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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 蔡豐羽 | zh_TW |
| dc.contributor.advisor | Feng-Yu Tsai | en |
| dc.contributor.author | 陳郁琪 | zh_TW |
| dc.contributor.author | Yu-Chi Chen | en |
| dc.date.accessioned | 2024-08-16T17:38:05Z | - |
| dc.date.available | 2024-09-16 | - |
| dc.date.copyright | 2024-08-16 | - |
| dc.date.issued | 2024 | - |
| dc.date.submitted | 2024-08-07 | - |
| dc.identifier.citation | Luo, S., & Daoud, W. A. Recent progress in organic–inorganic halide perovskite solar cells: Mechanisms and Material Design. Journal of Materials Chemistry A, 2015, 3(17), 8992–9010.
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Polymer-Modified Halide Perovskite Films for Efficient and Stable Planar Heterojunction Solar Cells. Sci Adv 2017, 3 (8). Efficient and Stable FAPbBr3 Perovskite Solar Cells via Interface Modification by a Low-Dimensional Perovskite Layer. ChenSusChem 2019,12,5007-5014. Von Hauff, E.; Klotz, D. Impedance Spectroscopy for Perovskite Solar Cells: Characterisation, Analysis, and Diagnosis. J Mater Chem C Mater 2022, 10 (2), 742–761. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/94706 | - |
| dc.description.abstract | 有機無機錫鉛混合型鈣鈦礦太陽能電池相較於目前主流的鉛基鈣鈦礦太陽能電池更為環保，在有機無機錫鉛混合型鈣鈦礦太陽能電池系統中，以芳香肼類化合物作為添加劑有助於提升電池穩定性，原因為芳香結構中推電子的特性，提升鄰近肼基抑制錫氧化的能力。因此本研究探討以下四種不同推電子取代基的芳香肼類化合物 phenylhydrazine hydrochloride (PH•HCl)、o-tolylhydrazine hydrochloride (OTH•HCl)、p-tolylhydrazine hydrochloride (PTH•HCl) 和1-naphthalenyl hydrazine hydrochloride (NH•HCl) 來對於錫鉛混合型鈣鈦礦太陽能電池的影響。其中以不含取代基之芳香肼類化合物PH•HCl作為基準，跟PHHCl相比之下，另外三種肼類化合物對於錫鉛混合型太陽能電池的穩定性均顯著提高。在元件穩定性方面: NH•HCl > OTH•HCl ~ PTH•HCl，其中NH•HCl使元件的壽命延長將近100%。除了穩定性的提升之外，薄膜的晶粒尺寸也有所增加，且能有效鈍化光自發光淬滅所造成的缺陷，也提高鈣鈦礦太陽能電池元件的複合電阻與載流子遷移率，進而使最高的光電轉換率提高10%，本研究的發現將為應用於錫鉛混合型與以錫為基底的鈣鈦礦太陽能電池之肼類添加劑有極大的幫助。 | zh_TW |
| dc.description.abstract | Aromatic hydrazine compounds have been shown to be effective stability-enhancing additives to Pb-Sn organic-inorganic halide perovskite solar cells (PSC)—a more eco-friendly alternative to the mainstream Pb-based PSC technology—owing to the electron-donating nature of the aromatic structure, which enhances the neighboring hydrazine group’s ability to suppress degradations Pb-Sn perovskites via oxidation of Sn2+. Aiming to advance this concept further, this study examined four aromatic hydrazine compounds with various electron-donating substituents as additives to Pb-Sn PSC devices, including phenylhydrazine hydrochloride (PH•HCl), o-tolylhydrazine hydrochloride (OTH•HCl), p-tolylhydrazine hydrochloride (PTH•HCl), and 1-naphthalenyl hydrazine hydrochloride (NH•HCl). Compared to PH•HCl, which has a non-substituted phenyl group and was used as a benchmark, the three other electron-donating-group-substituted hydrazines all showed greater enhancements in the stability of PSC devices, validating the premise of this work. The levels of stability enhancement yielded by the three substituted hydrazines followed the strength of their electron-donating substituents, i.e. NH•HCl > OTH•HCl ~ PTH•HCl, with NH•HCl extending the device lifetime by > 100%. In addition to stability enhancements, the three substituted hydrazines increased the crystal grain size in the Pb-Sn perovskite film, passivated photoluminescence-quenching defects therein, and increased recombination resistance and charge-carrier mobility through the PSC device, resulting in a maximal enhancement of 10% in power conversion efficiency. The findings of this work will offer guidance to designing and selecting hydrazine-type additives for Pb-Sn and Sn-based PSCs. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-08-16T17:38:05Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-08-16T17:38:05Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員審定書i
誌謝ii 摘要iii Abstract iv Content vi Lists of Figures viii Lists of Tables xii Chapter 1 Introduction 1 1.1 Lead-lean perovskite solar cells 1 1.2 Hydrazine compounds as additive to Sn-containing PVSK 3 1.3 Literature review on hydrazine additives for Sn-containing PSCs 4 1.4 Motivation, Approach and Objective 6 Chapter 2 Experiment Section 8 2.1 Chemicals 8 2.2 Instruments 11 2.3 Solution preparation of Pb-Sn PSCs 12 2.3.1 HTL / PEDOT:PSS 12 2.3.2 Pb-Sn perovskite precursor solution / Cs0.25FA0.75Pb0.5Sn0.5I3 13 2.3.3 Additive solution / OTH•HCl 13 2.3.4 Additive solution / PTH•HCl 13 2.3.5 Additive solution / NH•HCl 14 2.4 Fabrication of Pb-Sn PSCs 14 2.4.1 Cleaning of transparent conductive glass 14 2.4.2 UV ozone surface treatment of transparent conductive glass 14 2.4.3 Spin coating of PEDOT:PSS hole transport layer 14 2.4.4 Spin coating of Cs0.25FA0.75Pb0.5Sn0.5I3 perovskite precursor solution 15 2.4.5 Evaporation of C60 electron transport layer 15 2.4.6 Evaporation of BCP 15 2.4.7 Evaporation of Ag silver electrode 16 2.5 Methods of device analysis and measurement 16 2.5.1 Currentvoltage measurement of PSCs 16 2.5.2 UVvisible absorption spectrum 17 2.5.3 External quantum efficiency (EQE) 18 2.5.4 Xray diffraction (XRD) 19 2.5.5 Xray photoelectron spectroscopy (XPS) 19 2.5.6 Fouriertransform infrared spectroscopy (FTIR) 19 2.5.7 Electrochemical impedance spectroscopy (EIS) 19 2.5.8 Spacecharge limited current (SCLC) measurements 20 2.5.9 Reducing test of the hydrazine compounds 21 Chapter 3 Results and Discussion 22 3.1 Reducing strength of the hydrazine additives 22 3.2 Effects of the hydrazine additives on PbSn PSC device characteristics 24 3.2.1 Determining proper concentrations of the hydrazine additives 24 3.2.2 The J-V curves of three additives for PbSn PSCs 25 3.2.3 The EQE spectra of three additives for PbSn PSCs 26 3.2.4 The device stability of four additives 27 3.3 Discussions 30 3.3.1 Morphological analysis 30 3.3.2 Optical Characterization 34 3.3.3 Compositional analysis 38 3.3.4 EIS and SCLC measurements 39 Chapter 4 Conclusion 44 Chapter 5 Reference 45 | - |
| dc.language.iso | zh_TW | - |
| dc.title | 不同取代基之肼類添加劑對有機無機錫鉛鈣鈦礦 太陽能電池元件效能之研究 | zh_TW |
| dc.title | Effects of substituents of hydrazine additives on the characteristics of organic-inorganic hybrid lead-tin perovskite photovoltaic devices | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 闕居振; 黃裕清; 李坤穆 | zh_TW |
| dc.contributor.oralexamcommittee | Chu-Chen Chueh;Yu-Ching Huang;Kun-Mu Lee | en |
| dc.subject.keyword | 有機無機錫鉛混和型鈣鈦礦太陽能電池,鈣鈦礦太陽能電池穩定性,添加劑工程,還原劑,肼類化合物, | zh_TW |
| dc.subject.keyword | organic-inorganic hybrid lead-tin perovskite solar cells,photovoltaic device stability,additive engineering,reducing agents,hydrazine compounds, | en |
| dc.relation.page | 50 | - |
| dc.identifier.doi | 10.6342/NTU202403324 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2024-08-10 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 材料科學與工程學系 | - |
| 顯示於系所單位： | 材料科學與工程學系 | |
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