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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳俊維(Chun-Wei Chen) | |
dc.contributor.author | Kun-Hua Tu | en |
dc.contributor.author | 杜昆樺 | zh_TW |
dc.date.accessioned | 2021-05-20T20:45:38Z | - |
dc.date.available | 2020-07-01 | |
dc.date.available | 2021-05-20T20:45:38Z | - |
dc.date.copyright | 2011-08-12 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-08 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/9858 | - |
dc.description.abstract | 有機高分子太陽能電池具有低成本、可撓曲且能大面積製造的優勢,因而吸引大家廣泛的興趣。然而,目前高分子太陽能電池在應用上還有一些不利的因素,其陽極材料氧化銦錫透明電極不易撓曲且價格日益升高,電洞傳輸層PEDOT:PSS 有吸濕性且容易在紫外光下衰退,陰極的低功函數金屬則是在大氣中容易氧化不穩定。因此,此研究的目的是利用奈米碳材穩定的化學性質以及其良好的導電和可撓曲特性,藉以取代原本高分子太陽能電池中陰陽極和電洞傳輸層的材料,發展出以奈米碳材為基材的高分子太陽能電池。其一是以一維奈米碳管為透明導電電極,二維氧化態石墨烯為電洞傳輸層,兩者結合做為高分子太陽能電池的陽極平台,此元件表現出與一般元件接近的光電轉換效率,且具有可撓曲、可水溶液製程且大面積製造的優點。另外則是分別以n型及p型摻雜後的石墨烯做為太陽能電池中的陰陽極,發展出可以用roll-to-roll連續卷軸生產方式的元件,加上其半透明且可撓曲的優點,更有利於未來低成本製造和多元的應用。這兩種以奈米碳材維基材的高分子太陽能電池,成功結合了奈米碳材與高分子太陽能電池的優點,充分展現了其未來在生產及實際應用上的潛力。 | zh_TW |
dc.description.abstract | Polymer solar cells have attracted a great interest for fabricating low-cost large-area mechanically flexible photovoltaic devices compared to the conventional inorganic counterparts. But the conventionally used ITO anode, PEDOT:PSS, and the low work function metal cathode all have its own shortcomings, hindering the devices from practical application. In this research, we would like to demonstrate new architectures of polymer solar cells based on allotropes of carbon nanomaterials, by utilizing p-type doped graphene or single walled carbon nanotube (SWNT) thin film as the anode, graphene oxide (GO) as the hole transport layer, n-type doping graphene as the cathode, and fullerene derivative PCBM/P3HT bulk heterojunctions as the photoactive layer. The photovoltaic device based on the solution processed SWNT/GO platform has exhibited good power conversion efficiency of 3.1% as compared to the conventional device (PCE=3.57%). And the new innovation of polymer solar cell based on all-graphene electrodes provides a potential route to develop a flexible, semitransparent photovoltaic device which can be fully integrated with the low-cost, roll-to-roll fabrication process. By overcoming the drawbacks of polymer solar cells, these two approaches have shown the potential of serving the long-term solutions for the future energy supply. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T20:45:38Z (GMT). No. of bitstreams: 1 ntu-100-R98527030-1.pdf: 6550373 bytes, checksum: 490bbc3a3f7866ca32107d0526c1f429 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 口試委員會審定書 I
Acknowledgements II 摘要 IV Abstract V Contents VI List of Figures IX List of Tables XIII List of Publications XIV Chapter 1 Introduction 1 1.1. The demand for alternative energy 2 1.2. Conventional inorganic solar cell 3 1.3. Organic/polymer photovoltaics 5 1.4. Carbon based nanomaterials 10 1.4.1. Fullerene and fullerene derivatives 10 1.4.2. Single walled carbon nanotube 11 1.4.3. Graphene 15 1.5. Research motivation 17 1.6. Reference 18 Chapter 2 Experimental setup 21 2.1. Solar cell characterization 22 2.1.1. Air mass 1.5 solar spectrum 22 2.1.2. External quantum efficiency 23 2.1.3. Transient photovoltage (TPV) 24 2.2. Transparent conducting electrode characterization 26 2.2.1. UV-visible spectroscopy 26 2.2.2. Sheet resistance measurement 26 2.3. Raman spectroscopy 28 2.4. Surface morphology and surface potential measurement 30 2.4.1. Atomic force microscopy (AFM) 30 2.4.2. Kevin probe force microscopy (KPFM) 32 2.5. Hall effect measurement 34 Chapter 3 Solution processable nanocarbon platform for polymer solar cells 35 3.1. Introduction 35 3.2. SWNT conducting thin film as transparent electrode 37 3.2.1. The preparation of SWNT electrode 37 3.2.2. Characterization of SWNT electrode 39 3.3. Graphene oxide as hole transport layer in OPVs 42 3.3.1. The preparation of graphene oxide 43 3.3.2. Characterization of graphene oxide 45 3.4. P3HT:PCBM polymer solar cell on the SWNT/GO nanocarbon platform 49 3.4.1. Experimental details 49 3.4.2. Characterization of SWNT/GO platform 51 3.4.3. Solar cell device characteristics 53 3.5. Conclusion 61 3.6. Reference 62 Chapter 4 Polymer solar cells based on all-graphene electrodes 67 4.1. Introduction 67 4.2. Graphene as transparent conducting electrode 70 4.2.1. The synthesis of graphene on copper foil 70 4.2.2. The preparation of graphene electrode 71 4.3. Work function engineering of graphene electrodes by using layer-by-layer doping technique 73 4.3.1. The preparation of p-type doping graphene electrode 74 4.3.2. The preparation of n-type doping graphene electrode 75 4.3.3. Characterization of LbL doped graphene electrode 76 4.4. P3HT:PCBM polymer solar cells with n- and p-type doped graphene electrodes 88 4.4.1. Experimental details 88 4.4.2. Device with p-type doped graphene as the anode 89 4.4.3. Device with n-type doped graphene as the cathode 91 4.4.4. Device with all-graphene electrodes 93 4.5. Conclusion 96 4.6. Reference 97 Chapter 5 Conclusion 102 5.1. Conclusions 102 5.2. Suggestions for future investigations 103 | |
dc.language.iso | en | |
dc.title | 奈米碳材於高分子太陽能電池上之應用 | zh_TW |
dc.title | Nanocarbon Based Polymer Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳學禮,吳季珍 | |
dc.subject.keyword | 石墨烯,單壁奈米碳管,透明導電電極,太陽能電池,水溶液製程, | zh_TW |
dc.subject.keyword | graphene,graphene oxide,single walled carbon nanotube,transparent conducting electrode,polymer solar cell,solution process,roll-to-roll, | en |
dc.relation.page | 104 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2011-08-08 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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