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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 童心欣(Hsin-Hsin Tung) | |
dc.contributor.author | Shan-chieh Tsai | en |
dc.contributor.author | 蔡善潔 | zh_TW |
dc.date.accessioned | 2021-05-20T20:02:02Z | - |
dc.date.available | 2009-08-21 | |
dc.date.available | 2021-05-20T20:02:02Z | - |
dc.date.copyright | 2009-08-21 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-08-20 | |
dc.identifier.citation | . '行政院環境保護署環境資料庫網頁.' from http://edb.epa.gov.tw/envdb2/.
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Toxicol 65: 104-111. Mahdavi, H., J. Amani, et al. (2008). 'Triphenylphosphine oxide on non-cross-linked maleimide-styrene copolymer support: As a novel stable phase transfer catalyst.' Catalysis Communications 9(15): 2532-2535. Morf, L. S. and P. H. Brunner (2000). 'Effect of operating conditions and input variations on.' Waste Management & Research 18: 4-15. Ore, S., J. Todorovic, et al. (2007). 'Toxicity of leachate from bottom ash in a road construction.' Waste Management 27(11): 1626-1637. Purushothama, S. (1997). 'Analysis of PAH from coal fly ash.' Fuel Processing Technology 53: 235-242. Rappe, C. (1992). 'Sources of PCDDs PCDFs. Introduction. reactions, levels, patterns, profiles and trends.' Chemosphere 25: 41-44. Shui-Jen Chena, Lien-Te Hsieha, Shui-Chi Chiu (2003). 'Characteristics of the PAH emissions from the incineration of livestock wastes with/without APCD.' Tessier, A., P. G. C. Campbell, et al. (2002). 'Sequential extraction procedure for the speciation of particulate trace metals.' Analytical Chemistry 51(7): 844. Theodoratos, P., N. Papassiopi, et al. (2002). 'Evaluation of monobasic calcium phosphate for the immobilization of heavy metals in contaminated soils from Lavrion.' Journal of Hazardous Materials B94: 135–146. Wozniak, D. J. and J. Y. C. Huang (1982). 'Variables Affecting Metal Removal from Sludge.' Journal (Water Pollution Control Federation) 54(12): 1574-1580. 工業污染防治技術服務團, Ed. (1996). 事業廢棄物焚化爐設計與選用手冊. 臺北市, 工 業汙染防治技術服務團. 王家麟. (2008). '次世代白光LED 用紅色發光Eu(Ⅲ)螢光體.' from http://www.asia-info.net/detail_elec.asp?id=7370. 行政院環境保護署. (2007). '一般廢棄物-垃圾焚化廠焚化底渣再利用管理方式.' from http://w3.epa.gov.tw/epalaw/docfile/074082.pdf. 吳佩勳 (2007). '都市焚化廠底渣再利用於鋪面工程及現地環境監測 ' 國立臺灣大學環 境工程學硏究所碩士論文. 李志偉, 李明國, et al. (2007). 都市垃圾焚化底渣以水萃及磷酸穩定為資源再利用前處 69 理程序之研究. 第22 屆廢棄物處理技術研討會. 李忠文 (2004). '焚化底渣水洗前處理及應用之探討.' 國立中央大學土木工程學系碩士 論文. 林育丞 (2003). '垃圾焚化底渣與水泥拌合後之潛在問題探討.' 國立中央大學土木工程 研究所碩士論文. 范文彬, 陳鴻亮, et al. (2006). 垃圾焚化底渣粒徑與重金屬總量及溶出量之探討」. 中 華民國環境工程學會第二十一屆廢棄物處理技術研討會. 孫常榮, 高思懷, et al. (2005). 磷酸穩定都市垃圾焚化底渣之研究(II)—銅、鋅之穩定」. 第十屆海峽兩岸環境保護學術研討會. 孫常榮, 高思懷, et al. (2005). 磷酸穩定都市垃圾焚化底渣之研究(I)-鉛之穩定. 第十 屆海峽兩岸環境保護學術研討會. 高思懷, 周錦東, et al. (1999). '都市垃圾焚化底灰對有機物質吸脫附特性之探討.' 第 十四屆廢棄物處理技術研討會: 7-15~7-22. 國賓大地環保事業股份有限公司 (2006). '焚化爐底渣於道路工程之應用.' 綠營建材料 再利用再生研討會. 張正弘 (2006). '感應加熱技術熱解處理生物污泥.' 嘉南藥理科技大學環境工程與科學 系碩士論文. 郭同宇, 蘇育立, et al. (2004). '應用於瀝青混凝土之垃圾焚化底渣材料特性探討.' 第 六屆鋪面材料再生學術研討會 E(15-1~8). 陳韋伶 (2004). '不同焚化爐底碴物化性質比較分析.' 國立中央大學土木工程研究所,碩 士論文. 經濟部工業局 (March 1996). '事業廢棄物焚化爐設計與選用手冊.' 雷揚中 (2004). '垃圾焚化爐底碴應用於道路基底層之研究.' 國立中央大學土木工程研 究所碩士論文. 盧宥宇 (June, 2008). '焚化底渣再利用於道路工程之長期環境監測.' 國立台灣大學環境 工程學研究所碩士論文. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/8823 | - |
dc.description.abstract | 隨著環保技術的演進,廢棄物的處理方式已由傳統的掩埋法轉為焚化處理。本研究
針對焚化底渣再生製成的底渣骨材為研究對象,追蹤偵測底渣骨材再生使用對環境 的長期性影響、底渣骨材的基本特性及水洗試驗的溶出特性。再生影響中顯示氯鹽 及溶出性有機物在初期會有大量溶出的情形,隨使用時間增加、溶出量已減少並漸 漸趨於穩定。底渣基本特性檢測顯示底渣再生之流程具有足夠的能力使重金屬形成 穩定化合物並減少重金屬的溶出量。水洗的溶出特性顯示溶解性有機物及重金屬會 在低液固比時溶出量減低,應是受到水洗液中氯鹽濃度提高而抑制溶出。水溫部分 對於高液固比的水洗實驗有較大的影響。但整體而言仍以20℃液固比20 的條件對 去除有機物、氯鹽及重金屬有最好的效果。在水洗液的半揮發性有機物檢測中,測 得triphenylphosphine oxide 出現於目前所有的樣品中。 | zh_TW |
dc.description.abstract | In this study, we evaluate the safety from monitoring of a road application with
incineration bottom ash. On the environmental monitoring of road application, there are high concentrations of dissolved organic carbon and chloride in sample at first. Despite the concentration reduce after three years, the construction of chemical bonding may become unstable because of low pH value. The elemental properties of bottom ash show the reprocessing of bottom ash has good ability in fixing heavy metal with stable chemical bonding. The water washing experiments showed a low concentration of dissolved organic carbon and heavy metals in low liquid to solid ratio. We also detect the triphenylphosphine oxide in water washing process in all samples. | en |
dc.description.provenance | Made available in DSpace on 2021-05-20T20:02:02Z (GMT). No. of bitstreams: 1 ntu-98-R96541123-1.pdf: 1675822 bytes, checksum: 7fcf9b0755516de04e737a1350b6f55c (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 目錄
第一章 前言....................................................................................................................... 1 1.1 研究源起.............................................................................................................. 1 1.2 研究目的.............................................................................................................. 2 1.3 研究項目.............................................................................................................. 2 第二章 文獻回顧............................................................................................................... 3 2.1 底渣骨材來源...................................................................................................... 3 2.1.1 焚化廠簡介............................................................................................... 3 2.1.2 焚化底渣骨材及飛灰............................................................................... 4 2.2 底渣骨材特性概論.............................................................................................. 5 2.2.1 物理成分................................................................................................... 5 2.2.2 物理特性................................................................................................... 6 2.2.3 化學組成................................................................................................... 6 2.3 底渣再利用相關法規.......................................................................................... 7 2.4 底渣再生.............................................................................................................. 8 2.5 底渣再利用的影響.............................................................................................11 第三章 工作內容及方法................................................................................................. 14 3.1 實場設計及研究對象........................................................................................ 14 3.2 研究及監測方法................................................................................................ 16 3.2.1 試驗道路現場環境水樣監測................................................................. 16 3.2.2 再利用材料之基本特性......................................................................... 19 3.2.3 再利用材料之水洗樣品研究................................................................. 21 第四章 結果與討論......................................................................................................... 24 4.1 現場採樣資料.................................................................................................... 24 4.1.1 pH 值........................................................................................................ 24 4.1.2 導電度..................................................................................................... 25 4.1.3 氯鹽......................................................................................................... 27 4.1.4 溶解性有機碳......................................................................................... 27 4.1.5 含氯有機物............................................................................................. 28 4.1.6 現場水樣重金屬..................................................................................... 29 4.1.7 雨量......................................................................................................... 34 4.2 底渣骨材基本特性............................................................................................ 36 4.2.1 底渣骨材水分......................................................................................... 36 4.2.2 TCLP..................................................................................................... 37 4.2.3 總重金屬................................................................................................. 38 4.3 底渣骨材水洗特性............................................................................................ 40 4.3.1 溶解性有機碳比較................................................................................. 40 4.3.2 氯鹽比較................................................................................................. 44 2 4.3.3 重金屬..................................................................................................... 47 4.3.4 水洗溶出的有機物................................................................................. 56 第五章 結論..................................................................................................................... 63 5.1 再利用道路現場採樣........................................................................................ 63 5.2 底渣骨材基本特性............................................................................................ 64 5.3 底渣骨材水洗特性............................................................................................ 65 5.4 建議.................................................................................................................... 66 文獻.................................................................................................................................. 67 表目錄 表一 2004 年台北縣底渣骨材之物理組成...................................................................... 5 表二 一般細骨材與垃圾焚化底渣骨材之物理性質比較表........................................... 6 表三 台灣現行底渣再生之TCLP 溶出標準................................................................... 8 表四 溶出總量估算......................................................................................................... 36 表五 台北縣底渣骨材含水率......................................................................................... 37 表六 TCLP 溶出量在總重金屬中的比例...................................................................... 40 表七 水洗底渣骨材溶出的半揮發性有機物................................................................. 57 圖目錄 圖一 鹵素與環境反應為含鹵有機物............................................................................. 12 圖二 萬里現場道路材料結構......................................................................................... 16 圖三 現場水樣分析流程................................................................................................. 17 圖四 底渣骨材實驗流程................................................................................................. 22 圖五 萬里現場水樣pH 值.............................................................................................. 25 圖六 萬里現場水樣導電度............................................................................................. 26 圖七 萬里現場水樣氯鹽................................................................................................. 27 圖八 萬里現場水樣溶解性有機碳................................................................................. 28 3 圖九 萬里現場水樣的含鹵有機物總量......................................................................... 29 圖十 萬里環境水樣As 濃度.......................................................................................... 30 圖十一 萬里環境水樣Ba 濃度...................................................................................... 31 圖十二 萬里環境水樣Cd 濃度...................................................................................... 31 圖十三 萬里環境水樣Cr 濃度....................................................................................... 32 圖十四 萬里環境水樣Cu 濃度...................................................................................... 32 圖十五 萬里環境水樣Pb 濃度...................................................................................... 33 圖十六 萬里環境水樣Se 濃度....................................................................................... 33 圖十七 萬里環境水樣Zn 濃度...................................................................................... 34 圖十八 萬里雨量............................................................................................................. 35 圖十九 樹林、新店、八里底渣骨材的TCLP 檢測結果............................................. 39 圖二十 樹林、新店、八里底渣骨材的總重金屬檢測結果......................................... 40 圖二十一 台北縣三廠水洗液DOC 比較...................................................................... 42 圖二十二 台北縣三廠單位底渣骨材DOC 比較.......................................................... 42 圖二十三 新店廠不同溫度水洗出的DOC................................................................... 43 圖二十四 新店廠不同溫度單位底渣骨材洗出的DOC............................................... 43 圖二十五 台北縣三廠水洗液氯鹽比較......................................................................... 45 圖二十六 台北縣三廠單位底渣骨材氯鹽比較............................................................. 45 圖二十七 新店廠不同溫度水洗出的氯鹽..................................................................... 46 圖二十八 新店廠不同溫度單位底渣骨材洗出的氯鹽................................................. 46 圖二十九 不同焚化廠底渣骨材洗出的As ................................................................... 49 圖三十 不同焚化廠底渣骨材洗出的Ba ....................................................................... 49 圖三十一 不同焚化廠底渣骨材洗出的Cd................................................................... 50 圖三十二 不同焚化廠底渣骨材洗出的Cr.................................................................... 50 圖三十三 不同焚化廠底渣骨材洗出的Cu................................................................... 51 圖三十四 不同焚化廠底渣骨材洗出的Pb ................................................................... 51 圖三十五 不同焚化廠底渣骨材洗出的Zn ................................................................... 52 圖三十六 不同焚化廠底渣骨材洗出的Se.................................................................... 52 4 圖三十七 不同溫度水洗新店廠底渣骨材洗出的As ................................................... 53 圖三十八 不同溫度水洗新店廠底渣骨材洗出的Ba ................................................... 53 圖三十九 不同溫度水洗新店廠底渣骨材洗出的Cd................................................... 54 圖四十 不同溫度水洗新店廠底渣骨材洗出的Cu....................................................... 54 圖四十一 不同溫度水洗新店廠底渣骨材洗出的Pb ................................................... 55 圖四十二 不同溫度水洗新店廠底渣骨材洗出的Zn ................................................... 55 圖四十三 不同溫度水洗新店廠底渣骨材洗出的Se.................................................... 56 圖四十四 20ppm 的鄰二氯苯標準品............................................................................ 58 圖四十五 空白組............................................................................................................. 58 圖四十六 三月份的樹林廠底渣骨材............................................................................. 59 圖四十七 三月份的新店廠底渣骨材............................................................................. 59 圖四十八 三月份的八里廠底渣骨材............................................................................. 60 圖五十 五月份的新店廠底渣骨材................................................................................. 61 圖五十一 五月份的八里廠底渣骨材............................................................................. 61 圖五十二triphenylphosphine oxide................................................................................. 62 | |
dc.language.iso | zh-TW | |
dc.title | 底渣實場應用之監測與半揮發性有機物檢測 | zh_TW |
dc.title | The Environmental Monitoring of a Road Application and
Detection of sVOC with Incineration Bottom Ash | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林正芳,顏秀慧 | |
dc.subject.keyword | 底渣,水洗,重金屬,溶解性有機碳, | zh_TW |
dc.subject.keyword | bottom ash,heavy metal,DOC, | en |
dc.relation.page | 93 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2009-08-20 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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