請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/9665完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 韋文誠(Wen-Cheng Wei) | |
| dc.contributor.author | Han-Yu Hsieh | en |
| dc.contributor.author | 謝函育 | zh_TW |
| dc.date.accessioned | 2021-05-20T20:34:23Z | - |
| dc.date.available | 2009-08-05 | |
| dc.date.available | 2021-05-20T20:34:23Z | - |
| dc.date.copyright | 2008-08-05 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-30 | |
| dc.identifier.citation | 1. Website, http://ab-initio.mit.edu/photons/tutorial/
2. Website, http://en.wikipedia.org/wiki/ 3. Y. H. Yun, K. W. Park, S. C. Choi, “Photoluminescence and surface morphologies of ZnGa2O4 thin film phosphors deposited by a chemical solution method,” J. Ceram. Pross. Res., 6 [4] 305-08 (2005) 4. 楊素華, 螢光粉在發光上的應用, 科學發展, 358, 66-71 (2002) 5. Website, http://www.lostseaopals.com.au/opals/index.asp 6. Website, http://nano.nchc.org.tw/photonic/ch1.php 7. Website, http://en.wikipedia.org/wiki/ 8. P. Russell, “Photonic crystal fibers,” Science, 299, 358-62 (2003) 9. S. Noda, K. Tomoda, N. Yamamoto, and A. Chutinan, “Full three-dimensional photonic band-gap crystals at near-infrared wavelengths,” Science, 298, 604-06 (2000) 10. S. Y. Lin, E. Chow, V. Hietala, P. R. Villeneuve, and J. D. Joannopoulos, “Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal,” Science, 282, 274-76 (1998) 11. 陳啟昌, 張正揚, 張利銘, T. Pertsch, 侯佳宏, M. P. Bernal, 羅仕守, 邱華恭, 蕭輔力, A. Khelif, 欒丕綱, 丁于真, 詹益仁, 綦振瀛, 李建階, “光子晶體的過去, 現在與未來,” 台灣奈米會刊, 5, 24-35 (2006) 12. N. A. M. Verhaegh and A. V. Blaaderen, “Dispersions of Rhodamine-Labeled Silica Spheres: Synthesis, Characterization, and Fluorescence Confocal Scanning Laser Microscopy,” Langmuir, 10, 1427-38 (1994) 13. D. J. Norris, E. G. Arlinghaus, L. Meng, R. Heiny, and L. E. Scriven, “Opaline photonic crystals: How does self-assembly work?,” Adv. Mater., 16 [16] 1393-99 (2004) 14. J. Cesarano III and I. A. Aksay, “Stability of aqueous a-Al2O3 suspensions with poly (methacrylic acid) polyelectrolyte,” J. Am. Ceram. Soc., 71 [4] 250-54 (1998) 15. B. V. Velamakanni and F. F. Lange, “Effect of interparticle potentials and sedimentation on particle packing density of bimodal particle distributions during pressure filtration,” J. Am. Ceram, Soc., 74 [1] 166-72 (1991) 16. J. S. Reed, Principle of ceramics processing, 2nd edition, John Wiley and Sons., New York, 1995 17. R. G. Horn, “Surface forces and their action in ceramic materials,” J. Am. Ceram. Soc., 73 [4] 1117-1135 (1990) 18. A. W. Adamson, 陶雨台譯, 表面物理化學, 千華出版社, 1998 19. S. H. Im, Y. T. Lim, D. S. Suh, and O. O. Park, “Three-dimentaionl self-assembly of colloids at a water –air interface: A novel technique for the fabrication of photonic band-gap crystals,“ Adv. Mater., 14 [19] 1367-69 (2002) 20. S. H. Park, D. Qin, and Y. Xia, “Crystallization of meso-scale particles over large areas,” 10, No. 13, Adv. Mater., 10 [13] 1028-32 (1998) 21. H. Cong and W. Cao, “Colloidal crystallization induced by capillary force,” Langmuir, 19, 8177-81 (2003) 22. D. Xia, A. Biswas, D. Li, and S. R. J. Brueck, “Directed self-assembly of silica nanoparticles into nanometer-scale patterned surface using spin-coating,“ Adv. Mater., 16 [16] 1427-32 (2004) 23. A. V. Blaaderen, R. Ruel, and P. Wiltzius, “Templated-directed colloidal crystallization,“ Nature, 385 [23] 321-24 (1997) 24. 鄭子樵, 李紅英, 稀土功能材料, 化學工業出版社,北京, 2003 25. A. Safari, B. Kulwicki, IEEE, Piscataway, NJ, 127 (1997) 26. R. C. Ropp, Luminescence and the Solid state, Elsevier, Boston, 2004 27. P. D. Rack, P. H. Holloway, “The structure, device physics, and material properties of thin film electroluminescent displays,” Mat. Sci. and Eng., R21, 171-219 (1998) 28. K. Liu, Z. Ji, C. Wang, Z. He, L. Sun, and Z. Ye, “Emission from a planar structured electroluminescent device on silicon wafer,” Mater Sci. & Eng. ,B 121, 145-47 (2005) 29. Website, http://en.wikipedia.org/wiki/Electroluminescence 30. D. B. Williams, and C. B. Carter, Transmission electron microscope, PLNUM, New York and London, 1996 31. A. H. Kitai, “Oxide phosphor and dielectric thin films for electroluminescence devices,” Thin Solid Films, 445, 367-376 (2003) 32. W. D. Callister, Jr., Materials science and engineering an introduction, 5th edition, John Wiley and Sons., New York, 1995 33. N. Kawahashi and H. Shiho, “Copper and copper compounds as coatings on polystyrene particles and as hollow spheres,” J. Mater. Chem., 10, 2294-2297 (2000) 34. A. Imhof, “Preparation and characterization of titania -coated polystyrene spheres and hollow titania shells,” Langmuir, 17, 3579-85 (2001) 35. X. C. Guo and P. Dong, “Multistep coating of thick titania layers on mono-disperse silica nano-spheres,” Langmuir, 15, 5535-40 (1999) 36. H. Shiho, and N. Kawahashi, “Titanium compounds as coatings on polystyrene latices and as hollow spheres,” Colloid Polym. Sci., 278, 270-74 (2000) 37. H. Shiho, and N. Kawahashi, “Iron Compounds as Coatings on Polystyrene Latex and as Hollow Spheres,” J. Colloid and Int. Sci., 226, 91-97 (2000) 38. S. F. Wang, Y. F. Hsu, T. C. K. Yang, C. M. Chang, Y. Chen, C. Y. Huang, and F. S. Yen, “Silica coating on ultrafine a-alumina particles,” Mater. Sci. Eng. A, 395, 148-52 (2005) 39. J. H. Park, Y. G. Kim, C. Oh, S. I. Shin, Y. C. Kim, S. G. Oh, and S. H. Kong, “Fabrication of hollow silver spheres by MPTMS-functionalized hollow silica spheres as templates,” Mat. Res. Bull., 40, 271-80 (2005) 40. R. I. Walton, R. I. Smith, F. Millange, I. J. Clark, D. C. Sinclair, and D. O’Hare, “An in situ time-resolved neutron diffraction study of the hydrothermal crystallization of barium titanate,” Chem. Commun., 1267-68 (2000) 41. F. Caruso, R. A. Caruso, and H. Mohwald, “Production of hollow microspheres from nano-structured composite particles,” Chem. Mater., 11, 3309-14 (1999) 42. K. Zhang, X. Zhang, H. Chen, X. Chen, L. Zheng, J. Zhang, and B. Yang, “Hollow titania spheres with movable silica spheres inside,“ Langmuir, 20, 11312-14 (2004) 43. M. Okubo, K. Ichikawa, and M. Fujimura, “Production of multi-hollow polymer microspheres by stepwise alkali/acid method II. Alkali treatment process,” Colloid Polym. Sci., 269, 1257-62 (1991) 44. C. P. Li, J. S. Chang, and W. F. Su, “Synthesis of monodispersed silica particles,” J. Mater. Sci. Eng., 35 [4] 245-249 (2003) 45. J. W. Kim, Y. G. Joe, and K. D. Suh, “Poly(methyl methacrylate) hollow particles by water-in-oil-in-water emulsion polymerization,” Colloid Polym. Sci., 277, 252-56 (1999) 46. Website, http://www.chemat.com/html/solgel.html 47. Website, http://ruby.colorado.edu/~smyth/min/willemite.html 48. Website, http://www.minweb.co.uk/ 49. K. Liu, Z. Ji, C. Wang, Z. He, L. Sun, and Z. Ye, “Emission from a planar structure electroluminescent devise on silicon wafer,” Mater. Sci. Eng. B, 121, 145-47 (2005) 50. T. S. Ahmadi, M. Haase, and H. Weller, “Low-temperature synthesis of pure and Mn-doped willemite phosphor (Zn2SiO4:Mn) in aqueous medium,” Mat. Res. Bull., 35, 1869-79 (2000) 51. T. S. Copeland, B. I. Lee, J. Qi, and A. K. Elrod, “Synthesis and luminescent properties of Mn2+-doped zinc silicate phosphors by sol-gel methods,” J. lumin., 97, 168-73 (2002) 52. Z. Ji, L. Kun, S. Yongliang, and Y. Zhizhen, “Fabrication and characterization of Mn-doped zinc silicate films on silicon wafer,” J. cryst. growth, 255, 353-56 (2003) 53. Website, http://webmineral.com/ 54. H. Chang, H. D. Park, K. S. Sohn, and D. Lee, “Electronic structure of Zn2SiO4 and Zn2SiO4:Mn,” J. Korean phy. Soc., 34 [6] 545-48 (1999) 55. Y. M. Chiang, D. Birnie III, and W. D. Kingery, “Physical Ceramics”, John Wiley and Sons., New York, 1995 56. E. N. Bunting, J. Am. Ceram. Soc., 13 [1] 8 (1930) 57. T. Taghavinia, G. Lerondel, H. Makino, A. Parisini, A. Yamamoto, T. Yao, Y. Kawazoe, and T. Goto, “Activation of porous silicon layers using Zn2SiO4:Mn2+ phosphor particles,” J. lumen, 96, 171-75 (2002) 58. A. Morell, and N. E. Kiati, “Green phosphors for large plasma TV screens,” J. Electrochem. Soc., 140 [7] 2019-2022 (1993) 59. Y. H. Yun, K. W. Park, and S. C. Choi, ”Photoluminescence and surface morphologies of ZnGa2O4 thin film phosphors deposited by a chemical solution method,” J. Ceram. Process. Res., 6 [4] 305-08 (2005) 60. T. Minami, “Oxide thin-film electroluminescent devices and materials,” Solid-States Electronics, 47, 2237-43 (2003) 61. G. H. Lee, N. Iwata, S. J. Kim, and M. S. Kim, “Photoluminescence of ZnO fine powders synthesized by sol-gel process,” J. Ceram. Soc. Jp., 113 [1] 64-66 (2005) 62. 陳右儒 (Y. R. Chen), 固態氧化物燃料電池之氣相法薄膜合成與鉍系封裝玻璃/氧化鋯之介面接合反應, 國立台灣大學材料科學與工程所碩士論文,( 2007) 63. C. C. T. Yang, H. J. Cho, and W. J. Wei, “Quantitative characterization of various tetragonal zirconia polycrystals (TZPs),” J. Eur. Ceram. Soc., 22, 199-207 (2002) 64. Website: http://www.hic.ch.ntu.edu.tw/ 65. Y. C. Kang and S. B. Park, “Zn2SiO4:Mn Phosphor particles prepared by spray pyrolysis using a filter expansion aerosol generator,” Materials Research Bulletin, 35, 1143-51 (2000) 66. T. H. Cho and H. J Chang, “Preparation and characterizations of Zn2SiO4:Mn green phosphors,” Ceram. Int., 29, 611-18 (2003) 67. 國立台灣師範大學科學教育中心, 高中化學, 國立編譯館, 台北市, 1990 68. Website, http://www.ktf-split.hr/periodni/en/abc/kpt.html 69. 汪健民, 陶瓷技術手冊,中華民國粉末冶金學會, 新竹縣, 1999 70. 巫柏奇, 呂宗昕, Modification and Characterization of Strontium Orthosilicate and Yttrium Oxide Phosphors, 國立台灣大學碩士論文, 2005 71. Website, http://140.134.32.129/nowsci/img/dspapp-0/dspapp-1.htm 72. C. Lara, M. J. Pascual, M. O. Prado, and A. Duran, “Sintering of glasses in the system RO-Al2O3-BaO-SiO2 (R = Mg, Ca, Zn) studied by hot staged microscopy,” Solid State Ionics, 170, 201-08 (2004) 73. T. S. Ahmadi, M. Haase, and H. Weller, “Low-temperature synthesis of pure and Mn-doped willemite phosphor (Zn2SiO4:Mn) in aqueous medium,” Mat. Res. Bull., 35, 1869-79 (2000) 74. A. Beiser, Concepts of Modern Physics 6th, McGraw-Hill, Boston, 2003 75. F. J. Blatt, Modern Physics, McGraw-Hill, New York, 1992 76. M. W. Barsoum, Fundamentals of ceramics, Taylor & Francis, New York, 2003 77. J. E. Huheey, E. A. Keiter, and R. L. Keiter, Inorganic chemistry : principles of structure and reactivity 4th, Harper Collins College Publishers, New York, 1993 78. R. P. S. Chakradhar, B. M. Nagabhushana, G. T. Chandrappa, K. P. Ramesh, and J. L. Rao, “Solution combustion derived nanocrystalline Zn2SiO4:Mn phosphors: A spectroscopic,” J. Chem. Phys., 121 [20] 10250-59 (2004) 79. H. Chang, H. D. Park, K. S. Sohn, and J. D. Lee, “Electronic structure of Zn2iO4 and Zn2SiO4:Mn,” J. Korean Phys. Soc., 34 [6] 545-48 (1999) 80. Website, http://srdata.nist.gov/xps/ 81. M. Zelsmann, E. Picard, T. Charvolin, E. Hadji, M. Heitzmann, B. Dal’zotto, M. E. Nier, C. Seassal, P.Rojo-Romeo, and X. Letartre, “Seventy-fold enhancement of light extraction from a defectless photonic crystal mad on silicon-on-insulator,” Appl. Phys. Lett., 83 [13] 2542-44 (2003) 82. L. I. Halaoui, N. M. Abrams, and T. E. Mallouk, “Increasing the conversion efficiency of dye-sensitized TiO2 photoelectrochemical cells by coupling to photonic crystals,” J. Phys. Chem., B, 109, 6334-42 (2005) 83. Y. A. Vlasov, K. Luterova, I. Pelant, and B. Hönerlage, “Enhancement of optical gain of semiconductors embedded in three-dimensional photonic crystals,” Appl. Phys. Lett., 71 [12] 1616-18 (1997) 84. C. M. Chuang, W. B. Lu, W. F. Su, C. M. Lin, and Y. F. Chen, “Manipulation of luminescence from CdSe nanoparticles by three-dimensional photonic crystal,” J. Appl. Phys., 97, (2005) 85. Y. Li, T. Kunitake, S. Fujikawa, and K. Ozasa, “Photoluminescence modification in 2D-ordered films of fluorescent microspheres,” Langmuir, 23 [17] 9109-13 (2007) | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/9665 | - |
| dc.description.abstract | 摻雜錳之矽酸鋅(Mn-doped Zn2SiO4)是一種具有高亮度綠光放射(520 nm)的光致發光和陰極發光之螢光材料。在本篇研究中，我們嘗試了六種方法製備矽酸鋅螢光粉。其中ZSpII和ZSpVI具有最好的效果。以膠粒製程和強迫析出法製備氧化矽/矽酸鋅核殼組成之膠體溶液。鋅離子和錳離子會鍍膜於氧化矽顆粒。在乾燥和熱處理之後，在表面析出之鋅/錳離子會與氧化矽反應成為矽酸鋅結晶相。鋅/錳離子的析出行為以感應耦合電漿-原子放射光譜(ICP-AES)做分析；核殼之微結構則由電子顯微鏡做分析；結晶相由X光繞射儀鑑定；光致發光及陰極發光由光譜儀測量。實驗結果顯示隨著熱處理溫度上升，析出物首先形成氧化鋅，並與氧化矽反應形成矽酸鋅結晶。最後可得到由矽酸鋅鍍膜於具有光子晶體特性的氧化矽模版。此外，矽酸鋅粉末也製作成漿料塗佈於透明電極以作為陰極發光元件，同時對於此元件之光學表現做分析。 | zh_TW |
| dc.description.abstract | Manganese doped zinc silicate (Zn2SiO4:Mn) is a kind of phosphor materials that has a photoluminescent (PL) (at 520 nm) and cathode-luminescent (CL) properties with relative high intensity green light emission. In this study, six methods were tried to synthesis Zn2SiO4 powder. Two (ZSpII and ZSpVI) methods have the best performance. The colloidal particle consisted of SiO2 core-Zn2SiO4:Mn shell has been synthesized via colloidal process and forced precipitation. The reactants Zn/Mn ions were coated on the SiO2 particles. After drying and calcination, the Zn/Mn precipitates reacted with SiO2, then transformed to Zn2SiO4 phase. The behavior of Zn/Mn ions precipitation on silica spheres were studied by ICP-AES. The morphology of core-shell structure was investigated by electron microscopy. The phase identification was studied by X-ray diffraction. The PL and CL properties were determined by photon spectrometer. The results showed that with the increase of annealing temperature, the precipitates formed ZnO first, then reacted with SiO2 and transformed to Zn2SiO4 phase. Finally, SiO2 template with PBG structure coated by ZnSiO4:Mn shell was obtained. Besides, Zn2SiO4 powders as a paste coated on transparent electrode for assembling a CL device. The performance of the device was characterized as well. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-20T20:34:23Z (GMT). No. of bitstreams: 1 ntu-97-R94527044-1.pdf: 8962248 bytes, checksum: bb27850dfbd3242b5523b668cff39f98 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II Content III List of Figures V List of Tables X Chapter 1 Introduction 1 Chapter 2 Literature Review 4 2.1 Photonic Band-Gap Crystals 4 2.1.1 Basic Concepts of Photonic Band-Gap Crystals 4 2.1.2 Assembly of Photonic Band-Gap Crystals 6 2.2 Luminescence Properties 19 2.3 Synthesis of Core-Shell Structures 28 2.3.1 Hydrothermal Method 29 2.3.2 Layer-by-layer Method 29 2.3.3 Osmotic Swelling 30 2.3.4 Sol-gel Method 31 2.3.5 Water/oil/water (W/O/W) Emulsion 32 2.4 Synthesis of Zn2SiO4:Mn Material 38 2.4.1 Zn2SiO4 Powders 39 2.4.2 Zn2SiO4 Thin Film 42 Chapter 3 Experimental Procedure 52 3.1 Materials 52 3.2 Experimental Design 52 3.3 Sample Preparations 53 3.4 Characterization 56 3.4.1 Phase Identification by XRD 56 3.4.2 Thermal Analysis by DTA 56 3.4.3 Zeta Potential Measurement 57 3.4.4 Microstructural Analysis by SEM/EDS and TEM 57 3.4.5 Chemical Composition Analysis by ICP-AES and XPS 58 3.4.6 Luminescence Property Analysis 59 Chapter 4 Results 66 4.1 Synthesis of Zn:Mn Coating on SiO2 Particles 66 4.2 Formation of Zn2SiO4:Mn 74 4.3 Microstructure Observations and EDS Measurements 81 4.4 Luminescence Property 91 Chapter 5 Discussions 104 5.1 Methods Comparison 104 5.2 Effects of Mn2+ to PL Property 117 5.3 PBG Effects to PL Property 127 Chapter 6 Conclusions 131 Reference 133 | |
| dc.language.iso | en | |
| dc.title | 摻雜錳之矽酸鋅/氧化矽殼/核微球之合成與光閘晶體(PBG)光譜之分析 | zh_TW |
| dc.title | Synthesis of Mn-doped Zn2SiO4/SiO2 core-shell structure and
characterization of photonic band-gap crystal (PBG) | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃啟原(Chi-Yuen Huang),劉如熹(Ru-Shi Liu),林清富(Ching-Fuh Lin) | |
| dc.subject.keyword | 光子晶體,殼/結構,螢光粉,摻雜錳之矽酸鋅,膠粒製成,光致發光,陰極發光, | zh_TW |
| dc.subject.keyword | PBG,core-shell,phosphor,Mn-doped Zn2SiO4,colloid,photoluminescence,cathode-luminescence, | en |
| dc.relation.page | 137 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2008-07-30 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-97-1.pdf | 8.75 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。