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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林唯芳(Wei-Fang Su) | |
dc.contributor.author | Jui-Hung Hsu | en |
dc.contributor.author | 徐瑞鴻 | zh_TW |
dc.date.accessioned | 2021-05-20T20:05:14Z | - |
dc.date.available | 2010-08-19 | |
dc.date.available | 2021-05-20T20:05:14Z | - |
dc.date.copyright | 2009-08-19 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-08-14 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/8964 | - |
dc.description.abstract | 本研究探討導電高分子P3HT與二氧化鈦奈米桿的混摻系統中,二氧化鈦奈米桿的表面改質研究。預期藉由奈米桿的表面改質,提昇有機無機混摻太陽能電池的能量轉換效率。在此,表面改質乃是利用化學置換反應,去除原本存附於二氧化鈦奈米桿表面的非導電分子,並分別吸附二種導電性的界面改質分子(interface modifier),即酞菁銅(CuPc)的衍生物Cudye及末端具羧酸基的己基噻吩寡體(oligomer 3HT-COOH),以增進載子在予體、受體界面的傳輸性質。由定性及定量分析結果,可確認表面改質分子可於二氧化鈦奈米桿表面產生有效吸附。雖然由於其較少的吸附量,改質分子的存在不足以額外提昇混摻系統對光子的吸收,但系統中的激子分離效率卻可在改質後獲得很大程度的提昇;電子與電洞的再結合亦可被有效抑制。另外,在表面改質後,P3HT與二氧化鈦間顯示了更為相近的親疏水性,混摻薄膜中的高分子也具備較佳的結晶排列,因此可推測表面改質亦有助於提昇混摻系統中,有機相(P3HT)與無機相(二氧化鈦奈米桿)之間的相容性。藉由釐清表面改質分子在有機太陽能電池作用層中的角色與功能,本研究提供了一提昇太陽能電池效率的可行途徑。 | zh_TW |
dc.description.abstract | This work presents the study of surface modification of TiO2 nanorod in bulk heterojunction composites based on poly(3-hexylthiophene) (P3HT) and TiO2 nanorods, trying to improve the performance of organic/inorganic hybrid solar cells. Surface modification of TiO2 was performed by replacing the insulating surface ligand (oleic acid) with two kinds of conductive, novel interface modifiers: the derivative of copper phthalocyanine (Cudye) and the regioregular 3-hexylthiophene oligomer with carboxylic end functional groups (oligomer 3HT–COOH). As surface modification was carried out, the hybrid system exhibited an improved charge separation by showing a more pronounced PL quenching. Also, back recombination between electrons and holes can be suppressed from the transient photo-voltage measurement, revealing a longer charge carrier lifetime. Furthermore, the compatibility between P3HT and TiO2 can also be improved after surface modification, as P3HT and modified TiO2 exhibited a more similar surface hydrophobicity (by contact angle measurement) and higher polymer crystallinity in the hybrid films (by XRD). All the data show that the oligomer 3HT-COOH is the better performed interface modifier than Cudye. By clarifying the functions and roles of interface modifier in the active layer of photovoltaic devices, this study provides a possible route for increasing the efficiency of organic solar cells. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T20:05:14Z (GMT). No. of bitstreams: 1 ntu-98-R96527018-1.pdf: 4613609 bytes, checksum: e0f558f9cdc33e7780db9dfb1100033d (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 摘要 I
Abstract II Contents III List of Figures V List of Tables IX Chapter 1 Introduction 1 1.1 Solar energy - a promising renewable energy source 1 1.2 Solar cell classifications 2 1.2.1 Conventional inorganic solar cells 2 1.2.2 Organic solar cells 3 1.3 Working principles of organic solar cells 4 1.4 Device architectures of organic solar cells 7 1.4.1 Single layer structure 7 1.4.2 Bi-layered heterojunction structure 8 1.4.3 Bulk heterojunction structure 9 1.5 Materials in organic solar cells 11 1.5.1 Donor materials 12 1.5.2 Acceptor materials 13 1.6 Improving solar cell performance by surface modification 14 1.6.1 A brief introduction to surface modification 14 1.6.2 Surface modification of the top metal electrode 18 1.6.3 Surface modification of the bottom electrode of transparent conductive oxide 21 1.6.4 Surface modification of the active layer materials 24 1.7 Research motivations 33 Chapter 2 Experimental section 36 2.1 Chemicals 36 2.2 Preparation of materials 37 2.2.1 Synthesis of TiO2 nanorods 37 2.2.2 Synthesis of the oligomer with carboxylate terminated 3-hexylthiophene (oligomer 3HT-COOH) 38 2.2.3 Surface modification of TiO2 nanorods 39 2.3 Preparation of samples 42 2.3.1 Preparation of P3HT/TiO2 hybrid films 42 2.4 Material characterizations and surface characterizations 44 2.4.1 Characterizations of TiO2 nanorods 44 2.4.2 Characterizations of the oligomer with carboxylate terminated 3-hexylthiophene (oligomer 3HT-COOH) 45 2.4.3 Characterizations of surface modified TiO2 nanorods 45 2.4.4 Characterizations of the properties of P3HT/TiO2-IM hybrid system 47 2.5 Device fabrications 49 Chapter 3 Results and Discussion 50 3.1 Characterizations of TiO2 nanorods 50 3.2 Characterizations of the oligomer with carboxylate terminated 3-hexylthiophene (oligomer 3HT-COOH) 52 3.3 Characterizations of surface modified TiO2 nanorods 54 3.3.1 Fundamental surface properties 54 3.3.2 Desorption test of interface modifiers 61 3.3.3 Quantitative evaluations of the adsorbed interface modifiers 64 3.4 Effect of TiO2 surface modification in P3HT/surface modified TiO2 hybrid system 67 3.4.1 Energy band structure of P3HT/surface modified TiO2 hybrid system 67 3.4.2 Light harvesting in P3HT/surface modified TiO2 hybrid system 72 3.4.3 Charge separation in P3HT/surface modified TiO2 hybrid system 73 3.4.4 Charge recombination in P3HT/surface modified TiO2 hybrid system 79 3.4.5 Hybrid morphology and surface properties in P3HT/surface modified TiO2 hybrid system 84 3.4.5.1 Hydrophobicity of the surface modified TiO2 84 3.4.5.2 Surface morphology of P3HT/surface modified TiO2 hybrid films 86 3.4.5.3 Interface-modifier-induced ordering effect of P3HT in P3HT/surface modified TiO2 hybrid films 91 3.5 Device performance 97 Chapter 4 Conclusion 99 References 101 | |
dc.language.iso | en | |
dc.title | 二氧化鈦奈米晶體之表面改質應用於有機無機混摻太陽能電池之研究 | zh_TW |
dc.title | Study of Surface Modification of TiO2 Nanorod in Organic/Inorganic Hybrid solar cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王立義(Lee-Yih Wang),陳學禮(Shuen-Li Chen),蔡豐羽(Feng-Yu Tsai),薛景中(Jing-Jong Shyue) | |
dc.subject.keyword | 有機太陽能電池,聚三己基噻,吩,二氧化鈦奈米桿,異質接面結構,表面改質,表面改質分子, | zh_TW |
dc.subject.keyword | organic solar cell,poly (3-hexylthiophene),TiO2 nanorod,bulk heterojunction structure,surface modification,interface modifier, | en |
dc.relation.page | 107 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2009-08-14 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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