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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 童世煌 | zh_TW |
| dc.contributor.advisor | Shih-Huang Tung | en |
| dc.contributor.author | 陳昱愷 | zh_TW |
| dc.contributor.author | Yu-Kai Chen | en |
| dc.date.accessioned | 2025-08-05T16:06:41Z | - |
| dc.date.available | 2025-08-06 | - |
| dc.date.copyright | 2025-08-05 | - |
| dc.date.issued | 2025 | - |
| dc.date.submitted | 2025-07-30 | - |
| dc.identifier.citation | (1) Liu, H.; Cao, C.; Huang, J.; Chen, Z.; Chen, G.; Lai, Y. Progress on particulate matter filtration technology: basic concepts, advanced materials, and performances. Nanoscale 2020, 12 (2), 437-453.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/98372 | - |
| dc.description.abstract | 空氣中的污染物，包括懸浮微粒 (PM) 、病原體和氣體，對於人體健康帶來了嚴重的挑戰。靜電紡絲技術已成為一種製備奈米纖維的簡便方法，用於分離空氣污染物。在本研究中，透過實驗室所歸納出的成孔機制和條件，製備出具有多孔結構的電紡纖維，並結合製備氣凝膠的技術，除了纖維表面上具有孔洞結構外，將體先的2D纖維薄膜變成3D立和網狀結構可大幅提升比表面積，成功製備出由苯乙烯-丙烯腈共聚物 (SAN) 所構成的具極低密度、高孔隙度的氣凝膠。
由於氣凝膠本身機械性能不足，本研究會加入少量水溶性高分子作為“黏著劑”來黏合分散的SAN電紡纖維，其中以添加聚乙烯醇 (PVA) 的效果最佳，在不破壞纖維孔洞的情況下，不僅提升了最大抗拉強度，所含之高極性的官能基也可提升對PM2.5的吸附能力。而透過比較添加不同水解程度的PVA可發現，相比於低水解程度的PVA，於高水解程度下會產生微孔結構，進一步增加氣凝膠的比表面積，可有效提升吸附PM2.5的能力。 在過濾性能方面，所得的複合氣凝膠展現出高於99 %的高過濾效率，僅66 Pa的低壓降。此外，本研究所使用之分散液為水與酒精，相較於傳統氣凝膠的製程，不僅製備步驟更為簡單且對環境友善。透過調控製程參數可製備出具不同結構的氣凝膠，於空氣污染物過濾應用上展現出巨大潛力。 | zh_TW |
| dc.description.abstract | Airborne pollutants, including particulate matter (PM), pathogens, and gases, pose significant health risks. Electrospinning has emerged as an effective method for producing nanofibers that are ideal for separating air pollutants. Porous electrospun fibers with a porous structure were fabricated based on the pore-forming mechanisms and conditions established in the laboratory. By combining aerogel fabrication techniques, the original 2D fibrous membranes were transformed into 3D network structures, significantly enhancing the specific surface area, resulting in aerogels made from styrene-acrylonitrile (SAN) copolymers that feature ultralow density and high porosity.
To address the aerogel's mechanical limitations, a small amount of water-soluble polymer was added as a ''glue'' to bind the dispersed SAN nanofibers. Among the tested polymers, polyvinyl alcohol (PVA) provided the best results, enhancing tensile strength without disrupting the fiber's pore structure. Furthermore, the polar functional groups in PVA contributed to improved PM2.5 adsorption. By comparing the addition of PVA with different degrees of hydrolysis, PVA with a higher degree of hydrolysis formed microporous structures that further increased the specific surface area of the aerogel compared to PVA with a low degree of hydrolysis. Additionally, the higher number of polar functional groups effectively enhanced its ability to adsorb PM2.5. The composite aerogels demonstrated excellent performance with over 99% filtration efficiency and a low-pressure drop of 66 Pa. Furthermore, using water and alcohol as dispersion made the fabrication process simpler and more environmentally friendly than traditional aerogel methods. The aerogels can be tailored for various structures, offering great potential for air pollutant filtration applications. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2025-08-05T16:06:41Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2025-08-05T16:06:41Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員審定書 i
致謝 ii 摘要 iii Abstract iv 目次 v 圖次 ix 表次 xiv 第一章 緒論 1 1.1 前言與研究動機 1 第二章 文獻回顧 2 2.1 靜電紡絲技術 2 2.1.1 概述 2 2.1.2 電紡裝置及原理 2 2.1.3 影響電紡纖維的條件與參數 6 2.2 多孔纖維的成孔機制 8 2.2.1 呼吸圖法 (Breath Figure, BF) 8 2.2.2 蒸氣誘導相分離 (Vapor Induced Phase Separation, VIPS) 10 2.2.3 非溶劑誘導相分離法 (Nonsolvent Induced Phase Separation, NIPS) 11 2.2.4 熱誘導相分離法 (Thermally Induced Phase Separation, TIPS) 12 2.2.5 水溶性溶劑輔助呼吸圖法 (Water-Miscible Solvent Assistant Breath Figure, WMSBF) 13 2.3 氣凝膠介紹 15 2.3.1 概述 15 2.3.2 氣凝膠機械性質的探討 17 2.4 PM2.5空氣過濾應用 21 2.4.1 空氣懸浮粒子介紹 21 2.4.2 空氣懸浮粒子淨化方法 21 2.4.3 影響空氣懸浮粒子過濾效率的因素及機制 23 第三章 實驗內容 25 3.1 實驗材料 25 3.1.1 高分子 25 3.1.2 溶劑與鹽類 26 3.2 電紡裝置 28 3.3 實驗儀器 28 3.4 實驗步驟與儀器原理 29 3.4.1 製備靜電紡絲纖維薄膜 29 3.4.2 製備纖維氣凝膠 30 3.4.3 溶劑蒸氣法 (Solvent Vapor Treatment) 31 3.4.4 空氣懸浮微粒過濾測試 32 3.4.5 場發射掃描式電子顯微鏡 (Field Emission-Scanning Electron Microscopy, FE-SEM) 33 3.4.6 冷凍乾燥機 (Freeze Dryer) 35 3.4.7 接觸角量測儀 (Contact Angle Analyzer) 36 3.4.8 壓汞測孔儀 (Mercury Injection Apparatus) 37 3.4.9 紅外線衰減全反射光譜（Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy, ATR-IR） 38 3.4.10 示差掃描熱量分析儀 (Differential Scanning Calorimetry, DSC) 39 3.4.11 萬能拉伸試驗機 (Universal Tensile Tester, UTM) 40 第四章 結果與討倫 41 4.1 氣凝膠的製備方法 41 4.1.1 靜電紡絲的形貌 42 4.1.2 找尋分散SAN孔洞纖維之攪拌液溶劑 43 4.1.3 調配不同溶劑組合之攪拌溶液 44 4.1.4 SAN孔洞纖維分散液之最佳重量濃度 49 4.1.5 改變纖維形貌製備平滑纖維氣凝膠 51 4.2 各樣品命名方式 52 4.3 改善孔洞纖維氣凝膠的機械性質 54 4.3.1 溶劑蒸氣法 (Solvent Vapor Treatment) 54 4.3.2 加入水溶性高分子 55 4.4 不同水解程度PVA對孔洞纖維氣凝膠形貌、化學組成及機械性質之影響 60 4.4.1 不同水解程度的PVA在複合氣凝膠中的形貌 60 4.4.2 探討複合氣凝膠的化學組成 62 4.4.3 探討複合氣凝膠的機械性質 65 4.5 不同水解程度PVA對孔洞纖維氣凝膠熱性質、親疏水性及孔洞結構變化之影響 68 4.5.1 複合氣凝膠的熱性質分析 68 4.5.2 探討纖維薄膜與各氣凝膠的親疏水性 70 4.5.3 複合氣凝膠及纖維薄膜的孔洞尺寸與結構 71 4.5.4 複合氣凝膠與纖維薄膜之孔隙度及孔徑分布 76 4.6 過濾空氣懸浮微粒PM2.5之應用 79 4.6.1 探討複合氣凝膠之過濾效率 80 4.6.2 複合氣凝膠過濾前後之元素分析 87 4.6.3 探討不同風速對於過濾效率的影響 89 4.6.4 材料過濾性能之文獻比較 92 第五章 結論 93 參考文獻 94 附錄 105 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 靜電紡絲 | zh_TW |
| dc.subject | 呼吸圖法 | zh_TW |
| dc.subject | 多孔纖維 | zh_TW |
| dc.subject | 氣凝膠 | zh_TW |
| dc.subject | 空氣懸浮微粒PM2.5 | zh_TW |
| dc.subject | Breath figure | en |
| dc.subject | Electrospinning | en |
| dc.subject | PM2.5 filtration | en |
| dc.subject | Aerogel | en |
| dc.subject | Porous fibers | en |
| dc.title | 製備苯乙烯-丙烯腈共聚物多孔纖維氣凝膠應用於 空氣懸浮微粒過濾 | zh_TW |
| dc.title | Preparation of poly(styrene-co-acrylonitrile) porous fiber aerogels for particulate matter filtration | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 113-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 邱昱誠;陳錦文;賴偉淇 | zh_TW |
| dc.contributor.oralexamcommittee | Yu-Cheng Chiu;Chin-Wen Chen;Wei-Chi Lai | en |
| dc.subject.keyword | 靜電紡絲,呼吸圖法,多孔纖維,氣凝膠,空氣懸浮微粒PM2.5, | zh_TW |
| dc.subject.keyword | Electrospinning,Breath figure,Porous fibers,Aerogel,PM2.5 filtration, | en |
| dc.relation.page | 109 | - |
| dc.identifier.doi | 10.6342/NTU202503030 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2025-08-01 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | - |
| dc.date.embargo-lift | 2025-08-06 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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| ntu-113-2.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 7.57 MB | Adobe PDF |
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