請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/93516完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉貴生 | zh_TW |
| dc.contributor.advisor | Guey-Sheng Liou | en |
| dc.contributor.author | 卓易如 | zh_TW |
| dc.contributor.author | Yi-Ju Cho | en |
| dc.date.accessioned | 2024-08-05T16:19:00Z | - |
| dc.date.available | 2024-08-06 | - |
| dc.date.copyright | 2024-08-05 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2024-07-17 | - |
| dc.identifier.citation | REFERENCES
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/93516 | - |
| dc.description.abstract | 本研究設計與製備芳基胺單衍生物 (N, N-Bis(4-aminophenyl)-N′-(4-carboxyphenyl)-N′-(4-methoxyphenyl)-1,4-phenylenediamine) 之高原子經濟效應AB2型超支化聚醯胺(HPA)。合成的HPA以不同的封端劑進行修飾，以增加多段變色。這些具有固有微孔結構的電活性超支化聚醯胺HPA-TPA和HPA-B，電化學過程中能有效提升電解質的擴散性，並在不同施加電位下表現出多段的變色行為，縮短響應時間和高化學穩定性。值得注意的是HPA-TPA具有最大的固有微孔結構，表現出最突出的特性，如保持光學對比度、三段顏色變化、高著色效率、最短的響應時間和高穩定性。在這項研究中， HPA-TPA的電致變色在裝置表現出卓越的性能，最大著色效率(578 cm2/C)、最大響應速率(27.4% s-1)以及在經1000次切換後，仍保持優異的開關穩定性，具有高達99%的光學可逆性。 | zh_TW |
| dc.description.abstract | A high atomic efficiency AB2-type hyperbranched polyamide (HPA) derived from arylamine monomer (N, N-Bis(4-aminophenyl)-N′-(4-carboxyphenyl)-N′-(4-methoxy-phenyl)-1,4-phenylenediamine) is judiciously designed and prepared. Furthermore, the synthesized HPA is modified with different end-capping units to increase the intrinsic microporous structures. These electroactive HPAs (HPA-B and HPA-TPA) with intrinsic microporous structures exhibit increased counter-ion diffusivity in electrochemical processes, showing multicolored electrochromic behavior at various applied potentials, excellent electrochemical stability, and short switching response times. With the most significant intrinsic microporous structures, HPA-TPA showcased outstanding characteristics, such as a significant optical contrast ratio, three-stage color change, the highest coloration efficiency (CE), shortest switching response times, and high stability. In this investigation, electrochromic devices utilizing ECD-HPA-TPA exhibited remarkable performance, as evidenced by the maximum coloration efficiency (578 cm2/C), the rapid coloration (27.4% s-1), and remarkable switching stability, which persisted even after 1000 cycles, with a higher 99% reversibility in optical properties. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2024-08-05T16:19:00Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2024-08-05T16:19:00Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | TABLE OF CONTENTS
ACKNOWLEDGEMENTS i ABSTRACT (in English) ii ABSTRACT (in Chinese) iii TABLE OF CONTENTS iv LIST OF FIGURES vii LIST OF SCHEMES xiv CHAPTER 1 Introduction 1 1.1 High-Performance Polymers (HPPs) 2 1.1.1 Aromatic Polyamide Synthesis 4 1.1.2 Purposeful Modification of Aromatic Polyamides 6 1.2 Hyperbranched Polymers (HBPs) 8 1.2.1 Degree of Branching 8 1.2.2 Properties of Hyperbranched Polymers 11 1.3 Electrochromism 13 1.3.1 A Brief History and Evolution of Electrochromism 13 1.3.2 Important Performance Parameters and Terminology for Electrochromism 15 1.3.3 Electrochromic Materials 18 1.3.4 Electrochromic Device Systems (ECDs) 29 1.4 Research Motivation 31 CHAPTER 2 Experimental Section 32 2.1 Materials 33 2.2 Monomer Synthesis 35 Synthesis of AB2-type Monomer (TPPA-AB2) 35 Synthesis of AB-type Monomer (TPPA-AB) 40 Model Compounds 46 2.3 Synthesis of Polyamides 48 Preparation of AB2 Hyperbranched Polyamide 48 Preparation of AB Linear Polyamide 49 2.4 Preparation of the Polymeric Films 50 2.5 Fabrication of the Electrochromic Devices (ECDs) 50 2.6 Measurement 51 CHAPTER 3 Results and Discussion 54 3.1 AB2 and AB Type Monomer Synthesis 55 3.2 Polyamide Synthesis 78 3.3 Polymer Characterization 89 Basic Characterization of Polyamides 89 Microporous Characteristics of the Polyamides 95 3.4 Electrochemical and Electrochromic Properties of Polymer Films 98 Electrochemical Properties 98 Spectroelectrochemistry and Electrochromic Properties 106 Measurement of n-Electrons Transferred for HPA-TPA 110 Electrochromic Switching Studies 116 3.5 Electrochromic Device 122 CHAPTER 4 Conclusion 132 REFERENCES 135 | - |
| dc.language.iso | en | - |
| dc.subject | 電致變色 | zh_TW |
| dc.subject | 固有微孔洞 | zh_TW |
| dc.subject | 芳基胺衍生物 | zh_TW |
| dc.subject | AB2超支化聚醯胺 | zh_TW |
| dc.subject | 響應速度提升 | zh_TW |
| dc.subject | switching capability enhancement | en |
| dc.subject | arylamine derivatives | en |
| dc.subject | electrochromism | en |
| dc.subject | intrinsic microporosity | en |
| dc.subject | AB2-type hyperbranched polyamide | en |
| dc.title | 新型芳香胺族AB2型超支化聚醯胺高分子之設計、合成與電致變色應用 | zh_TW |
| dc.title | Novel Arylamine-based AB2-type Hyperbranched Polyamide: Design, Synthesis, and Electrochromic Properties | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 蕭勝輝;龔宇睿;張嘉文 | zh_TW |
| dc.contributor.oralexamcommittee | Sheng-Huei Hsiao;Yu-Ruei Kung;Cha-Wen Chang | en |
| dc.subject.keyword | 電致變色,響應速度提升,AB2超支化聚醯胺,芳基胺衍生物,固有微孔洞, | zh_TW |
| dc.subject.keyword | electrochromism,switching capability enhancement,AB2-type hyperbranched polyamide,arylamine derivatives,intrinsic microporosity, | en |
| dc.relation.page | 145 | - |
| dc.identifier.doi | 10.6342/NTU202401818 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2024-07-18 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | - |
| dc.date.embargo-lift | 2025-07-16 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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