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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭淑芬(Soo-fin Cheng) | |
| dc.contributor.author | Yi-Chieh Chen | en |
| dc.contributor.author | 陳奕价 | zh_TW |
| dc.date.accessioned | 2021-06-07T17:50:51Z | - |
| dc.date.copyright | 2012-11-22 | |
| dc.date.issued | 2012 | |
| dc.date.submitted | 2012-11-08 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/15727 | - |
| dc.description.abstract | 本研究在鹼性條件(pH8-10)下利用共沉澱法合成，以陽離子型界面活性劑CTEABr(Cetyltriethylammonium bromide)作為模板，矽源為sodium silicate (Na2SiO3)，加入NaAlO2作為鋁源來合成不同孔洞結構之含鋁介孔二氧化矽。利用不同陰離子來調控孔洞結構，其中(Cl-與NO3-)可以分別得到具有三維立方堆積孔洞結構(3D-cubic，Pm3n)之介孔材料SBA-1-alk與二維六方堆積孔洞結構(2D-hexagonal，p6mm)之介孔材料HMM-alk，加入的鋁金屬含量達到Al/Si=5％。接著將矽源換成ZSM-5沸石晶種合成具有結晶性孔壁的ZSBA-1-alk結構，並以CTMABr作為模板合成二維六方堆積孔洞結構MCM-41分別與非晶相孔壁的Al-SBA-1-alk和Al-HMM-alk做比較。所合成的材料經由XRD、N2 adsorption-desorption isotherm、FT-IR、Al-NMR 和TPD等技術鑑定，可得知所合成出來的材料有很好的二維或三維介孔結構、表面積達到900 m2/g、加入晶種的ZSBA-1-alk酸含量比SBA-1-alk高，孔壁具有ZSM-5的結晶性、大部分的鋁離子是在骨架的四面體中心。最後利用所製備含鋁介孔材料作為酸觸媒，催法2,4-di-tert-butylphenol及cinnamyl alcohol的烷基化反應，結果三維立方堆積的Al-SBA-1-alk催化活性高於二維六方堆積的Al-MCM-41及Al-HMM-alk，而含沸石晶種的5Al-ZSBA-1-alk的催化效果最好，flavan的產率在95 °c反應4小時可以達到56％(mol/g catal)。 | zh_TW |
| dc.description.abstract | Al-incorporated 3D-cubic(Pm3n) SBA-1-alk and 2D-hexagonal(p6mm) HMM-alk were synthesized by one-pot method in alkaline condition (pH=8-10) by using CTEABr (Cetyltriethylammonium bromide) as the template NaAlO2 as Al source, and Na-silicate as the silica source in the presence of NO3- and Cl- anions, respectively. Furthermore, Al-incorporated ZSM-5 seeds were used as the Al and Si sources to synthesize cubic Al-ZSBA-1-alk. Meanwhile, Al-MCM-41 was compared using CTMABr as the template in order to compared the properties with Al-SBA-1-alk and Al-HMM-alk. The resultant materials were characterized by X-ray diffraction (XRD), N2 adsorption-desorption isotherm, FT-IR, Al-NMR and TPD. The small-angle XRD patterns of Al-SBA-1-alk and Al-HMM-alk confirmed the 3-D cubic Pm3n phase and 2-D hexagonal p6mm phases. ZSBA-1-alk exhibited an absorption band at 550 cm-1 in the FT-IR spectrum, which is assigned to the stretching of five-membered T-O-T (T = Si or Al) rings in ZSM-5. In Al-NMR most Al is assigned to the tetrahedrally-coordinated Al species The materials were tested as catalysts in alkylation of 2,4-di-tert-butylphenol with cinnamyl alcohol.3D-cubic Al-SBA-1-alk showed better activity than 2D-hexagonal Al-HMM-alk and Al-MCM-41, while 5Al-ZSBA-1-alk gave the best catalyst activity and yield reached 56％(mol/g catal) at 95 °C in 4 hours. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T17:50:51Z (GMT). No. of bitstreams: 1 ntu-101-R99223169-1.pdf: 2677291 bytes, checksum: 50a5c6c9c3140a93405614d55cd664cf (MD5) Previous issue date: 2012 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 圖目錄 V 表目錄 Ⅶ 第一章 緒論 1 1-1 界面活性劑微胞性質及介孔材料SBA-1的簡介 1 1-2堆積參數(g)對微胞結構的影響 8 1-3鹼式法與酸式法生成SBA-1之性質比較 10 1-4 沸石的簡介 11 1-5沸石奈米粒子自組裝之介孔分子篩材料簡介 13 1-6研究目的 15 第二章 實驗部分 16 2-1 化學藥品 16 2-2 合成步驟 17 2-2-1合成界面活性劑CTEABr(Hexadecyltriethylammonium bromide) 17 2-2-2鹼式法合成Al-SBA-1-alk 17 2-2-3鹼式法合成Al-HMM-alk 17 2-2-4合成Al-MCM-41 18 2-2-5以Al-ZSM-5為晶種的SBA-1-alk(簡稱Al-ZSBA-1-alk)之合成 18 2-3鑑定介孔材料之儀器與方法 19 2-4催化反應 24 2-5產物及反應物鑑定 26 第三章 結果與討論 28 3-1界面活性劑的鑑定 28 3-2 純矽SBA-1-alk的結構鑑定 29 3-3 含鋁的SBA-1-alk(簡稱Al-SBA-1-alk)與含鋁及ZSM-5晶種的ZSBA-1-alk(簡稱Al-ZSBA-1-alk)介孔分子篩之合成與鑑定 30 3-4 Al-HMM-alk與Al-MCM-41材料結構鑑定 36 3-5催化反應 44 第四章 結論 51 第五章 參考文獻 52 | |
| dc.language.iso | zh-TW | |
| dc.title | 不同結構之含鋁介孔材料之合成與催化反應比較 | zh_TW |
| dc.title | Preparation and catalytic activities of Al-incorporated mesoporous material with different structures | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 蔡 蘊 明(Yeun-Min Tsai),簡 淑 華(Shu-Hua Chien) | |
| dc.subject.keyword | 含鋁中孔洞材料,界面活性劑,催化反應, | zh_TW |
| dc.subject.keyword | mesoporous material,SBA-1,CTEABr,catalytic reaction, | en |
| dc.relation.page | 55 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2012-11-08 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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