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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Liang-Yun Wang | en |
| dc.contributor.author | 王亮云 | zh_TW |
| dc.date.accessioned | 2021-06-08T00:12:06Z | - |
| dc.date.copyright | 2013-08-09 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-06 | |
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[12] Crystallographic data (excluding structure factors) for the [2]rotaxanes [11-H][TFPB] and [16-H][PF6] have been deposited with the Cambridge Crystallographic Data Center as supplementary publications no. CCDC-917835 and 917836. Copies of the data can be obtained free of charge upon application to CCDC, 12 Union Road, Cambridge CB21EZ, UK [fax: (+44)1223-336-033; email: deposit@ccdc.cam.ac.uk]. [13] Crystal data for [11-H][TFPB]: [C50H64O7NS2][C28H32O7S2][C32H12BF24] [CH2Cl2]; Mr = 2347.95; triclinic; space group P-1; a = 14.4985(3); b = 17.7566(3); c = 24.1925(5) A; V= 5966.4(2) A3; rcalcd = 1.307 g cm-3; m(CuKa) = 1.134 mm-1; T = 200(2) K; colorless columnar; 21,747 independent measured reflections; F2 refinement; R1 = 0.0906; wR2 = 0.2558. [14] (a) Ashton, P. R.; Chrystal, E. J. T.; Glink, P. T.; Menzer, S.; Schiavo, C.; Spencer, N.; Stoddart, J. F.; Tasker, P. A.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1996, 2, 709-728; (b) R. Ashton, P.; C. T. Fyfe, M.; K. 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S.; Matuszewski, B.; Tholen-Collison, J. J. Am. Chem. Soc. 1984, 106, 1779–1789. [20] (a) Montalti, M. Chem. Comm. 1998, 1461–1462; (b) Lin, C.-F.; Lai, C.-C.; Liu, Y.-H.; Peng, S.-M.; Chiu, S.-H. Chem. Eur. J. 2007, 13, 4350–4355. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/17423 | - |
| dc.description.abstract | 在本研究中，我們使用缺少氧原子以及具有兩個芳香基甲基碸(arylmethylsulfone) 的大環分子為主體分子，與雙[3,5-二甲基苄基]銨-四[3,5-雙(三氟甲基)苯基]硼酸之啞鈴形分子為客體分子，利用穿透後縮環法來合成車輪烷分子。將此 [2]準車輪烷分子進行光化學反應，照光之後從兩個芳香基甲基碸的部位脫去二氧化硫，所得到的 [2]車輪烷分子能在393 K的氘二甲亞碸 (CD3SOCD3) 溶液中穩定存活至少5小時。 | zh_TW |
| dc.description.abstract | We report a “threading followed by shrinking” approach toward rotaxane synthesis using an “oxygen-deficient” macrocycle containing two arylmethyl sulfone units and the dumbbell-shaped salt bis(3,5-dimethylbenzyl)ammonium tetrakis(3,5-trifluoromethylphenyl)borate as the host and guest components, respectively. Extruding SO2 from both of the arylmethyl sulfone motifs of the corresponding [2]pseudorotaxane resulted in a [2]rotaxane that was sufficiently stable to maintain its molecular integrity in CD3SOCD3 at 393 K for at least 5 h. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T00:12:06Z (GMT). No. of bitstreams: 1 ntu-102-F94223001-1.pdf: 11966333 bytes, checksum: 17c34a1205dcf1193b2fd622dd5f3998 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 中文摘要 i
英文摘要 ii 論文發表 iii 目錄 iv 流程目錄 v 圖目錄 vi 表目錄 ix 第一章 1 1.1研究動機 2 1.2結果與討論 8 1.3結論 33 實驗部分 34 參考文獻 48 附錄 53 | |
| dc.language.iso | zh-TW | |
| dc.title | 利用「穿透後縮環法」合成以二級銨離子為基礎之高穩定性車輪烷分子 | zh_TW |
| dc.title | Using “Threading Followed by Shrinking” to Synthesize Highly Stable Dialkylammonium-Ion-Based Rotaxanes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 陳平(Richard P. Cheng),徐秀福,李文山,賴建成,薛聖耀 | |
| dc.subject.keyword | 車輪烷,縮環,超分子化學,合成方法, | zh_TW |
| dc.subject.keyword | rotaxanes,shrinking,supramolecular chemistry,synthetic methods, | en |
| dc.relation.page | 101 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2013-08-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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