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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉貴生 | zh_TW |
| dc.contributor.advisor | Guey-Sheng Liou | en |
| dc.contributor.author | 杜旻修 | zh_TW |
| dc.contributor.author | Min-Hsiu Tu | en |
| dc.date.accessioned | 2023-09-15T16:17:50Z | - |
| dc.date.available | 2023-09-16 | - |
| dc.date.copyright | 2023-09-15 | - |
| dc.date.issued | 2022 | - |
| dc.date.submitted | 2002-01-01 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/89695 | - |
| dc.description.abstract | 本論文分為四個章節，第一章為總體緒論，介紹功能性高分子、電致變色之發展與改良，以及Tröger's base的結構與化學特性。接著在第二章的研究中，成功合成並鑑定出了一個新型的含TB單元的三苯胺二胺單體TBTPA-NH2，並利用其醯胺衍生物TBTPA-M作為模型分子，透過循環伏安法(CV)、微分脈衝伏安法(DPV)及能斯特分析以研究此新型電活性分子之電致變色行為表現。此外，我們利用此新型單體製備成自具微孔的聚醯胺高分子PTBTPA，透過量測密度與電化學阻抗圖譜證明其微孔性，並以此研究自具微孔性質對於反應時間與電致變色表現之影響。而在第三章的研究當中，一系列對位胺基取代之三苯胺衍生物展現出低氧化電位與多段變色之特性，透過循環伏安法(CV)與光譜電化學量測，其電化學性質與氧化機制被完整闡述。此外，此一系列分子展現出高度電化學穩定性，所製備之電致變色元件性質已透過多種電化學量測方式記錄，展現出具有高對比度與長時間穩定之成效。最後，第四章總結了實驗結果，我們發現TB單元可形成自具微孔結構，增加了高分子的自由體積，此特性既提高了響應速度也降低了驅動電壓。此外，對位胺基取代的TPA分子在電致變色元件中表現出優異的穩定性與著色效率，提供了一種方式以製造多段變色、高效之電致變色元件。 | zh_TW |
| dc.description.abstract | This study has been divided into four chapters. Firstly, a general introduction was provided in chapter 1, introducing high-performance polymers, the development and enhancement of electrochromism (EC), and Tröger's base (TB) chemistry. Secondly, in chapter 2, a novel electroactive diamine monomer, TBTPA-NH2, was synthesized and characterized. To investigate the electrochemical properties of this molecule, an amide-type model compound, TBTPA-M, was synthesized for the experiments. With cyclic voltammetry (CV), differential pulse voltammetry, and Nernstian analysis, the EC properties of this monomer with TB moiety were recorded. Furthermore, an intrinsic microporous polyamide, PTBTPA, was prepared from this monomer. The porosity was confirmed by film density and electrochemical impedance spectroscopy (EIS). Measurements such as cyclic voltammetry, spectroelectrochemistry, and switching response were taken to evaluate the benefits of intrinsic microporous moieties. The electrochemical parameters of PTBTPA were recorded, showing better results. Then, in chapter 3, the electrochemical properties of a series of para-amino substituted TPA derivatives were investigated. The multi-electrochromic and low-driving-voltage attributes became the advantages for electrochromic applications. Moreover, these amino substituted TPA revealed unexpectedly high stability in long-term measurement. The electroactive TPA chromophores were further fabricated as electrochromic devices (ECDs). The oxidation mechanism and EC properties were clarified by the measurements including cyclic voltammetry, spectroelectrochemistry, and switching response Finally, the experiment results were summarized in chapter 4. We found out that the introduction of TB moiety created micropores which increased the free volume of polymers, enhancing the response speed and reducing the driving voltage. Additionally, the electrochemical properties of para-amino substituted TPA derivatives were thoroughly studied. The ECDs revealed superior stability and coloration efficiency, providing a facile method of fabricating multi-electrochromic, energy-efficient devices. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-09-15T16:17:50Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-09-15T16:17:50Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | TABLE OF CONTENTS 致謝 I ABSTRACT (in English) II 中文摘要 IV TABLE OF CONTENTS V LIST OF TABLES VIII LIST OF FIGURES IX LIST OF SCHEMES XVI CHAPTER 1 General Introduction 1 1.1 High-Performance Polymers 2 1.1.1 Preparation of Aromatic Polyamides 3 1.1.2 Modification of Aromatic Polyamides 6 1.1.3 Semi-aromatic Polyamides 7 1.2 Electrochromism 9 1.2.1 Evolution of Electrochromism 9 1.2.2 Common Electrochromic Materials 10 1.2.3 Triarylamine-based Electrochromic Materials 18 1.3 Tröger's Base Chemistry 21 1.4 Research Motivation 24 CHAPTER 2 Synthesis and Electrochemical Properties of Novel Triarylamine-Based Materials with Tröger’s Base Moiety 25 2.1 Introduction 26 2.2 Experimental Section 28 2.2.1 Materials 28 2.2.2 Synthesis of Monomers 29 2.2.3 Synthesis of Polyamides 34 2.2.4 Preparation of Polyamide Films 37 2.2.5 Measurement 37 2.3 Result and Discussion 39 2.3.1 Synthesis and Characterization 39 2.3.2 Polymer Basic Properties 51 2.3.3 Thermal Properties of polyamides 53 2.3.4 Electrochemical Properties of Model Compounds 55 2.3.4.1 Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) 55 2.3.4.2 Nernstian Analysis of TBTPA-M 59 2.3.5 Electrochemical Properties of Polyamides 62 2.3.5.1 Cyclic Voltammetry (CV) 62 2.3.5.2 Electrochemical Impedance Spectroscopy (EIS) 64 2.3.5.3 Spectroelectrochemical Properties 66 CHAPTER 3 Electrochemical Behaviors of para-Amino Substituted Triphenylamine Derivatives 70 3.1 Introduction 71 3.2 Experimental Section 71 3.2.1 Materials 73 3.2.2 Fabrication of the Liquid-type Electrochromic Devices (ECDs) 73 3.2.3 Measurement 74 3.3 Result and Discussion 75 3.3.1 Electrochemical Properties of para-amino-substituted TPA Derivatives 75 3.3.1.1 Cyclic Voltammetry (CV) and Spectroelectrochemistry 75 3.3.1.2 Differential Pulse Voltammetry (DPV) 81 3.3.1.3 Cyclic Stability 82 3.3.2 Electrochromic Properties of ECDs 85 3.3.2.1 Cyclic Voltammetry (CV) and Spectroelectrochemistry 86 3.3.2.2 Switching Response and Stability 95 CHAPTER 4 Conclusion 100 REFERENCES 104 | - |
| dc.language.iso | en | - |
| dc.subject | 多段變色 | zh_TW |
| dc.subject | 自具微孔 | zh_TW |
| dc.subject | 電致變色聚醯胺 | zh_TW |
| dc.subject | 特羅格鹼 | zh_TW |
| dc.subject | electrochromic polyamide | en |
| dc.subject | intrinsic microporosity | en |
| dc.subject | Tröger's base | en |
| dc.subject | multi-electrochromism | en |
| dc.title | 新型特羅格鹼三芳香胺材料之合成及其電致變色性質探討 | zh_TW |
| dc.title | Synthesis and Electrochromic Properties of Novel Triarylamine-Based Materials with Tröger’s Base Moiety | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 110-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 張嘉文 | zh_TW |
| dc.contributor.oralexamcommittee | Sheng-Huei Hsiao;Yu-Ruei Kung;Cha-Wen Chang | en |
| dc.subject.keyword | 電致變色聚醯胺,自具微孔,特羅格鹼,多段變色, | zh_TW |
| dc.subject.keyword | electrochromic polyamide,intrinsic microporosity,Tröger's base,multi-electrochromism, | en |
| dc.relation.page | 110 | - |
| dc.identifier.doi | 10.6342/NTU202103009 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2022-09-27 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | - |
| dc.date.embargo-lift | 2023-09-26 | - |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-110-2.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 7.44 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。