請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22169完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 廖英志(Ying-Chih Liao) | |
| dc.contributor.author | Fu-Ren Xiao | en |
| dc.contributor.author | 蕭富仁 | zh_TW |
| dc.date.accessioned | 2021-06-08T04:06:16Z | - |
| dc.date.copyright | 2018-08-01 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-07-26 | |
| dc.identifier.citation | 1. G. Schwartz, B. C.-K. Tee, J. Mei, A. L. Appleton, D. H. Kim, H. Wang, Z. Bao. Flexible polymer transistors with high pressure sensitivity for application in electronic skin and health monitoring. Nat. Commun. 2013, 4, 1859.
2. D.-H. Kim, N. Lu, R. Ma, Y.-S. Kim, R.-H. Kim, S. Wang, J. Wu, S. M. Won, H. Tao, A. Islam, K. J. Yu, T. Kim, R. Chowdhury, M. Ying, L. Xu, M. Li, H.-J. Chung, H. Keum, M. McCormick, P. Liu, Y.-W. Zhang, F. G. Omenetto, Y. Huang, T. Coleman, J. A Rogers. Epidermal electronics, Science 2011, 333, 838. 3. M. Kaltenbrunner, T. Sekitani, J. Reeder, T. Yokota, K. Kuribara, T. Tokuhara, M. Drack, R. Schwodiauer, I. Graz, S. Bauer-Gogonea, S. Bauer, T. Somey An ultra-lightweight design for imperceptible plastic electronics. Nature 2013, 499, 458. 4. W. Honda, S. Harada, T. Arie, S. Akita, K. Takei. Wearable, Human‐Interactive, Health‐Monitoring, Wireless Devices Fabricated by Macroscale Printing Techniques. Adv. Funct. Mater. 2014, 24, 3299. 5. Pang, C. et al. A flexible and highly sensitive strain-gauge sensor using reversible interlocking of nanofibres. Nat. Mater. 2012, 11, 795–801. 6. Maheshwari, V. & Saraf, R. Tactile devices to sense touch on a par with a human finger. Angew. Chem. Int. Edit. 2008, 47, 7808–7826. 7. Wang, L. & Li, Y. A review for conductive polymer piezoresistive composites and a development of a compliant pressure transducer. IEEE Trans. Instru. Measu. 2013, 62, 495–502. 8. J. Park, M. Kim, Y. Lee, H. S. Lee, H. Ko. Fingertip skin–inspired microstructured ferroelectric skins discriminate static/dynamic pressure and temperature stimuli. Sci. Adv. 2015, 1, e1500661. 9. J. Park, Y. Lee, J. Hong, M. Ha, Y. D. Jung, H. Lim, S. Y. Kim, H. Ko. Giant Tunneling Piezoresistance of Composite Elastomers with Interlocked Microdome Arrays for Ultrasensitive and Multimodal Electronic Skins. ACS Nano 2014, 8, 4689. 10. J. Park, Y. Lee, J. Hong, Y. Lee, M. Ha, Y. Jung, H. Lim, S. Y. Kim, H. Ko. Tactile-Direction-Sensitive and Stretchable Electronic Skins Based on Human-Skin-Inspired Interlocked Microstructures. ACS Nano 2014, 8, 12020. 11. B. C. Tee, A. Chortos, A. Berndt, A. K. Nguyen, A. Tom, A. Mcguire, Z. C. Lin, K. Tien, W. G. Bae, H. Wang. A skin-inspired organic digital mechanoreceptor. Science 2015, 350, 313. 12. G. Y. Bae, W. P. Sang, D. Kim, G. Lee, D. H. Kim, Y. Chung, K. Cho. Linearly and Highly Pressure‐Sensitive Electronic Skin Based on a Bioinspired Hierarchical Structural Array. Adv. Mater. 2016, 28, 5300. 13. C. L. Choong, M. B. Shim, B. S. Lee, S. Jeon, D. S. Ko, T. H. Kang, J. Bae, S. H. Lee, K. E. Byun, J. Im. Highly Stretchable Resistive Pressure Sensors Using a Conductive Elastomeric Composite on a Micropyramid Array. Adv. Mater. 2014, 26, 3451. 14. H. H. Chou, A. Nguyen, A. Chortos, J. W. To, C. Lu, J. Mei, T. Kurosawa, W. G. Bae, J. B. Tok, Z. Bao. A chameleon-inspired stretchable electronic skin with. Nat. Commun. 2015, 6, 8011. 15. S. A. Hasan, Y. Jung, S. Kim, C. L. Jung, S. Oh, J. Kim, H. Lim. A Sensitivity Enhanced MWCNT/PDMS Tactile Sensor Using Micropillars and Low Energy Ar+ Ion Beam Treatment. Sensors 2016, 16, 93. 16. H. Park, Y. R. Jeong, J. Yun, S. Y. Hong, S. Jin, S. J. Lee, G. Zi, J. S. Ha. Stretchable Array of Highly Sensitive Pressure Sensors Consisting of Polyaniline Nanofibers and Au-Coated Polydimethylsiloxane Micropillars. ACS Nano 2015, 9, 9974. 17. L. Pan, A. Chortos, G. Yu, Y. Wang, S. Isaacson, R. Allen, Y. Shi, R. Dauskardt, Z. Bao. An ultra-sensitive resistive pressure sensor based on hollow-sphere microstructure induced elasticity in conducting polymer film. Nat. Commun. 2014, 5, 3002. 18. H. B. Yao, J. Ge, C. F. Wang, X. Wang, W. Hu, Z. J. Zheng, Y. Ni, S. H. Yu. A Flexible and Highly Pressure‐Sensitive Graphene–Polyurethane Sponge Based on Fractured Microstructure Design. Adv. Mater. 2013, 25, 6692. 19. H. Bi, I. W. Chen, T. Lin, F. Huang. A New Tubular Graphene Form of a Tetrahedrally Connected Cellular Structure. Adv. Mater. 2015, 27, 5943. 20. A. Rinaldi, A. Tamburrano, M. Fortunato, M. Sarto. A Flexible and Highly Sensitive Pressure Sensor Based on a PDMS Foam Coated with Graphene Nanoplatelets. Sensors 2016, 16, 2148. 21. Y. A. Samad, Y. Li, A. Schiffer, S. M. Alhassan, K. Liao. Graphene Foam Developed with a Novel Two‐Step Technique for Low and High Strains and Pressure‐Sensing Applications. Small 2015, 11, 2380. 22. Y. Si, X. Wang, C. Yan, L. Yang, J. Yu, B. Ding. Pressure Sensors: Ultralight Biomass‐Derived Carbonaceous Nanofibrous Aerogels with Superelasticity and High Pressure‐Sensitivity. Adv. Mater. 2016, 28, 9512. 23. Y. Wei, Q. Xu. An overview of micro-force sensing techniques. An overview of micro-force sensing techniques. Sens. Actuators A: Phys. 2015, 234 359–374. 24. M. Motamed, J. Yan. A review of biological, biomimetic and miniature force sensing for microflight, in: Intelligent Robots and Systems. IEEE/RSJ International Conference on 2005 2005, pp. 3939–3946. 25. Ali E. Kubba, Ahmed Hasson, Ammar I. Kubba, and Gregory Hall, 'A microcapacitive pressure sensor design and modelling. ' Journal of Sensors and Sensor Systems 2016, 5, 95-112. 26. Gaviraj, S. N.; Donald, P. B.; Zeynep, Ç.-B.; İsmail Erkin, G. Micromachined force/tactile sensors using nickel–chromium piezoresistors. J. Micromech. Microeng. 2012, 22. 27. Ashruf, C.M.A. Thin flexible pressure sensors. Sens. Rev. 2002, 22, 322–327. 28. S.K. Clark and K.D. Wise. Pressure sensitivity in anisotropically etched thin-diaphragm pressure sensors. IEEE Transactions on Electron Devices 1979, Vol. ED-26, pp. 1887-1896. 29. W.P. Eaton and J.H. Smith. Micromachined pressure sensors: review and recent developments. Smart Master., Struct. 1997, 6, pp. 530-539. 30. A. Shashank, M.I. Tiwana, S.J. Redmond, N.H. Lovell. Design, simulation and fabrication of a low cost capacitive tactile shear sensor for a robotic hand. 2009 Annual International Conference of the IEEE Engineering in Medicine and Biology Society 2009, pp. 4132–4135. 31. Zhang, X.W.; Zheng, P.Y.; Yi, X.Q. Time dependence of piezoresistance for the conductor-filled polymer composites. J. Polym. Sci. Part B Polym. Phys. 2000, 38, 2739–2749. 32. Zhang, X.W.; Pan, Y.; Zheng, Q.; Yi, X.S. Piezoresistance of conductor filled insulator composites. Polym. Int. 2001, 50, 229–236. 33. Hussain, M.; Choa, Y.H.; Niihara, K. Fabrication process and electrical behavior of novel pressure-sensitive composites. Compos. Part A 2001, 32, 1689–1696. 34. Xu, F.; Ge, Y.; Yu, Y.; Ding, J.; Ju, T.; Li, S. The design of a novel flexible tactile sensor based on pressure-conductive rubber. Sens. Transducer. 2011, 124, 19–29. 35. Ausanio, G.; Barone, A.; Campana, C.; Iannotti, V.; Luponio, C.; Pepe, G.; Lanotte, L. Giant resistivity change induced by strain in a composite of conducting particles in an elastomer matrix. Sens. Actuators A Phys. 2006, 127, 56–62. 36. Bloor, D.; Donnelly, K.; Hands, P.J.; Laughlin, P.; Lussey, D. A metal-polymer composite with unusual properties. J. Phys. D Appl. Phys. 2005, 38, 2851–2860. 37. Hwang, J.; Jang, J.; Hong, K.; Kim, K. N.; Han, J. H.; Shin, K.; Park, C.E. Poly(3-hexylthiophene) wrapped carbon nanotube/poly(dimethylsiloxane) composites for use in finger-sensing piezoresistive pressure sensors. Carbon 2011, 49, 106–110 38. Knite, M.; Teteris, V.; Kiploka, A.; Kaupuzs, J. Polyisoprene-carbon black nanocomposites as tensile strain and pressure sensor materials. Sens. Actuators A 2004, 110, 142–149. 39. Jiang, M.J.; Dang, Z.M.; Xu, H.P. Significant temperature and pressure sensitivities of electrical properties in chemically modified multiwall carbon nanotube/methylvinyl silicone rubber nanocomposites. Appl. Phys. Lett. 2006, 89, doi:10.1063/1.2369643. 40. Jiang, M.-J.; Dang, Z.-M.; Xu, H.-P.; Yao, S.-H.; Bai, J. Effect of aspect ratio of multiwall carbon nanotubes on resistance-pressure sensitivity of rubber nanocomposites. Appl. Phys. Lett. 2007, 91, doi:10.1063/1.2772671. 41. Dang, Z.M.; Jiang, M.J.; Xie, D.; Yao, S.H.; Zhang, L.Q.; Bai, J.J. Supersensitive linear piezoresistive property in carbon nanotubes/silicone rubber nanocomposites. Appl. Phys. 2008, 104, doi:10.1063/1.2956605. 42. Hu, C.H.; Liu, C.H.; Chen, L.Z.; Peng, Y.C.; Fan, S.S. Resistance-pressure sensitivity and a mechanism study of multiwall carbon nanotube networks/poly(dimethylsiloxane) composites. Appl. Phys. Lett. 2008, 93, doi:10.1063/1.2961028. 43. Hou, Y.; Wang, D.; Zhang, X.M.; Zhao, H.; Zha, J.W.; Dang, Z.M. Positive piezoresistive behavior of electrically conductive alkyl-functionalized graphene/polydimethylsilicone nanocomposites. J. Mater. Chem. C 2013, 1, 515–521. 44. Chen, L.; Chen, G.H.; Lu, L. Piezoresistive behavior study on finger-sensing silicone rubber/graphite nanosheet nanocomposites. Adv. Funct. Mater. 2007, 17, 898–904. 45. Martin, C.A.; Sandler, J.K.W.; Shaffer, M.S.P.; Schwarz, M.-K.; Bauhofer, W.; Schulte, K.; Windle, A.H. Formation of percolating networks in multi-wall carbon-nanotube-epoxy composites. Compos. Sci. Technol. 2004, 64 (15 SPEC. ISS.), 2309–2316. 46. 73. Sandler, J.K.W.; Kirk, J.E.; Kinloch, I.A.; Shaffer, M.S.P.; Windle, A.H. Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer 2003, 44, 5893–5899. 47. Alamusi; Hu, N.; Fukunaga, H.; Atobe, S.; Liu, Y.; Li, J. Piezoresistive Strain Sensors Made from Carbon Nanotubes Based Polymer Nanocomposites. Sensors 2011, 11, 10691–10723. 48. S. Stassi, V. Cauda, G. Canavese, C. F. Pirri. Flexible tactile sensing based on piezoresistive composites: A review. Sensors 2014, vol. 14, no. 3, pp. 5296-5332. 49. W. Luheng, D. Tianhuai, W. Peng. Influence of carbon black concentration on piezoresistivity for carbon-black-filled silicone rubber composite. Carbon 2009, 47 , pp. 3151-3157. 50. Matthias Lückmann, Wolfgang Steinhoff. Crosslinking of fluoroelastomers and the influence on final properties. DuPont. 51. P.B. Liu, D.L. Liu, H.W. Zou, P. Fan, W. Xu. Structure and properties of closed-cell foam prepared from irradiation crosslinked silicone rubber. J. Appl. Polym. Sci. 2009, 113, pp. 3590-3595. 52. Matsumoto, S. Ogawa, T. Matsuda, A. Ueda, H. Aota, T. Fujii, H. Toridome. Further discussion on correlation between brittleness and inhomogeneous network structure of cross-linked resins originating in specific polymerization behavior of triallyl isocyanurate. Macromolecules 2008, 41 (21) , pp. 7938-7945. 53. X.W. Zhang, Y. Pan, Q. Zheng, X.S. Yi. Time dependence of piezorezistance for the conductor-filled polymer composites. J. Polym. Sci. B 2000, 38, pp. 2739-2749. 54. L.H. Wang, Y.Y. Han. Compressive relaxation of the stress and resistance for carbon nanotube filled silicone rubber composite. Compos Part A: Appl Sci Manuf. 2013, 47, pp. 63-71. 55. Tian, H.; Shu, Y.; Wang, X. F.; Mohammad, M. A.; Bie, Z.; Xie, Q. Y.; Li, C.; Mi, W. T.; Yang, Y.; Ren, T. L. A Graphene-Based Resistive Pressure Sensor with Record-High Sensitivity in a Wide Pressure Range. Sci. Rep. 2015, 5, 8603. 56. H.B. Yao, J. Ge, C.F. Wang, X. Wang, W. Hu, Z.J. Zheng. A flexible and highly pressure-sensitive graphene-polyurethane sponge based on fractured microstructure design. Adv. Mater. 2013 25 (46), pp. 6692–6698. 57. Jung S., Kim J.H., Kim J., Choi S., Lee J., Park I., Hyeon T., Kim D.H. Reverse-micelle-induced porous pressure-sensitive rubber for wearable human-machine interfaces. Adv. Mater. 2014, 26, pp. 4825-483. 58. Der Meng Company (1975). http://shinyi40.myweb.hinet.net/english/home.htm 59. E.K. Lee, S.Y. Cho. Preparation and characterization of natural rubber foams:effects of foaming temperature and carbon black content. Korean J Chem. Eng. 2007, 24 (6), pp. 1070-1075. 60. Xin, C. L.; He, Y. D.; Li, Q. C.; Huang, Y. Z.; Yan, B. R.; Wang, X. Crystallization behavior and foaming properties of polypropylene containing ultra-high molecular weight polyethylene under supercritical carbon dioxide. J. Appl. Polym. Sci. 2011, 119, 1275. 61. S.K. Goel, E.J. Beckman. Generation of microcellular polymeric foams using supercritical carbon-dioxide.1. Effect of pressure and temperature on nucleation, Polymer Engineering and Science 1994, 34 (14) , pp. 1137-1147 62. L. Pan, A. Chortos, G. Yu, Y. Wang, S. Isaacson, R. Allen, et al. An ultra-sensitive resistive pressure sensor based on hollow-sphere microstructure induced elasticity in conducting polymer film. Nat. Commun. 2014, 5 , p. 3002. 63. De Vries, D. Characterization of polymeric foams. Eindhoven University of Technology, 2009. 64. Gibson, L. J.; Ashby, M. F. Cellular Solids: Structure and Properties, 2nd ed.; Cambridge University Press: Cambridge, 65. Wang, B., Peng, Z., Zhang, Y.C. & Zhang, Y. Compressive response and energy absorption of foam EPDM. J. Appl. Polym. Sci. 2007, 105, 3462–3469. 66. B. Nguon, and M. Jouaneh. Design and characterization of a precision fluid dispensing valve. International Journal of Advanced Manufacturing Technology 2004, 24(3-4): p. 251-260. 67. K. Yoshimura, K. Nakano, K. Okamoto, T. Miyake. Mechanical and electrical properties in porous structure of ketjenblack/silicone-rubber composites, Sens Actuat A: Phys. 2012, 180 , pp. 55-62. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/22169 | - |
| dc.description.abstract | 本論文主要在探討多孔性結構在不同發泡條件下,氟橡膠(DAI-EL™-G801)、單壁奈米碳管(SWCNT)和不同發泡劑比例(AIBN和DPT)的導電橡膠的發泡結構對於電阻係數與機械性質變化的影響。壓阻式壓力感測器是直接將機械應變轉換為電阻變化,由於其簡單的讀出機制、簡易的製程和高像素密度而被廣泛使用。傳統壓阻式橡膠由於本身的黏彈性,導致楊氏係數過高,造成了許多問題,如蠕變現象、緩慢響應時間和壓力感測的靈敏度極低等等。在0-200kPa的壓力範圍內,我們透過多孔性結構降低了八倍壓阻橡膠的楊氏模量,因此在相同的壓縮應力下產生更多的應變,壓力感測的靈敏度相對增加了約12.8倍。
接著我們改變發泡劑的含量來控制孔徑大小(1.8-0.43mm),得以調控壓阻式壓力之靈敏度(2.63-4.31 MPa-1)。然而不同壓縮速率會產生有不同的延遲時間,當壓縮速度提升時(5 - 25mm/min),其相對電阻和應力越容易穩定,反應/回復時間也從7秒減少至2秒。為了探討多孔橡膠的耐久性,我們以同等應力(200kPa)和速率(25mm/min)去重覆壓縮多孔性橡膠一千次,其相對電阻無明顯變化。本實驗通過印刷技術、簡易的混摻和熱處理來簡化製作過程,且能微小化和設計陣列感應電極的尺寸(0.125 mm2)和圖案,應用在打擊壓力感測器來偵測出拳的壓力(50-120kPa)、出拳週期(3.5-1 sec/punch )和出拳的次數等等。 | zh_TW |
| dc.description.abstract | The purpose of this study was to investigate the effect of porous structure on the sensitivity of pressure sensing and Yong’s modulus. The piezoresistive rubber was composed of fluorine rubber (DAI-ELTM-G801), single wall carbon nanotube (SWCNT) and different foaming agent (AIBN and DPT). The piezoresistive sensor transferred mechanical strain into varying resistance and is widely used because of its simple readout mechanism, simple process and potential high pixel density. Due to the viscoelasticity, traditional piezoresistive conductive rubber possess high Yong’s modulus which lead to the creep phenomenon, slow response time and low sensitivity. We used porous structure to decreased Yong’s modulus eight times in the range of 0-200kPa, which can enhance the deformation to create more conductive path under the same stress and the sensitivity of pressure sensing increased about 12.9 times.
To control the pore size (1.8-0.43mm), we changed the foaming agent content to adjust the piezoresistive pressure sensitivity (2.63-4.31 MPa-1). However, different compressive rates can influence delay times. When the compression rate is increased (5-25 mm/min), the relative resistance and relative stress reached stability more quickly, so the reaction/recovery time is reduced from 7 seconds to 2 seconds. By comparing with traditional piezoresistive rubber at the same stress (200kPa) and rate (25mm/min) compressing in 1000 cycle, the relative resistance of porous rubber did not change significantly, showing great durability. This method simplifies the fabrication, miniaturized the size (0.125 mm2) and design conductive pattern of the array sensing electrode through printing technology, simple mixing and heat treatment, which can be applied to the boxing sensor to detect the punching strength (50-120kPa), punching cycle time (3.5-1 sec/punch) and the number of punches. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T04:06:16Z (GMT). No. of bitstreams: 1 ntu-107-R05524106-1.pdf: 4522464 bytes, checksum: efb3e0a91652d528c1727e161432329d (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 中文摘要 i
ABSTRACT ii 目錄 iv 圖目錄 vii 表目錄 ix 第一章 緒論 1 1.1 研究背景與動機 1 1.2 研究目的 2 1.3 論文架構 2 第二章 壓力感測器 3 2.1 壓力感測器 3 2.1.1 壓阻式壓力感測器 3 2.1.2 電容式壓力感測器 4 2.1.3 壓電式壓測器 5 2.2 壓阻式導電橡膠 7 2.2.1 滲流現象 8 2.2.2 量子穿隧效應 9 2.2.3 橡膠的交聯和機械性質 11 2.2.4 蠕變現象/壓力鬆弛現象 13 2.3 壓阻式靈敏感測器 15 2.3.1 交鎖結構 16 2.3.2 多孔性結構 18 2.4 多孔性結構 20 2.4.1 發泡原理 20 2.4.2 多孔壓阻式材料製程 24 2.4.3 多孔性結構橡膠應力 27 2.5 點膠塗佈技術 29 第三章 實驗系統程序 31 3.1 實驗藥品與儀器介紹 31 3.1.1 實驗藥品 31 3.1.2 實驗儀器 32 3.2 實驗流程 33 3.2.1 壓阻式感測器製作 33 3.2.2 壓力感測 35 3.2.3 孔隙率量測 35 第四章 多孔性結構壓阻感應分析 36 4.1 壓阻式橡膠 36 4.2 AIBN多孔性結構分析 40 4.2.1 多孔性橡膠之分析 40 4.2.2 不均勻發泡結構分析 42 4.3 DPT的多孔性結構分析 45 4.3.1 導電填料對於多孔性橡膠之分析 45 4.3.2 發泡劑對於多孔性橡膠分析 46 4.3.3 多孔壓力感測器之偵測極限 51 4.3.4 多孔橡膠反應/回復時間 52 4.3.5 壓感現象的重覆性 53 4.3.6 手指按壓測試 54 4.4 壓阻式陣列感測 55 4.5 拳擊打擊壓力感測器 56 第五章結論與未來展望 58 參考資料 59 | |
| dc.language.iso | zh-TW | |
| dc.subject | 靈敏度 | zh_TW |
| dc.subject | 多孔性結構 | zh_TW |
| dc.subject | 壓阻式壓力感測器 | zh_TW |
| dc.subject | Porous structure | en |
| dc.subject | piezoresistive pressure sensor | en |
| dc.subject | sensitivity | en |
| dc.title | 多孔性壓阻式感測器的孔隙結構和靈敏度之研究 | zh_TW |
| dc.title | Studies on the Porous Structure and Sensitivity of Pressure Sensor | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 竇維平(Wei-Ping Dow),葛明德(Ming-Der Ger),鍾仁傑(Ren-Jei Chung) | |
| dc.subject.keyword | 多孔性結構,壓阻式壓力感測器,靈敏度, | zh_TW |
| dc.subject.keyword | Porous structure,piezoresistive pressure sensor,sensitivity, | en |
| dc.relation.page | 64 | |
| dc.identifier.doi | 10.6342/NTU201802001 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2018-07-26 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位: | 化學工程學系 | |
文件中的檔案:
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-107-1.pdf 未授權公開取用 | 4.42 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。
