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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 康敦彥(Dun-Yen Kang) | |
| dc.contributor.author | Ta-Lun Tao | en |
| dc.contributor.author | 陶大倫 | zh_TW |
| dc.date.accessioned | 2021-06-07T17:50:15Z | - |
| dc.date.copyright | 2020-08-04 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-03 | |
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Xu, M.-x.; He, Y.; Wang, Y.-p.; Cui, X.-m., Preparation of a non-hydrothermal NaA zeolite membrane and defect elimination by vacuum-inhalation repair method. Chem. Eng. Sci. 2017, 158, 117-123. 45. Chen, Z.; Yang, J.; Yin, D.; Li, Y.; Wu, S.; Lu, J.; Wang, J., Fabrication of poly(1-vinylimidazole)/mordenite grafting membrane with high pervaporation performance for the dehydration of acetic acid. J. Membr. Sci. 2010, 349 (1), 175-182. 46. Chen, Z.; Yin, D.; Li, Y.; Yang, J.; Lu, J.; Zhang, Y.; Wang, J., Functional defect-patching of a zeolite membrane for the dehydration of acetic acid by pervaporation. J. Membr. Sci. 2011, 369 (1), 506-513. 47. Zhang, B.; Wang, C.; Lang, L.; Cui, R.; Liu, X., Selective Defect-Patching of Zeolite Membranes Using Chemical Liquid Deposition at Organic/Aqueous Interfaces. Adv. Funct. Mater. 2008, 18 (21), 3434-3443. 48. Tang, Z.; Dong, J.; Nenoff, T. M., Internal Surface Modification of MFI-Type Zeolite Membranes for High Selectivity and High Flux for Hydrogen. Langmuir 2009, 25 (9), 4848-4852. 49. Yan, Y.; Davis, M. E.; Gavalas, G. R., Preparation of highly selective zeolite ZSM-5 membranes by a post-synthetic coking treatment. J. Membr. Sci. 1997, 123 (1), 95-103. 50. Xu, C.; Guo, Y.; Xiao, Q.; Zhong, Y.; Zhu, W., Synthesis and characterization of large, pure mordenite crystals. JPMat 2012, 19 (5), 847-852. 51. Itabashi, K.; Kamimura, Y.; Iyoki, K.; Shimojima, A.; Okubo, T., A Working Hypothesis for Broadening Framework Types of Zeolites in Seed-Assisted Synthesis without Organic Structure-Directing Agent. J. Am. Chem. Soc. 2012, 134 (28), 11542-11549. 52. Zou, C.; Lin, L.-C., Exploring the potential and design of zeolite nanosheets as pervaporation membranes for ethanol extraction. ChemComm 2018, 54 (94), 13200-13203. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/15698 | - |
| dc.description.abstract | 沸石薄膜廣泛的應用於滲透蒸發進行乙醇除水分離。在本研究中，我們提出一項新穎的合成後處理技術—大氣電漿(atmospheric-pressure plasma jet)，目的為提昇沸石薄膜對於醇類除水的分離效能。本論文中我們以FER、MOR、FER-MOR hybrid三種沸石薄膜作為研究的對象。經大氣電漿處理後，三種沸石薄膜之分離選擇率皆有所提升，FER沸石薄膜的水/乙醇選擇率由93提升至377；MOR沸石薄膜由141上升至286；FER-MOR hybrid沸石薄膜則由178上升至315，並可以在FER與MOR兩種沸石薄膜中觀察到分離水通量些微的上升。我們利用不同的材料檢測方法來釐清大氣電漿對於薄膜效能上升的機制為何。在大氣電漿作用之下，沸石薄膜的結晶性以及空氣通透性降低，這表明沸石薄膜晶界中的部份針孔缺陷可能因此減少，部分解釋了水/乙醇分離選擇率提升的原因。此外，在經過大氣電漿處理後的沸石薄膜表面經由水接觸角的量測顯示出表面變得更加親水，這是另一個增進水/乙醇分離效能的原因。我們預期大氣電漿處理技術將能夠有效套用於其他構型種類之沸石薄膜，並應用於乙醇除水分離程序中。 | zh_TW |
| dc.description.abstract | Zeolite membranes are widely used for the dehydration of alcohol via pervaporation. This work presents a novel post-synthesis atmospheric-pressure plasma jet (APPJ) treatment aimed at enhancing the water/ethanol separation factor for FER, MOR, and FER-MOR hybrid zeolite membranes. APPJ treatment was shown to increase the separation factor of the three membranes as follows: FER (93 to 377), MOR (141 to 286), and FER-MOR (178 to 315). Pure FER zeolite and MOR membranes increased the water flux slightly. APPJ treatment was shown to reduce crystallinity and air permeability, which suggests a partial elimination of pinholes at grain boundaries in the zeolite membranes and may partially explain the improvement in water/ethanol separation performance. The hydrophilic surface of the APPJ-treated samples, characterized by the water contact angle measurement, may also contribute to the improved separation performance. Note that the proposed APPJ treatment scheme is also applicable to other types of zeolite membrane for alcohol dehydration. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-07T17:50:15Z (GMT). No. of bitstreams: 1 U0001-0308202013481800.pdf: 4746681 bytes, checksum: e36238577e2d1e5af7e4600095eca338 (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 口試委員會審定書 I 致謝 II 摘要 III Abstract IV 目錄 V 圖目錄 VII 第一章 緒論 1 1-1 前言 1 第二章 文獻回顧 3 2-1 沸石 (Zeolite) 3 2-1-1 沸石簡介 3 2-1-2 沸石分子篩孔道結構 4 2-1-3 沸石薄膜應用 5 2-2 膜分離—滲透蒸發 (Pervaporation) 6 2-2-1 滲透蒸發簡介 6 2-2-2 沸石薄膜於滲透蒸發上的發展情況 6 2-2-3 沸石薄膜所面臨的挑戰 7 2-3 研究目的 8 第三章 實驗步驟 9 3-1 化學藥品 9 3-2 沸石粉體合成 10 3-2-1 FER 沸石粉體合成 10 3-2-2 MOR 沸石粉體合成 10 3-3 沸石晶種層沉積 11 3-3-1 FER 沸石晶種層沉積 12 3-3-2 MOR 沸石晶種層沉積 13 3-4 沸石薄膜合成 14 3-4-1 FER 沸石薄膜合成 14 3-4-2 FER-MOR hybrid 沸石薄膜合成 14 3-4-3 MOR 沸石薄膜合成 15 3-5 大氣電漿後處理 15 3-6 檢測儀器 16 3-6-1 X光繞射儀 (X-ray Diffraction, XRD) 16 3-6-2 場發射掃描式電子顯微鏡 (Field Emission Scanning Electron Microscope, FE-SEM) 16 3-6-3 能量散佈光譜儀 (Energy Dispersive Spectrometer, EDS) 17 3-6-4 接觸角量測儀 (Contact Angle Goniometer) 17 3-6-5 滲透蒸發儀 (Pervaporation, PV) 18 3-6-6 氣相層析儀 (Gas Chromatograph, GC) 19 3-6-7 大氣電漿 (Atmospheric Pressure Plasma Jet, APPJ) 20 3-6-8 薄膜空氣透過率量測裝置 (Setup for Measuring Membrane Air Permeation) 21 第四章 結果與討論 23 4-1 沸石結構鑑定與分析 23 4-1-1 沸石粉體合成 23 4-1-2 沸石晶種層沉積 25 4-1-3 沸石薄膜合成 27 4-1-4 沸石薄膜大氣電漿處理前後之比較 31 4-2 沸石薄膜滲透蒸發效能探討 37 4-2-1 As-synthesized沸石薄膜滲透蒸發效能 37 4-2-2 電漿後處理沸石薄膜滲透蒸發效能 38 第五章 結論與未來展望 46 參考文獻 48 | |
| dc.language.iso | zh-TW | |
| dc.subject | 缺陷修補 | zh_TW |
| dc.subject | 沸石薄膜 | zh_TW |
| dc.subject | 滲透蒸發 | zh_TW |
| dc.subject | 大氣電漿 | zh_TW |
| dc.subject | 醇類除水 | zh_TW |
| dc.subject | atmospheric-pressure plasma jet | en |
| dc.subject | alcohol dehydration | en |
| dc.subject | zeolite membrane | en |
| dc.subject | pervaporation | en |
| dc.subject | defect repairing | en |
| dc.title | 大氣電漿處理之沸石複合薄膜於滲透蒸發的應用 | zh_TW |
| dc.title | Atmospheric Plasma Treated Hybrid Zeolite Membranes for Pervaporation | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 游文岳(Wen-Yueh Yu),羅世強(Shyh-Chyang Luo),江佳穎(Chia-Ying Chiang) | |
| dc.subject.keyword | 沸石薄膜,滲透蒸發,大氣電漿,醇類除水,缺陷修補, | zh_TW |
| dc.subject.keyword | zeolite membrane,pervaporation,atmospheric-pressure plasma jet,alcohol dehydration,defect repairing, | en |
| dc.relation.page | 51 | |
| dc.identifier.doi | 10.6342/NTU202002266 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-08-04 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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