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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
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dc.contributor.advisor | 白書禎 | |
dc.contributor.author | Ai-Hua Ning | en |
dc.contributor.author | 甯愛華 | zh_TW |
dc.date.accessioned | 2021-05-20T20:42:00Z | - |
dc.date.available | 2009-07-24 | |
dc.date.available | 2021-05-20T20:42:00Z | - |
dc.date.copyright | 2008-07-24 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-07-21 | |
dc.identifier.citation | APHA, 1992. Standard methods for the examination of water and wastewater. 18th, Washington D. C., 4-85~4-91
Armstrong, F. A. J., 1963. Determination of nitrate in water by ultraviolet spectrophotometry. Analytical Chemistry, Vol. 35, pp. 1292 Bianchi, T., S., 2007. Biogeochemistry of estuaries. Oxford University Press, Inc. New York Chow, T. J., Johnstone, M. S., 1962. Determination of nitrate in sea water. Analytica Chimica Acta., Vol. 27, pp. 441 Frank, J. M., 2006. Chemical oceanography. 3rd, CRC Press, pp. 305-314 Grasshoff, K., 1999. in Grasshoff, K., Ehrhardt, M., Kremling, K. eds., Methods of seawater analysis. 3rd, Verlag Chemie, Weinheim, pp. 180-186 Griess, P., 1879. Bemerkungen zu der Abhandlung der H.N. Weselky und Benedikt Ueber einege Azoverbindungen. Berichte der Deutschen chemischen Gesellschaft, Vol. 12, pp. 426-428 Head, P. C.,1985. Practical estuarine chemistry. Cambridge University Press, Inc. pp. 98-109 Hobbie, J. E., 2000. Estuarine science : a synthetic approach to research and practice. Island Press, Washington DC, pp. 1-11 Jenkins, D., Medsker, L. L., 1964. Brucine method for determination of nitrate in ocean estuarine + fresh waters. Analytical Chemistry, Vol. 36, pp. 610-612 Langmuir, D., Jacobson, R. L., 1970. Specific-ion electrode determination of nitrate in some freshwater and sewage effluents. Environmental science & technology, Vol. 4, pp. 834 Libes, S. M., 1992. An introduction to marine biogeochemistry. John Wiley & Sons, Inc. New York, pp. 154-155 Liu, K. K., Kao, S. J., Wen, L. S., Chen, K. L., 2007. Carbon and nitrogen isotopic compositions of particulate organic matter and biogeochemical processes in the eutrophic Danshuei Estuary in northern Taiwan. Science of the total environment, Vol. 382, pp. 103-120 Morris, A. W., Riley, J. P., 1963. The determination of nitrate in sea water. Analytica Chimica Acta., Vol. 29, pp. 272-279 Mullin, J. B., Riley, J. P., 1955. The spectrophotometric determination of nitrate in natural waters, with particular reference to sea-water. Analytica Chimica Acta, Vol. 12, pp. 464-480 Pai, S. C., Yang, C. C., 1990. Formation kinetics of pink azo dye in the determination of nitrite in natural waters. Analytica Chimica Acta, Vol. 232, pp. 345-349 Pai, S. C., Riley, J. P., 1994. Determination of nitrate in the presence of nitrite in natural waters by flow injection analysis with a non-quantitative on-line cadmium reductor. Intern. J. Environ. Anal. Chem., Vol. 57, pp. 263-277 Riley, J. P., Chester, R., 1971. Introduction to marine chemistry. Academic Press, London, pp. 152-167 Small, H., Stevens, T. S., Bauman, W. C., 1975. Novel ion-exchange chromatographic method using conductimetric detection. Analytical Chemistry, Vol. 47, pp. 1801-1809 Stainton, M. P., 1974. Simple Efficient reduction column for use in automated determination of nitrate in water. Analytical Chemistry, Vol.46, pp. 1616 Strickland, J. T. H., Parsons, T. R., 1972. A practical handbook of sea water analysis. 2nd, Canadian Museum of Nature, Ottawa, pp. 71-76 Wood, E. D., Armstrong, F. A. J., Richards, F. A., 1967. Determination of nitrate in sea water by cadmium-copper reduction to nitrite. J. Mar. Biol. Ass. U. K., Vol. 47, pp. 23-31 江承濂, 2003. 鎘銅還原法測定水中硝酸鹽實驗條件優化暨無載流自動分析儀之設計. 國立台灣大學理學院海洋研究所碩士論文 施英隆, 2000. 環境化學. 3rd, 五南圖書出版股份有限公司, 台北, pp.570 謝志強, 2007. 自助式無觸硝酸鹽分析儀之研究. 國立台灣大學理學院海洋研究所碩士論文 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/9798 | - |
dc.description.abstract | 當今常以鎘銅還原法作為測定自然水體中硝酸鹽的方法,但河口環境中廣鹽性的樣本,卻會對鎘銅還原法產生干擾。本文利用不同鹽度的標準品,對鎘銅還原法進行分段測試,得知改變樣本的鹽度會影響鎘銅管的還原率,且觀察出緩衝錯合試劑的成分與酸鹼值也會造成還原反應的差異,因而以氯化銨、乙二胺四乙酸的濃度、酸鹼值為試劑變化因子,進行緩衝錯合試劑、鹽度與還原率三者之間的系列實驗,得到最適合測定廣鹽性樣本的緩衝錯合試劑,其成分為4% w/v氯化銨混合0.5% w/v乙二胺四乙酸,並以氫氧化鈉調整酸鹼值至7.5。此緩衝試劑能大幅降低鹽度干擾,且使還原率隨鹽度呈現近似線性的變化。當分析全數樣本後,求得淡、海水標準品的還原率,算出鹽度修正公式( E( S ) = a•S + E( DDW std ), 其中a = ( E( SW std ) – E( DDW std ) ) /ΔS ),將校正後的還原率代入硝酸鹽的計算( [ NO3- ] = { ( Abs total / k NO2- ) - [ NO2- ] } / E( S ) ),即可得到準確的濃度值。 | zh_TW |
dc.description.abstract | The precision and accuracy of the copper-cadmium reduction method for nitrate determination have been evaluated for estuarine waters, and the interference induced by salinity has been studied. An erratic decay trend on the efficiency of the reduction column was found as salinity increases. Further study indicates that the efficiency is closely related to the concentration and pH of the complexing reagents ( NH4Cl or EDTA ) add prior to allowing the sample to pass through the column. Application of a combination of 4% w/v NH4Cl and 0.5% w/v EDTA gives more stable results than using either reagent alone. However, for estuarine samples with a wide salinity, the raw readings still need correction. Empirical formulae are proposed for this purpose:
E ( S ) = a•S + E ( DDW std ) a = ( E ( SW std ) - E ( DDW std ) ) /ΔS [ NO3- ] = { ( Abs total / k NO2- ) - [ NO2- ] } / E (S) where E, a, S, k represent efficiency of the column, slope, salinity, and slope for nitrite respectively. The above equation set provides a more accurate and convenient way to calculate the concentration of nitrate in estuarine environment with salinity ranging from 0 to 35. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T20:42:00Z (GMT). No. of bitstreams: 1 ntu-97-R95241402-1.pdf: 738790 bytes, checksum: d21526481de8b179e173a687ffd2a3e8 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | 口試委員會審定書
誌謝 中文摘要...................................................i 英文摘要..................................................ii 目錄.....................................................iii 圖目錄.....................................................v 表目錄....................................................vi 第一章 緒論...............................................1 1.1 概述...................................................1 1.2 硝酸鹽測定方法的演進...................................2 1.3 硝酸鹽分析方法測定上的盲點.............................3 1.4 研究目標...............................................4 第二章 鹽度對鎘銅還原法測定硝酸鹽的干擾...................6 2.1 概述...................................................6 2.2 鹽度對鎘銅還原法的影響.................................6 2.2.1 亞硝酸鹽呈色的試驗.................................7 2.2.2 鹽度對硝酸鹽呈色的影響............................10 2.3 各家方法受鹽度影響的情況..............................11 2.4 本章綜合討論..........................................14 第三章 緩衝錯合試劑的試驗................................24 3.1 概述..................................................24 3.2 試劑成分的選擇........................................24 3.2.1探討乙二胺四乙酸的濃度與酸鹼值對試劑之影響.........25 3.2.2變換試劑中銨濃度的影響.............................27 3.2.3建議試劑配方.......................................29 3.3 緩衝錯合試劑基本應用條件測試..........................29 3.3.1 樣本與試劑之添加比例的測定........................29 3.3.2 試劑有效保存期間之測試............................31 3.3.3 試劑對鎘銅還原管穩定度的影響......................32 3.4 本章綜合討論..........................................33 第四章 感潮帶樣本的實測..................................52 4.1 概述..................................................52 4.2 實驗室內系統測試......................................52 4.2.1 數據計算方式.....................................52 4.2.2 標準添加試驗........................................55 4.2.3 檢量線線性範圍探討..................................56 4.3 實測河口環境樣本......................................58 第五章 結論..............................................71 參考文獻..................................................73 | |
dc.language.iso | zh-TW | |
dc.title | 以鎘銅還原法測定河口環境中硝酸鹽之鹽度干擾及解決之道 | zh_TW |
dc.title | Elimination of salt effect for the determination of nitrate in estuarine waters | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 溫良碩,方天熹,熊同銘 | |
dc.subject.keyword | 硝酸鹽,鎘銅還原法,鹽度效應,河口環境, | zh_TW |
dc.subject.keyword | nitrate,Cd-Cu reduction method,salt effect, | en |
dc.relation.page | 76 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2008-07-23 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 海洋研究所 | zh_TW |
顯示於系所單位: | 海洋研究所 |
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