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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯(Ching-Wen Chiu) | |
| dc.contributor.author | Chih-Hsun Liu | en |
| dc.contributor.author | 劉芷薰 | zh_TW |
| dc.date.accessioned | 2021-06-07T17:57:28Z | - |
| dc.date.copyright | 2012-08-19 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-08-13 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/15993 | - |
| dc.description.abstract | 由近三、四十年的科學發展中可知，氮異環碳烯的合成與應用已經愈來愈廣泛，除常見的使用其作為有機金屬化合物的配基之外，近期也被利用在孔洞材料的合成。目前多芽的氮異環碳烯都以有機分子為骨架，其合成多仰賴多步驟的有機合成反應，而且每改變骨架結構就必須更改新的合成步驟，所以多芽的氮異環碳烯的研究就仍屬少數。在本篇研究報告中，我們利用自組裝的概念，以具有氮異環碳烯與酸根的有機配基為組裝單體，並以金屬簇或金屬氧化物作為多芽氮異環碳烯的骨架，合成出多種具不同對稱性的多芽氮異環碳烯。這些金屬簇團的選擇包含了鋅、銅、鈷、鐵的化合物，其結構則可為水車狀的四芽氮異環碳烯與正八面體的六芽氮異環碳烯等。這些具高對稱性的多芽氮異環碳烯將可做為金屬有機骨架材料（Metal-Organic Framwork）中非常具有潛力的配基。 | zh_TW |
| dc.description.abstract | For more than decades, the syntheses and coordination chemistry of N-heterocyclic carbenes remain one of the most popular fields of chemical research. Recent development in NHCs showed that the role of NHC has shifted from a strong donating ligand in metal complexes to the bridging unit in oligomeric and polymeric materials. Nowadays all of the reported poly-NHCs are synthesized via stepwise procedures with organic molecular backbones. When one would like to change the symmetry of poly-NHCs, a new molecular backbone and, possibly, new synthetic route has to be applied. This may be the reason why the research of poly-NHCs is still limited. In this work, we synthesized a bifunctional ligand, which features an imidazolium unit on one side of the molecule and a carboxylic acid group on the other side, and investigated its potential in forming poly-NHCs via assembly approach. The resulting poly-NHC ligands are envisioned to possess numerous geometries with metal-cluster or metal-oxide cluster as molecular backbone. The selection of metal ions includes zinc, copper, cobalt and iron, and the structure of poly-NHCs can range from low-symmetric C2 ligand to highly symmetric paddle wheel and octahedral geometry. All of these poly-NHCs are potential bridging ligands for metal-organic framework. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T17:57:28Z (GMT). No. of bitstreams: 1 ntu-101-R99223184-1.pdf: 2231137 bytes, checksum: 2bb30438fa49ae2784245a1badfb0bf1 (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 謝誌 I
摘要 II Abstract III Table of Contents IV List of Figures VII List of Schemes IX Chapter 1 Introduction 1 1-1 Introduction of the N-heterocyclic carbene (NHC) 1 1-2 Synthesis of azolium salts as the NHC precursors 3 1-3 The properties of the NHCs 5 1-4 The development of the poly NHCs 8 1-4-1 Chelating-type NHCs 9 1-4-2 Bridging-type poly NHCs 11 1-5 Research Aim 15 Chapter 2 Method 17 2-1 The assembly platform for poly-NHC 17 2-2 Molecular design 19 2-3 Synthesis of the bifunctional ligand 20 2-4 Syntheses of poly imidazolium metal clusters 22 Chapter 3 Experimental Section 29 3-1 General consideration 29 3-2 Syntheses of the compound 1–8 29 3-2-1 Synthesis of the compound 2 29 3-2-2 Synthesis of the compound 3 30 3-2-3 Synthesis of the compound 4 31 3-2-4 Synthesis of the compound 5-6 32 3-2-5 Synthesis of the compound 7 33 3-2-6 Synthesis of the compound 8 34 3-3 Syntheses of the crystals 9–16 35 3-3-1 Synthesis of the crystal 9 35 3-3-2 Synthesis of the crystal 10 35 3-3-3 Synthesis of the crystal 11 35 3-3-4 Synthesis of the crystal 12 36 3-3-5 Synthesis of the crystal 13 36 3-3-6 Synthesis of the crystal 14 36 3-3-7 Synthesis of the crystal 15 37 3-3-8 Synthesis of the crystal 16 38 Conclusion 39 References 40 AppendixⅠ NMR 45 AppendixⅡ Syntheses of poly imidazolium metal clusters 51 AppendixⅢ Crystal data 68 | |
| dc.language.iso | en | |
| dc.subject | 鈷錯合物 | zh_TW |
| dc.subject | 氮異環碳烯 | zh_TW |
| dc.subject | 鋅錯合物 | zh_TW |
| dc.subject | N-Heterocyclic Carbene | en |
| dc.subject | zinc complex | en |
| dc.subject | cobalt complex | en |
| dc.title | 以自組裝方法合成無機骨架之多芽氮異環碳烯 | zh_TW |
| dc.title | Inorganic Backbone for Poly N-Heterocyclic Carbenes via Self-Assembly Approach | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 100-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 鄭淑芬(Soofin Cheng),張裕煦(Yu-Hsu Chang) | |
| dc.subject.keyword | 氮異環碳烯,鋅錯合物,鈷錯合物, | zh_TW |
| dc.subject.keyword | N-Heterocyclic Carbene,zinc complex,cobalt complex, | en |
| dc.relation.page | 76 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2012-08-14 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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