Skip navigation

DSpace

機構典藏 DSpace 系統致力於保存各式數位資料(如:文字、圖片、PDF)並使其易於取用。

點此認識 DSpace
DSpace logo
English
中文
  • 瀏覽論文
    • 校院系所
    • 出版年
    • 作者
    • 標題
    • 關鍵字
    • 指導教授
  • 搜尋 TDR
  • 授權 Q&A
    • 我的頁面
    • 接受 E-mail 通知
    • 編輯個人資料
  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 應用物理研究所
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16340
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor蔡定平 教授
dc.contributor.authorYen-Ju Liuen
dc.contributor.author劉燕儒zh_TW
dc.date.accessioned2021-06-07T18:10:30Z-
dc.date.copyright2012-07-20
dc.date.issued2012
dc.date.submitted2012-07-06
dc.identifier.citation1. S.R. Ovshinsky, “Reversible electrical switching phenomena in disordered structures,” Phys. Rev. Lett. 21, 1450-1453 (1968).
2. G. F. Zhou, H. J. Borg, J. C. N. Rijpers, and M. Lankhorst, “Crystallizationb ehavior of Phase Change materials: comparison between nucleation- and growth-dominated crystallization”, Optical Data Storage, 2000. Conference Digest,(2000)
3. Benno Tieke, Martijn Dekker, Nicola Pfeffer, Roel van woudenberg, Guo-Fu Zhou,and Igolt P. D. Ubbens,v “High data-rate phase-change media for the digital video recording system”, Jpn. J. Appl. Phys. 39, 762(2000)
4. T. Ohta, “Phase-Change Optical Memory Promotes the DVD Optical Disk”, J. Opt. Adv. Mat. 3, 609 (2001)
5. 徐豪汶,“鍺銻碲相變化奈米薄膜之奈米尺度光熱性質的研究”,碩士論文, 中央物理研究所 (2006).
6. Feinleib, J.deNeufville, S.C. Moss, and S.R.Ovshisky, “Rapid reversible light-induced crystallization of amorphous semiconductors”, Appl. Phys. Lett. 18, 254 (1971).
7. J. H. Coombs, A. P. J. M. Jongenelis, W. van Es-Spiekman, and B. A. J. Jacobs, “Laser-induced crystallization phenomena in GeTe-based alloys. I. Characterization of nucleation and growth”, J. Appl. Phys. 78, 4096 (1995).
8. N. Kh. Abrikosov and G. T. Danilova-Dobryakova, Izv. Akad. Nauk SSSR, Neorg. Mater. 1, 204 (1965).
9. R. Kojima, S. Okabayashi, T. Kashihara, K. Horai, and N. Yamada, Proc. Symp. on Phase-Change Recording 8, 35 (1996) (in Japanese).
10. Noboru Yamada et al., “Rapid-phase transitions of GeTe-Sb2Te3 pseudobinary amorphous thin films for an optical disk memory”, J. Appl. Phys. 69, 2849 (1991)
11. Noboru Yamada, Toshiyuki Matsunaga, “Structure of laser-crystallized Ge2Sb2+xTe5 sputtered thin films for use in optical memory”, J. Appl. Phys. 88, 7020 (2000).
12. Chubing Peng and M. Mansuripur, “Measurement of the thermal coefficients of rewritable phase-change optical recording media”, Appl. Opt. 39, 2374 (2000)
13. I. Friedrich et al., “Structure transforms of Ge2Sb2Te5 films studied by electrical resistance measurements”, J. Appl. Phys. 87, 4130 (2000).
14. 郭博成,“添加元素對Ge2Sb2Te5相變化光碟記錄之光學性質的影響”,台灣大學材料研究所 (2002)
15. Toshiyuki Matsunaga, Noboru Yamada, and Yoshiki Kubot, “Structures of stable and metastable Ge2Sb2Te5, an intermetallic compound in GeTe-Sb2Te3 pseudo-binary systems”, Acta Cryst. B 60, 685 (2004).
16. Zhimei Sun, Jian Zhou, and Rajeev Ahuja, “Structures of phase change materials for data storage”, PRL 96, 055507 (2006).
17. K. Kohary, V. M. Burlakov, and D. G. Pettifor, “Modeling the amorphous-to-to-crystalline phase change transformation in network materials”, Phys. Rev. B 71, 235309 (2005).
18. Zhimei Sun, Jian Zhou, and Rajeev Ahuja, “Unique Melting Behavior in Phase-Change Materials for Rewritable Data Storage”, PRL 98, 055505 (2007).
19. Zhimei Sun, Jian Zhou, and Rajeev Ahuja, “Unique Melting Behavior in Phase-Change Materials for Rewritable Data Storage”, PRL 98, 055505 (2007).
20. V.A. Kolobov, P. Fons, A. I. Frenkel, A. Ankudinov, J. Tominaga, and T. Uruga,” Understanding the phase-change mechanism of rewritable optical media”, Nat. Mater. 3, 703 (2004).
21. WeLnic et al., ”Unravelling the interplay of local structure and physical properties in phase-change materials”, Nat. Mater. 5, 56 (2006).
22. C. H. Chu, C. D. Shiue, H. W. Cheng, M. L. Tseng, H. P. Chiang, M. Mansuripur, D. P. Tsai, “Laser-induced phase transitions of Ge2Sb2Te5 thin films used in optical and electronic data storage and in thermal lithography,” Optics Express 18(17), 18383 (2010).
23. G. J. Zhang, et al, 'Femtosecond laser-induced crystallization in amorphous Ge2Sb2Te5 films,' Thin Solid Films 474, 169-172 (2005).
24. S. Raoux, C. T. Rettner, J. L. Jordan-Sweet, A. J. Kellock, T. Topuria, P. M. Rice, and D. C. Miller, 'Direct observation of amorphous to crystalline phase transitions in nanoparticle arrays of phase change materials,' J Appl Phys 102 (9) (2007).
25. V.Weidenhof et al., “Laser induced crystallization of amorphous Ge2Sb2Te5 Films”, J. Appl. Phys. 89, 3168 (2001).
26. Pramod K Khulbe et al., “Crystallization behavior of as-deposited, melt quenched, and primed amorphous states of Ge2Sb2.3Te5 films”, J. Appl. Phys. 88, 3926 (2000).
27. Toshihisa Nonaka et al., “Crystal structure of GeTe and Ge2Sb2Tb5 meta-stable phase”, Thin Solid Films 370, 258-261 (2000).
28. Walter K. Njoroge et al., “Density changes upon crystallization of Ge2Sb2.04Te4.74 films”, J. Vac. Sci. Technol. A 20(1), 230 (200).
29. 高宗聖,“氧化鋅複合材料奈米薄膜之近場超解析結構”,碩士論文,台灣大學物理學研究所 (2004).
30. Pramod K. Khulbe, Xiaodong Xun, and M. Mansuripur, “Crystallization and amorphization studies of a Ge2Sb2.3Te5 thin-film sample under pulsed laser irradiation,” Appl. Opt. 39, 2359 (2000).
31. Xiaodong Xun, James K. Erwin, Warren Bletscher, Jinhan Choi, Senta Kallenbach, and Masud Mansuripur, “Crystallization Studies on Phase-Change Optical Recording Media by Use of a Two-Dimensional Periodic Mark Array,” Appl. Opt. 40, 6535 (2002).
32. Pramod K. Khulbe, Terril Hurst, Michikazu Horie, and Masud Mansuripur, “Crystallization Behavior of Ge-Doped Eutectic Sb70Te30 Films in Optical Disks,” Appl. Opt. 41, 6220 (2002).
33. J. H. Coombs, A. P. J. M. Jongenelis, W. van Es-Spiekman, and B. A. J. Jacobs, “Laser-induced crystallization phenomena in GeTe-based alloys. I. Characterization of nucleation and growth,” J. Appl. Phys. 78, 4096 (1995).
34. Y.-C. Hsien, M. Mansuripur, J. Volkmer, and A. Brewen, “Measurement of the thermal coefficients of nonreversible phase-change optical recording films,” Appl. Opt. 36, 886 (1997).
35. Gerd M. Fischer, Briian Medower, Robert Revay, and Masud Mansuripur, “Thermal properties and crystallization dynamics of a phase-change alloy of write-once optical data storage,” Appl. Opt. 41, 1998 (2002).
36. Masud Mansuripur, J. Kevin Erwin , Warren Bletscher, Pramod Khulbe, Kayvan Sadeghi, Xiaodong Xun, Anurag Gupta, and Sergio Bj. Mendes, “Static tester for characterization of phase-change, dye-polymer, and magneto-optical media for optical data storage,” Appl. Opt. 38, 7095 (1999).
37. Mortimer Abramowitz, “Microscope: Basics and Beyond,” Olympus Microscopy Resource Center (2003).
38. G. Binning and H. Rohrer, Helv. Phys. Acta, 55, 726(1982).
39. G. Binning, H. Rohrer, C. Gerber, and E. Weibel, 'Surface Studies by Scanning Tunneling Microscopy,' Phys Rev Lett 49 (1), 57-61 (1982).
40. G. Binning ,C. F. Quate, and Ch. Gerber, Phys. Rev. Lett., 56, 930 (1986)
41. Y. Martin et al., J. Appl. Phys., 61, 4723 (1987)
42. Q. Zhong, D. Innis, K. Kjoller and V. B. Elings, Surf. Sci. Lett., 290, L688 (1993)
43. Joseph M. Wallace, “Applications of atomic force microscopy for the assessment of nanoscale morphological and mechanical properties of bone” Bone 50, 420–427 (2012)
44. Matsunaga, T.; Akola, J.; Kohara, S.; Honma, T.; Kobayashi, K.; Ikenaga, E.; Jones, R. O.; Yamada, N.; Takata, M.; Kojima, R., From local structure to nanosecond recrystallization dynamics in AgInSbTe phase-change materials. Nat Mater 2011, 10 (2), 129-134.
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16340-
dc.description.abstract相變化材料(Phase-change material)可藉由外在施加能量而使其在結晶態或非晶態之間做可逆的轉換,因此被廣泛地應用於高密度記錄之光儲存、相變化記憶體與半導體元件中。
本實驗是以濺鍍方式製備非晶態之相變化材料鍺銻碲(Ge2Sb2Te5, GST)薄膜,再藉由雷射加工使GST薄膜轉態成為結晶態,所使用的脈衝雷射可調整雷射功率(2mW~20mW)以及雷射脈衝長度(100ns~1500ns),藉由雷射改變製作不同類型的紀錄點,最後再以導電式原子力顯微儀(Conductive atomic force microscopy, C-AFM)以及光學顯微量測系統對紀錄點進行表面形貌、導電性以及光學性質之研究。
同時以雷射轉印術進行GST質量轉移,以非晶態的GST薄膜作為母版,玻璃基板作為母版,利用雷射聚焦於GST薄膜上,使其熔融並轉印至子版,觀察其轉印結構之製成穩定度以及結構均勻度。
zh_TW
dc.description.abstractPhase-change materials are used in rewritable optical disks and phase-change electronic memories. The application of phase-change materials are due to the ease and reversibility of the phase-transition between amorphous and crystalline state.
Amorphous thin films of Ge2Sb2Te5, sputter-deposited on a thin-film gold electrode, are investigated to understanding the local electrical conductivity under the influence of focused laser beam. The various laser power (2.0mW~20mW) and pulse duration (100ns~1500ns) used in writing recorded marks.The local conductivity of recorded marks and crystalline line can be investigated by a high-resolution and high-sensitivity of conductive atomic force microscopy (C-AFM).
Laser-induced forward transfer (LIFT) technique is a high-throughput fabrication method. Using the femtosecond laser pulses focused on a thin film of Ge2Sb2Te5 phase-change material, and transfer the illuminated material to a nearby substrate.
en
dc.description.provenanceMade available in DSpace on 2021-06-07T18:10:30Z (GMT). No. of bitstreams: 1
ntu-101-R99245007-1.pdf: 2981566 bytes, checksum: d370413891ffd112037ff2ed467d6bc8 (MD5)
Previous issue date: 2012
en
dc.description.tableofcontents中文摘要 I
Abstract II
目錄 III
圖目錄 V
表目錄 VII
第一章、緒論 1
1.1 前言 1
1.2 相變化材料 1
1.2.1 相變化過程 1
1.2.2 相變化結晶過程類型 3
1.2.3 相變化材料演進 5
1.2.4 相變化材料Ge2Sb2Te5結構 6
1.2.5 相變化材料Ge2Sb2Te5相態之間性質之差異 10
第二章、實驗儀器設備及基本原理 14
2.1 前言 14
2.2 四靶濺鍍機 14
2.2.1 儀器簡介及用途 14
2.2.2 樣品製作參數 17
2.3 靜態測試儀 17
2.3.1 儀器簡介及用途 17
2.3.2 儀器架構與元件介紹 18
2.3.2.1 儀器架構 18
2.3.2.2 雷射光泵探系統主要光學元件介紹 19
2.3.2.3 光學寫入實驗流程 23
2.4 超快雷射光學系統 24
2.4.1 超快雷射光學系統架構 24
2.4.2 儀器架構與元件介紹 25
2.5原子力顯微鏡 33
2.5.1 掃描探針顯微術 33
2.5.2 原子力顯微儀基本原理 33
2.5.3 原子力顯微儀基本操作模式 35
2.5.4 導電式原子力顯微儀 37
2.5.5 本實驗所使用之原子力顯微儀 37
第三章、實驗結果與分析 39
3.1 前言 39
3.2 樣品製備 39
3.3 實驗結果 40
3.3.1相變化材料鍺銻碲紀錄點性質之研究 40
3.3.2以雷射轉印技術製作相變化材料鍺銻碲微結構 49
3.4 實驗結果討論 51
第四章、結論 52
第五章、參考文獻 53
dc.language.isozh-TW
dc.subject雷射轉印術zh_TW
dc.subject相變化材料zh_TW
dc.subject雷射直寫技術zh_TW
dc.subject導電式原子力顯微儀zh_TW
dc.subjectconductive atomic force microscopyen
dc.subjectPhase-change materialen
dc.subjectLaser-induced forward transfer (LIFT)en
dc.subjectlaser direct-write techniquesen
dc.title以雷射直寫技術製作相變化材料微結構之研究zh_TW
dc.titleNanofabrication of phase-change material structures by laser direct-write techniquesen
dc.typeThesis
dc.date.schoolyear100-2
dc.description.degree碩士
dc.contributor.oralexamcommittee周趙遠鳳 教授,黃鼎偉 教授
dc.subject.keyword相變化材料,雷射直寫技術,導電式原子力顯微儀,雷射轉印術,zh_TW
dc.subject.keywordPhase-change material,laser direct-write techniques,conductive atomic force microscopy,Laser-induced forward transfer (LIFT),en
dc.relation.page57
dc.rights.note未授權
dc.date.accepted2012-07-06
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept應用物理所zh_TW
顯示於系所單位:應用物理研究所

文件中的檔案:
檔案 大小格式 
ntu-101-1.pdf
  未授權公開取用
2.91 MBAdobe PDF
顯示文件簡單紀錄


系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。

社群連結
聯絡資訊
10617臺北市大安區羅斯福路四段1號
No.1 Sec.4, Roosevelt Rd., Taipei, Taiwan, R.O.C. 106
Tel: (02)33662353
Email: ntuetds@ntu.edu.tw
意見箱
相關連結
館藏目錄
國內圖書館整合查詢 MetaCat
臺大學術典藏 NTU Scholars
臺大圖書館數位典藏館
本站聲明
© NTU Library All Rights Reserved