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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16263完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 蔡定平(Din Ping Tsai) | |
| dc.contributor.author | Li-Chung Kuo | en |
| dc.contributor.author | 郭立中 | zh_TW |
| dc.date.accessioned | 2021-06-07T18:07:15Z | - |
| dc.date.copyright | 2012-07-27 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-07-23 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/16263 | - |
| dc.description.abstract | 自從1969年「本多-藤島」效應被發現以來，光觸媒已運用在廢水處理、除臭、殺菌、氮化物分解、防污及氫能源的生產上。然而，光觸媒的轉換效率不佳且無法有效提升也限制了其更廣泛的運用於人類文明中。因此本研究設計了利用化學水熱法在光碟片塑膠基板上以低溫製成大面積氧化鋅奈米柱，並以經熱處理之不連續金作為輔助，進行甲基橙染料之光分解實驗。並利用電子顯微鏡、原子力顯微鏡、X光繞射儀以及紫外-可見光光譜來分析製作出的樣品。本實驗亦利用一特殊設計之旋轉盤反應器，提升分解物在光觸媒表面上的質量轉移效率。在染料之光分解的實驗結果顯示，在不連續之金膜上，奈米金結構於特定波長的光照射下，會產生表面電漿共振現象，進而使侷域性的電磁場增強，使得甲基橙降解反應效率之提升，顯示其光觸媒活性之增益。 | zh_TW |
| dc.description.abstract | Since the Honda-Fujishima effect discovered in 1969, the photocatalysis has been utilized in water treatment, deodorization, anti-bacteria, NOX decomposition, dirtiness prevention and production of hydrogen energy. However, low and hardly improved photocatalytic conversion efficiency limits its widely application in human civilization. Therefore, a large scale of ZnO nanorods are synthesized on a plastic optical disc substrate by hydrothermal method at low temperature. By discontinuous gold film supported, a methyl orange degradation experiment was conducted. SEM, AFM, XRD and UV/Vis spectroscopy were used to characterized the sample. A specially designed rotating disk reactor was developed to achieve high mass transfer rate and to increase the process efficiency. Localized suface plasmons were generated in the gold nanostructure on discontinuous gold film with specific light illumination. The experimental results show that by discontinuous gold film supported, the photocatalytic conversion rate does increase both with UV and UV/Vis light illumination. It shows that the LSP enhance the near electromagnetic field, and then increased the photocatalytic activities. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T18:07:15Z (GMT). No. of bitstreams: 1 ntu-101-R99245011-1.pdf: 2609336 bytes, checksum: 03f42cd67e060b3c781f9b07bc683e5b (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
中文摘要 i ABSTRACT ii 目錄 iii 圖目錄 vi 表目錄 viii 第一章 緒論 1 1.1 前言 1 1.2 半導體光觸媒 2 1.2.1 半導體光觸媒之發現與原理 2 1.2.2 常見之半導體光觸媒 5 1.2.3 光觸媒之發展與應用 7 1.3 金屬表面電漿共振 8 1.3.1 發展背景 8 1.3.2 介電物質與金屬介面的表面電漿共振 9 1.3.3 侷域性表面電漿共振 14 1.4 表面電漿共振光觸媒 17 1.4.1 表面電漿共振光觸媒之工作原理 17 1.4.2 近期發表之表面電漿共振光觸媒 21 1.5 研究動機 22 第二章 實驗架構 23 2.1 前言 23 2.2 四靶濺鍍系統 23 2.2.1 四靶濺鍍系統簡介 23 2.2.2 薄膜製作流程 24 2.3 常見之氧化鋅奈米柱合成方法 26 2.3.1 氣液固法 27 2.3.2 熱蒸鍍法 27 2.3.3 模板輔助成長 27 2.3.4 化學氣相沈積法 28 2.3.5 分子束磊晶法 28 2.3.6 水熱法 29 2.4 水熱法合成氧化鋅奈米柱 30 2.4.1 氧化鋅奈米柱樣品製作 30 2.4.2 表面電漿共振光觸媒光碟片樣品製作 31 2.5 旋轉盤反應器系統 31 2.5.1 旋轉盤反應器介紹 31 2.5.2 旋轉盤反應器實驗架構 32 第三章 實驗結果與分析 35 3.1 前言 35 3.2 水熱法合成氧化鋅奈米柱於光碟基板 35 3.2.1 氧化鋅奈米柱樣品分析 35 3.2.2 表面電漿共振光觸媒光碟片特性分析 38 3.3 甲基橙光降解實驗結果與分析 40 3.3.1 紫外光光分解甲基橙 40 3.3.2 可見光輔助表面電漿共振光觸媒光分解甲基橙 43 第四章 結論 46 參考文獻 47 | |
| dc.language.iso | zh-TW | |
| dc.subject | 光觸媒 | zh_TW |
| dc.subject | 廢水處理 | zh_TW |
| dc.subject | 旋轉盤反應器 | zh_TW |
| dc.subject | 表面電漿共振 | zh_TW |
| dc.subject | 氧化鋅 | zh_TW |
| dc.subject | Plasmonics | en |
| dc.subject | Rotating Disk Reactor | en |
| dc.subject | Water Treatment | en |
| dc.subject | Zinc Oxide | en |
| dc.subject | Photocatalysis | en |
| dc.title | 新穎表面電漿光觸媒光碟片 | zh_TW |
| dc.title | Novel Plasmonic Photocatalytic Optical Disc | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳紀聖(Jeffrey Chi-Sheng Wu),周趙遠鳳(Yuan-Fong Chau),董奕鍾(Yi-Chung Tung) | |
| dc.subject.keyword | 光觸媒,氧化鋅,表面電漿共振,旋轉盤反應器,廢水處理, | zh_TW |
| dc.subject.keyword | Photocatalysis,Zinc Oxide,Plasmonics,Rotating Disk Reactor,Water Treatment, | en |
| dc.relation.page | 54 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2012-07-23 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 應用物理所 | zh_TW |
| 顯示於系所單位： | 應用物理研究所 | |
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