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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 許麗 | zh_TW |
| dc.contributor.advisor | Li Xu | en |
| dc.contributor.author | 李威佑 | zh_TW |
| dc.contributor.author | Wei-You Li | en |
| dc.date.accessioned | 2024-09-12T16:18:09Z | - |
| dc.date.available | 2024-09-13 | - |
| dc.date.copyright | 2024-09-12 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-08-03 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/95607 | - |
| dc.description.abstract | 隨著電力需求的上升，且要逐步淘汰化石燃料，增加可再生能源的占比，太陽能固然成為了研究重點，近幾年鈣鈦礦太陽能電池從光電轉換效率由2.3 % 提升到26.1 %以趨近研究很久的矽基太陽能電池，做為第三代太陽能材料能在短時間內提升這麼多相信過不久就能超越矽基材料的太陽能。此外，鈣鈦礦太陽能電池為薄膜材料其重量輕、可彎曲、製作容易為主要發展，但要作為商業上使用需朝向大面積發展。
本實驗應用商業性價比高的奈秒脈衝雷射，透過全雷射雕刻技術研究在柔性鈣鈦礦鈦陽能模組上進行。 最後研究成果可再常見的柔性高分子聚合物Polyethylene Terephthalate (PET) 與Polyethylene Naphthalate (PEN) 利用旋轉塗佈，製作出有效面積約1 cm2，PEN柔性基板光電轉換效率為11.9 %，PET 柔性基板光電轉換效率為10.5 %，相較於小面積的標準片光電轉換效率PEN下降了8.9 %，PET只下降了3.1 %，可運用此技術進行商業化生產，在生產成本上具有絕佳的競爭優勢。 | zh_TW |
| dc.description.abstract | As the demand for electricity rises and the gradual phasing out of fossil fuels becomes necessary, increasing the share of renewable energy has become a critical focus of research. In recent years, perovskite solar cells have seen their photoelectric conversion efficiency rise from 2.3% to 26.1%, approaching the efficiency of silicon-based solar cells that have been studied for a long time. As a third-generation solar material, perovskites have shown such rapid improvement in a short time, making it likely that they will soon surpass silicon-based solar cells. Furthermore, perovskite solar cells are thin-film materials that are lightweight, flexible, and easy to manufacture, making them ideal for development. However, for commercial use, large-area development is necessary.
This experiment employs cost-effective nanosecond pulse lasers, using full laser engraving technology to study flexible perovskite solar modules. The final research results show that common flexible polymer substrates such as Polyethylene Terephthalate (PET) and Polyethylene Naphthalate (PEN), using spin coating, produced an effective area of approximately 1 cm². The photoelectric conversion efficiency of the PEN flexible substrate was 11.9%, while the PET flexible substrate had an efficiency of 10.5%. Compared to the small-area standard sheet photoelectric conversion efficiency, PEN decreased by 8.9% and PET only by 3.1%. This technique can be applied for commercial production, offering excellent competitive advantages in terms of production costs. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-09-12T16:18:09Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-09-12T16:18:09Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員審定書 i
致謝 ii 摘要 iii Abstract iv 目次 v 圖次 viii 表次 xii 1 第一章 緒論 1 1.1 前言 1 1.2 鈣鈦礦太陽能電池介紹 4 1.2.1 鈣鈦礦材料介紹 4 1.2.2 鈣鈦礦太陽能元件結構 5 1.3 鈣鈦礦太陽能電池性質介紹 6 1.3.1 短路電流(Short Circuit Current, Jsc) 8 1.3.2 開路電壓(Open Circuit Voltage, Voc) 10 1.3.3 填充因子(Fill Factor, FF) 11 1.3.4 光電轉換效率(Photovoltaic Conversion Efficiency, PCE) 13 2 第二章 文獻回顧 15 2.1 柔性鈣鈦礦太陽能電池介紹 15 2.2 柔性鈣鈦礦太陽能電池模組性質介紹 16 2.2.1 串聯模組製程順序介紹 17 2.2.2 串聯模組設計介紹 18 2.2.3 模組雷射加工介紹 19 2.2.4 柔性鈣鈦礦太陽能電池模組介紹 21 2.3 研究動機 31 3 第三章 實驗流程與方法介紹 32 3.1 實驗方法 32 3.1.1 柔性基板製備流程 32 3.1.2 柔性鈣鈦礦電池模組製備流程 33 3.1.3 雷射製程開發流程 36 3.1.4 柔性鈣太電池元件製備 38 3.2 實驗藥品製備方式 39 3.2.1 PEDOT:PSS溶液 39 3.2.2 2PACz溶液 39 3.2.3 CH3NH3PbI3 鈣鈦礦前驅溶液 39 3.2.4 PC61BM溶液 39 3.2.5 PEI介面修飾層溶液 40 3.3 實驗雷射基台架設與介紹 41 3.3.1 脈衝雷射和光路設計 41 3.3.2 2D振鏡系統 43 3.3.3 精密微控定位走台 45 3.4 模組實驗分析方法介紹 46 3.4.1 雷射參數定義與量測方法 46 3.4.2 傳輸線法分析(Transfer Line Method, TLM) 50 4 第四章 實驗結果與討論 52 4.1 柔性基板之選擇 52 4.2 柔性基板透明導電薄膜之選擇 53 4.3 柔性鈣鈦礦太陽能模組雷射結果 58 4.3.1 P1線雷射參數 58 4.3.2 P2線雷射參數 62 4.3.3 P3線雷射參數 68 4.4 柔性太陽能電池光電轉換效率實驗結果 71 4.5 柔性鈣鈦礦太陽能模組彎曲測試 75 5 第五章 結論與未來展望 77 5.1 結論 77 5.2 未來展望 77 參考文獻 78 6 附錄一 實驗用化學物質列表 85 7 附錄二 實驗儀器列表 87 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 奈秒脈衝雷射 | zh_TW |
| dc.subject | 全雷射雕刻 | zh_TW |
| dc.subject | 柔性鈣鈦礦太陽能模組 | zh_TW |
| dc.subject | all laser scribing | en |
| dc.subject | flexible perovskite solar module | en |
| dc.subject | nanosecond pulse laser | en |
| dc.title | 奈秒脈衝雷射雕刻技術應用於不同柔性鈣鈦礦太陽能電池模組之研究 | zh_TW |
| dc.title | Flexible Perovskite Solar Modules on Polyethylene Terephthalate (PET) and Polyethylene Naphthalate (PEN) by Laser Patterning Technology Based on Nanosecond Pulsed Laser | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 劉建豪;黃秉鈞 | zh_TW |
| dc.contributor.oralexamcommittee | Chien-Hao Liu;Bin-Juine Huang | en |
| dc.subject.keyword | 柔性鈣鈦礦太陽能模組,奈秒脈衝雷射,全雷射雕刻, | zh_TW |
| dc.subject.keyword | flexible perovskite solar module,nanosecond pulse laser,all laser scribing, | en |
| dc.relation.page | 88 | - |
| dc.identifier.doi | 10.6342/NTU202402059 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2024-08-06 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 機械工程學系 | - |
| dc.date.embargo-lift | 2029-07-30 | - |
| 顯示於系所單位： | 機械工程學系 | |
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| ntu-112-2.pdf 未授權公開取用 | 8.26 MB | Adobe PDF | 檢視/開啟 |
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