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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/100155完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭如忠 | zh_TW |
| dc.contributor.advisor | Ru-Jong Jeng | en |
| dc.contributor.author | 謝忠達 | zh_TW |
| dc.contributor.author | Chung-Ta Hsieh | en |
| dc.date.accessioned | 2025-09-24T16:40:39Z | - |
| dc.date.available | 2025-09-25 | - |
| dc.date.copyright | 2025-09-24 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-08-01 | - |
| dc.identifier.citation | 1. Koch, G., Cost of corrosion. Trends In Oil and Gas Corrosion Research and Technologies 2017, 3-30.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/100155 | - |
| dc.description.abstract | 鋼材因其優異的機械性質與成本效益，廣泛應用於建築、交通與工業等領域。然而，其在高濕與高鹽環境中極易腐蝕，導致結構劣化與重大資產損失，對經濟與公共安全構成嚴重威脅。傳統防腐塗層多採用溶劑型系統，但其所釋放的揮發性有機化合物(volatile organic compounds)對環境與人體健康造成負擔。為實現低污染且高效能之防腐機制，開發具環境友善性的水性混成塗層已成為材料科學中的重要研究趨勢。 本研究開發一種以高分子分散液為基礎之環保型水性塗層系統，用於鋼鐵(mild steel)之防腐蝕應用。首先，以乙二胺四乙酸二酐(ethylenediaminetetraacetic dianhydride)與2,2-(乙二氧基)雙(乙胺)(2,2-(ethylenedioxy)bis(ethylamine)合成具水溶性的聚酰胺酸(polyamic acid, PAmA)。其分子主鏈中之醚鍵與酰胺酸官能基提供大量極性位點，有助於促進3-甘油氧丙基三甲氧基矽烷(3-glycidoxypropyl trimethoxysilane, GPTMS)形成穩定的水性有機矽烷分散體，且無需額外添加界面活性劑或鹽類。進一步地，系統中最多可以25 wt%之四乙氧基矽烷(tetraethyl orthosilicate)替代GPTMS，以作為交聯劑與奈米二氧化矽前驅物，經最佳化條件製備水性有機/無機混成分散液。 與傳統聚丙烯酸分散液相比，本研究所製備之PAmA基有機/無機分散液經拉曼光譜(Raman spectroscopy)與29Si 核磁共振(29Si-NMR)分析顯示其縮合程度高達94.6%，證實已形成高交聯密度的矽氧網路結構，具被動保護層功能。該塗層在熱重分析中表現出超過380 °C的熱分解溫度，顯示出優異的熱穩定性。此外，PAmA的應用不僅促進交聯反應與矽氧結構生成，亦有助於形成酰亞胺結構，進一步增強塗層系統的結構完整性與化學穩定性，該現象亦由傅立葉轉換紅外光譜(FTIR)與示差掃描量熱分析(DSC)所驗證。 | zh_TW |
| dc.description.abstract | Steel is widely utilized in construction, transportation, and industrial sectors due to its excellent mechanical properties and cost-effectiveness. However, its high susceptibility to corrosion under humid and saline environments often results in structural degradation and significant asset loss, posing serious economic and safety concerns. Conventional anticorrosive coatings predominantly rely on solvent-based systems, which emit volatile organic compounds that are detrimental to both environmental and human health. In pursuit of low-pollution and high-efficiency corrosion protection, the development of eco-friendly waterborne hybrid coatings has become a key research direction in materials science. In this study, an environmentally friendly waterborne coating system was developed using a polymeric dispersion as the base, intended for corrosion protection of mild steel. A water-soluble polyamic acid (PAmA) was first synthesized via the reaction of ethylenediaminetetraacetic dianhydride and 2,2-(ethylenedioxy)bis(ethylamine). The incorporation of ether linkages and amic acid functional groups into the polymer backbone introduces numerous polar sites, which facilitate the formation of a stable aqueous silane dispersion primarily composed of 3-glycidoxypropyl trimethoxysilane (GPTMS), without the need for surfactants or salts. Up to 25 wt% of GPTMS can be replaced with tetraethyl orthosilicate , which functions as a crosslinking agent and a precursor to nanosilica, thereby forming an aqueous organic/inorganic hybrid dispersion under optimized conditions. Compared with reference samples such as polyacrylic acid dispersions, the PAmA-based organic/inorganic dispersion exhibited a high degree of condensation (94.6%) as confirmed by Raman spectroscopy and ²⁹Si nuclear magnetic resonance (²⁹Si-NMR), indicating the formation of a highly crosslinked siloxane network. This structure acts as a passive layer and contributes to the thermal decomposition temperature of the hybrid coating exceeding 380 °C, as demonstrated by thermogravimetric analysis. The presence of PAmA not only enhances the crosslinking density and silica network formation but also facilitates the development of imide structures, resulting in a more robust sol-gel derived hybrid coating system. These observations are consistent with findings from Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) analyses. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-09-24T16:40:39Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-09-24T16:40:39Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 誌謝 i
摘要 ii Abstract iii 目次 iv 圖次 vi 表次 viii 第一章 緒論 1 1-1 前言 1 第二章 文獻回顧 4 2-1 功能性塗層的發展與應用 4 2.1.1 工業與環境應用背景 8 2.1.2 功能性塗層分類與效能需求 12 2-2 聚合物塗層材料 14 2-3 鋼鐵材料 19 2.3.1 腐蝕的定義 20 2.3.2 鋼板腐蝕的機理 21 2.3.3 鋼板腐蝕的環境 24 2.3.4 鋼板腐蝕的防護方法 25 2.3.5 不同防腐蝕塗層探討 26 2-4 溶膠-凝膠法 36 2.4.1 有機-無機混成材料 38 2.4.2 奈米填料與混成體系 41 2-5 綠色製程 44 2.5.1 綠色化學與防腐塗層的應用 47 2.5.2 綠色化學防腐蝕技術的挑戰與未來趨勢 50 2-6 研究動機 55 第三章 實驗材料與方法 57 3-1 實驗藥品 57 3-2 實驗設備與儀器 58 3-3 實驗製備與步驟 60 3.3.1 聚醯胺酸的製備 60 3.3.2 矽烷分散液的製備 60 3-4 材料鑑定與分析方法 63 3-5 電化學性質評估 67 3-6 腐蝕性質評估 69 第四章 結果與討論 70 4-1 合成具脂肪族主鏈之聚醯胺酸 70 4-2 合成與表徵具脂肪族主鏈之聚醯胺酸 72 4-3 具脂肪族主鏈之PAmA之熱穩定性與熱轉變行為 73 4-4 水性PAmA有機–無機分散液的製備與特性分析 75 4-5 溶膠–凝膠製程應用於有機/無機混成複合材料之研究 77 4-6 混成塗層之熱穩定性與相分析 80 4-7 混成塗層表面親疏水性評估 83 4-8 混成塗層對鋼板腐蝕行為之抑制效能探討 85 4-9 鋼板表面塗層之防腐蝕評估 89 第五章 結論 91 第六章 未來展望 92 參考文獻 94 附錄 103 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 聚酰胺酸 | zh_TW |
| dc.subject | 水溶性 | zh_TW |
| dc.subject | 防腐蝕性 | zh_TW |
| dc.subject | 溶膠-凝膠法 | zh_TW |
| dc.subject | anti-corrosion | en |
| dc.subject | polyamic acid | en |
| dc.subject | sol-gel reaction | en |
| dc.subject | water-soluble | en |
| dc.title | 以水溶性聚醯胺酸為螯合劑之環保型混合材料於鋼材防腐蝕之應用研究 | zh_TW |
| dc.title | Study on Eco-Friendly Hybrid Materials for Steel Corrosion Protection Using Water-Soluble Polyamic Acid as a Chelating Agent | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 博士 | - |
| dc.contributor.oralexamcommittee | 邱文英;鄭有為;吳建欣;黃英治 | zh_TW |
| dc.contributor.oralexamcommittee | Wen-Yen Chiu;Yu-Wei Cheng;Chien-Hsin Wu;Ying-Chih Huang | en |
| dc.subject.keyword | 聚酰胺酸,水溶性,防腐蝕性,溶膠-凝膠法, | zh_TW |
| dc.subject.keyword | polyamic acid,water-soluble,anti-corrosion,sol-gel reaction, | en |
| dc.relation.page | 104 | - |
| dc.identifier.doi | 10.6342/NTU202502544 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2025-08-06 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | - |
| dc.date.embargo-lift | 2030-07-25 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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