews 35:1324-1340. [20] Odum, J., P. A. Lefevre, S. Tittensor, D. Paton, E. J. Routledge, N. A. Beresford, J. P. Sumpter and J. Ashby. 1997. The rodent uterotrophic assay: Critical protocol features, studies with nonyl phenols, and comparison with a yeast estrogenicity assay. Regulatory Toxicology and Pharmacology 25:176-188. [21] Patty, F. A. 1963. Industrial hygiene and toxicology (Fassett, D. W., Irosh, D. D., and Kumler, K., Eds.), Vol. II, New York: Interscience Pulishers. [22] Petrovic, M. and D. Barcelo. 2000. Determination of anionic and nonionic surfactants, their degradation products, and endocrine-disrupting compounds in sewage sludge by liquid chromatography/mass spectrometry. Analytical Chemistry 72:4560-4567. [23] Polcaro, A. M., S. Palmas, F. Renoldi and M. Mascia. 1999. On the performance of Ti/SnO2 and Ti/PbO2 anodes in electrochemical degradation of 2-chlorophenol for wastewater treatment. Journal of Applied Electrochemistry 29:147-151. [24] Polcaro, A. M., S. Palmas, F. Renoldi and M. Mascia. 2000. Three-dimensional electrodes for the electrochemical combustion of organic pollutants. Electrochimica Acta 46:389-394. [25] Pulgarin, C., N. Adler, P. Peringer and C. Comninellis. 1994. Electrochemical detoxification of a 1,4-benzoquinone solution in waste-water treatment. Water Research 28:887-893. [26] Tanaka, S., Y. Nakata, T. Kimura, Yustiawati, M. Kawasaki and H. Kuramitz. 2002. Electrochemical decomposition of bisphenol A using Pt/Ti and SnO2/Ti anodes. Journal of Applied Electrochemistry 32:197-201. [27] Tran, L. H., P. Drogui, G. Mercier and J. F. Blais. 2009. Electrochemical degradation of polycyclic aromatic hydrocarbons in creosote solution using ruthenium oxide on titanium expanded mesh anode. Journal of Hazardous Materials 164:1118-1129. [28] White, R., S. Jobling, S. A. Hoare, J. P. Sumpter and M. G. Parker. 1994. Environmentally persistent alkylphenolic compounds are estrogenic. Endocrinology 135:175-182. [29] Witorsch, R. J. 2002. Endocrine disruptors: Can biological effects and environmental risks be predicted? Regulatory Toxicology and Pharmacology 36:118-130. [30] Xu, L., N. He, J. Du, Y. Deng, Z. Li and T. Wang. 2009. A detailed investigation for determination of tannic acid by anodic stripping voltammetry using porous electrochemical sensor. Anal. Chim. Acta 634:49-53. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22401 | - |
| dc.description.abstract | 本研究開發了電化學酚類感測器以及酚類電解處理系統，並可整合成一具有酚類檢測及處理效能之複合式模組。
電化學酚類感測器利用流動注射分析系統為主體，搭配電化學介質（10 mM 黃血鹽溶液 in 10 mM, pH7.0 磷酸鹽緩衝溶液）所組成，其可避免檢測電極受到直接氧化酚類所受到的污染，並且在檢測電位為0.4 V、系統流速為0.4 ml/min之下，架構出一檢測極限至25 μM鄰苯二酚且可在3 min內檢測完成之分析系統。 酚類電解處理系統為利用活性碳粉末（Activated carbon powder，99~250 μm）自製一酚類反應器(2 mm i.d × 6 cm)，配合定電壓源施予偏壓架構出一電解處理系統，每公克活性碳粉末約可處理約 0.7g，並與第一部分電化學酚類檢測系統整合為一即時檢測處理系統。 | zh_TW |
| dc.description.abstract | An amperometric flow-injection analytical (FIA) system was developed for detecting phenols in waste water. To avoid electrode fouling during direct oxidation of phenols, mediator such as ferricyanide was introduced in the carrier (10 mM phosphate buffer, pH 7.0) to couple the oxidation reaction (0.4 V vs. Ag/AgCl; flow rate: 0.4 ml/min). Approximately 3 min after injecting 100 μl of sample solution, 25 μM catechol can be detected with S/N ratio higher than 3. There is practically no decrease in signal after 100 injections.
A phenol-removing model system was then constructed for reducing phenols such as endocrine disrupting chemicals. It was based on the adsorption of the hazardous chemicals on a packed-bed reactor (2 mm i.d × 6 cm) containing activated carbon powder (99~250 μm). The system can tolerate water containing 100 mM phenols. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T04:17:00Z (GMT). No. of bitstreams: 1 ntu-99-R97631033-1.pdf: 1939853 bytes, checksum: aab4abd3e9f3aa612bc77403cb9b982c (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 誌謝 i
摘要 ii ABSTRACT iii 目錄 iv 圖目錄 vii 第一章 前言 1 第二章 文獻探討 3 2.1酚類與環境荷爾蒙介紹 3 2.2現行酚類檢測方法 6 2.3酚類處理法 7 2.3.1現今環境酚類處理法 7 2.3.2環境酚類電解處理法 8 2.3.3活性碳反應器 9 第三章 材料與方法 10 3.1實驗藥品與研究設備 10 3.1.1實驗藥品 10 3.1.2實驗儀器設備 11 3.2以循環伏安法量測氧化還原電位 12 3.3電化學酚類感測器之開發 13 3.3.1電化學流穿槽之製作 14 3.3.2未含電化學介質之酚類感測器 15 3.3.3含電化學介質處理之酚類感測器 16 3.3.3.1電化學介質之選擇 16 3.3.3.2檢測原理與系統架設 17 3.3.3.3電化學介質對電化學酚類感測器之影響 19 3.3.3.4系統流速對電化學酚類感測器之影響 19 3.3.3.5檢測電壓對電化學酚類感測器之影響 20 3.3.3.6電化學介質濃度對電化學酚類感測器之影響 20 3.3.3.7含電化學介質酚類感測器之檢量 21 3.4環境酚類電解反應系統之開發 22 3.4.1活性碳反應器之製作 22 3.4.2環境酚類電解處理暨檢測系統 23 3.4.2.1處理原理與系統架設 23 3.4.2.2活性碳反應器對電流響應之影響 25 3.4.2.3氧化電流量降低之探討 25 3.4.2.3施加偏壓對單次注入處理效率之響應 26 3.4.3環境酚類電解反應器有效使用期限 27 3.4.3.1檢測原理與系統架設 27 3.4.3.2活性碳反應器之電導度響應 29 第四章 結果與討論 30 4.1實驗藥品之循環伏安圖 30 4.2高感度酚類檢測器之開發 31 4.2.1電化學介質對電化學酚類感測器性能之影響 31 4.2.2含介質酚類檢測器之最佳化 33 4.2.2.1系統流速對系統電流響應之影響 33 4.2.2.2檢測電壓對系統電流響應之影響 35 4.2.2.3介質濃度對系統檢測極限之影響 37 4.2.2.4含介質酚類檢測器之檢量 39 4.3環境酚類電解反應系統之開發 41 4.3.1活性碳反應器對電流響應之影響 41 4.3.2氧化電流量降低之探討 43 4.3.3施加偏壓對單次注入處理效率之響應 44 4.3.4活性碳反應器之電導度響應 46 第五章 結論 48 參考文獻 49 | |
| dc.language.iso | zh-TW | |
| dc.subject | 活性碳 | zh_TW |
| dc.subject | 流動注射分析系統 | zh_TW |
| dc.subject | 酚類 | zh_TW |
| dc.subject | 電解處理 | zh_TW |
| dc.subject | phenol | en |
| dc.subject | flow-injection analysis | en |
| dc.subject | activated carbon | en |
| dc.subject | electrolytic treatment | en |
| dc.title | 電化學酚類感測器及廢水電解處理系統的研發 | zh_TW |
| dc.title | Development of an Electrochemical Phenol Sensor and Electrolytic Treatment System for Waste Water | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 鄭宗記,艾群,陳林祈 | |
| dc.subject.keyword | 酚類,流動注射分析系統,活性碳,電解處理, | zh_TW |
| dc.subject.keyword | phenol,flow-injection analysis,activated carbon,electrolytic treatment, | en |
| dc.relation.page | 53 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2010-07-30 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物產業機電工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物機電工程學系 | |
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