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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 江建文 | zh_TW |
| dc.contributor.advisor | Kien Voon Kong | en |
| dc.contributor.author | 劉昱德 | zh_TW |
| dc.contributor.author | Yu-Te Liu | en |
| dc.date.accessioned | 2023-11-20T16:09:22Z | - |
| dc.date.available | 2023-11-21 | - |
| dc.date.copyright | 2023-11-20 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-09-05 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/91150 | - |
| dc.description.abstract | 光催化二氧化碳還原反應已經成為全球性議題，近年來，除了雙核超分子系統，利用氫鍵、動態配位結合等高效的光催化體系皆已被廣泛報導。值得注意的是，反應的可調控性是一個創新的目標，表明其為一個具有高自由度的開/關反應。本研究中選用二芳基乙烯衍生物作為光致變色材料，並於實驗中證明該材料的高度可逆性以及高響應。其中，透過核磁共振光譜儀及紫外線/可見光光譜儀進行滴定實驗，並成功確定了光催化劑與二芳基乙烯之間的配位關係。在光催化二氧化碳還原反應中，得知開放形式的轉換數 (TON) 為313；封閉形式的轉換數 (TON) 為27，並透過開放/封閉形式之間的光誘導相互轉換證明了二氧化碳還原反應的可控性。 | zh_TW |
| dc.description.abstract | There is a need to explore photocatalytic CO2 reduction worldwide. In recent years, high efficiency photocatalysis systems such as bi-nuclear supramolecular, hydrogen bonding, dynamic coordination, and others were reported extensively. It is noteworthy that the controllable element of the reaction is an innovative target, indicating that it is a switch-on/off reaction with a high degree of freedom. We have used diarylethene darivates as a photochromic material herein, and the material was demonstrated to be highly reversible and responsive. As a result of 1H nuclear magnetic resonance and UV titrations, we were able to determine the coordination between catalyst and diarylethene. A photocatalytic conversion of CO2 to CO gave a turnover number (TON) of 313 for the open form and 27 for the closed form, respectively, as a result of the photocatalytic CO2-to-CO conversion. The light-induced interconversion between open and closed forms demonstrated its controllability. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-11-20T16:09:22Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-11-20T16:09:22Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | Acknowledgement i
摘要 ii Abstract iii Table of Contents iv List of Figures vii List of Schemes xii List of Tables xiii Chapter 1 Introduction 1 1.1. CO2 reduction 1 1.2. Photocatalyst binuclear system 2 1.3. Noncovalent-bonding photocatalysis 5 1.4. Photochromism materials 7 1.5. Types of photoswitch molecules 7 1.6. Application of diarylethene materials 11 1.7. Motivation 15 Chapter 2 Results and Discussion 17 2.1. Characterization of Diarylethene 17 2.2. Characterization of Photochromic 19 2.3. Coordination Interaction between Diarylethene and CoPc 28 2.4. Photoinduced Interconversion between 6a and 6b 38 2.5. Photocatalytic CO2 Reduction of CoPc and DAE-CoPc 45 2.5.1 Photophysical properties of photosensitizers 46 2.5.2 Electrochemical properties of photosensitizers and catalysts 50 2.5.3 Emission quenching experiments 55 2.5.4 Photocatalytic CO2 Reduction 57 2.5.5 Proposed mechanism of light-induced electron transfer 61 2.6. Photocatalyst reaction system between 6a and 6b 64 2.7. Conclusion 67 Chapter 3 Experimental 68 3.1. General Information 68 3.2. Physical Measurements 71 3.3. Photocatalytic CO2 reduction 75 3.4. Preparation 78 Reference 86 Appendix I 103 Appendix II 139 | - |
| dc.language.iso | en | - |
| dc.title | 二芳基乙烯衍生物：一個創新的光催化 CO2轉化為CO的還原反應 | zh_TW |
| dc.title | Diarylethene Derivatives: An Innovative Target for Photocatalytic CO2-to-CO Reduction | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 112-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 劉沂欣;江偉宏;陳振中 | zh_TW |
| dc.contributor.oralexamcommittee | Yi-Hsin Liu;Wei-Hung Chiang;Chun-Chung Chan | en |
| dc.subject.keyword | 光催化,二氧化碳還原,光致變色材料,二芳基乙烯, | zh_TW |
| dc.subject.keyword | Photocatalyst,CO2 reduction,photochromic,diarylethene, | en |
| dc.relation.page | 144 | - |
| dc.identifier.doi | 10.6342/NTU202304213 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2023-09-06 | - |
| dc.contributor.author-college | 理學院 | - |
| dc.contributor.author-dept | 化學系 | - |
| dc.date.embargo-lift | 2028-09-05 | - |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-112-1.pdf 目前未授權公開取用 | 9.9 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。