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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李篤中 | zh_TW |
| dc.contributor.advisor | Duu-Jong Lee | en |
| dc.contributor.author | 蔡瑞惟 | zh_TW |
| dc.contributor.author | RUEI-WEI TSAI | en |
| dc.date.accessioned | 2023-08-08T16:24:18Z | - |
| dc.date.available | 2023-11-09 | - |
| dc.date.copyright | 2023-08-08 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-07-13 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/88124 | - |
| dc.description.abstract | 本研究基於由三醛基間苯三酚(triformylphloroglucinol, TP) 合成出具有酮烯胺鍵結键的共價有機框架材料，其由二維層組成的超結構可以透過π-π作用堆疊機制形成。研究的目的是比較在pH應力條件下三種Tp-COFs（TpPa(OH)2、TpPaSO3Na和TpBu）對於銅離子的堆疊穩定性及相應吸附性能。
這三種Tp-COFs在25攝氏度的中性水中均具有高度穩定性。然而，pH -0.2的應力條件會大幅破壞TpPa(OH)2的層堆疊，使其在pH 7和-0.2條件下的吸附能力分別為93.92 mg g-1和80.57 mg g-1。對於具有鈉離子的TpPaSO3Na結構，在極酸的環境下，過多的質子會取代鈉離子。導致吸附量 qe 較低，中性吸附為 101.56 mg g-1，酸性吸附的 qe 值為 58.54 mg g-1。而對於具有最高穩定性的TpBu，pH應力條件對其影響極小，其吸附能力約為84 mg g-1。 COF的穩定性與酰胺基和胺基堆積形成的層間氫鍵有關。 根據結構分析，推測層間氫鍵量順序為TpBu>TpPaSO3Na>TpPa(OH)2。經過實驗確認以確定穩定性程度。 此外，pH波動實驗表明，COF在回到中性環境後不會恢復到原來的狀態。 | zh_TW |
| dc.description.abstract | This study is based on synthesizing covalent organic framework (COF) materials with keto-enamine linkages derived from triformylphloroglucinol (TP). These COFs, composed of two-dimensional layered structures, can form superstructures through π-π stacking interactions. The research compares the stacking stability and corresponding adsorption performance of three Tp-COFs (TpPa(OH)2, TpPaSO3Na, and TpBu) under pH stress conditions concerning copper ions.
All three Tp-COFs exhibit high stability in neutral water at 25oC. However, under pH -0.2 stress conditions, TpPa(OH) 2's layer stacking is significantly exfoliated, resulting in adsorption capacities of 93.92 mg g-1 and 80.57 mg g-1 at pH 7 and -0.2, respectively. For TpPaSO3Na, which incorporates sodium ions, the structural effects under acidic stress conditions result in protons substituting Na ions. It causes a low qe value for 101.56 mg g-1 for neutral adsorption, 58.54 mg g-1 for acidic adsorption. The most stable structure, TpBu, is minimally affected by pH stress conditions, with an adsorption capacity of approximately 84 mg g-1. The stability of COFs is related to the interlayer hydrogen bonds formed by the stacking of amide and amine groups. Based on structural analysis, it is inferred that the order of interlayer hydrogen bond abundance is TpBu > TpPaSO3Na > TpPa(OH)2. This is experimentally confirmed to determine the stability levels. Furthermore, the pH-swing experiment reveals that COFs do not revert to their original state after returning to a neutral environment. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-08-08T16:24:18Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-08-08T16:24:18Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | Acknowledgment i
Abstract ii 摘要 iii Content iv List of Figures v List of Tables x Chapter 1 Introduction 1 Chapter 2 Literature Review 4 2.1 Reticular chemistry 4 2.2 Structure of COF 5 2.2.1 3D and 2DCOFs 6 2.2.2 Layer stacking 6 2.3 Application 8 2.3.1 Energy storage device 8 2.3.2 Separation membrane 9 2.3.3 Catalysis 9 2.3.4 Chemical sensor 10 2.4 Modification 10 2.5 Aim for this work 11 Chapter 3 Experimental 12 3.1 Chemical used 12 3.2 COF samples 13 3.2.1 COF Synthesis 13 3.2.2 pH–swing COF 15 3.3 Batch adsorption experiment 15 3.4 Characterization 15 3.4.1 Fourier-transform infrared spectroscopy (FTIR) 15 3.4.2 Powder X-ray diffraction (PXRD) 15 3.4.3 Zeta potential 15 3.4.4 Inductively coupled plasma optical emission spectrometer (ICP-OES) 16 3.4.5 Scanning Electron Microscopy (SEM) 16 3.4.6 Nitrogen adsorption and desorption isotherm 16 3.4.7 X-ray Photoelectron Spectroscopy (XPS) 17 Chapter 4 Results and Discussion 18 4.1 COF characterization 18 4.1.1 Surface functional groups of COFs 18 4.1.2 PXRD of TpPa(OH)2, TpPaSO3Na and TpBu 21 4.1.3 Zeta potential of COF 24 4.1.5 Image of COF 25 4.1.5 Nitrogen sorption isotherms 26 4.4 Kinetic adsorption test (pH 7 and pH -0.2) 27 4.2 pH stressed Tp-COFs 33 4.3 COF stability 34 Chapter 5 Conclusions 47 Reference 48 | - |
| dc.language.iso | en | - |
| dc.subject | 穩定性 | zh_TW |
| dc.subject | 吸附 | zh_TW |
| dc.subject | 極端條件 | zh_TW |
| dc.subject | 酮-亞胺-COFs | zh_TW |
| dc.subject | 剝離 | zh_TW |
| dc.subject | extremely condition | en |
| dc.subject | keto-enamine-based COFs | en |
| dc.subject | exfoliation | en |
| dc.subject | stability | en |
| dc.subject | adsorption | en |
| dc.title | 酮-亞胺共價有機框架在極端 pH 條件下的穩定性 | zh_TW |
| dc.title | Stability of keto-enamine-based covalent organic frameworks under extreme pH’s | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 徐治平;曾琇瑱 | zh_TW |
| dc.contributor.oralexamcommittee | Jyh-Ping Hsu;Shio-jenn Tseng | en |
| dc.subject.keyword | 酮-亞胺-COFs,極端條件,剝離,吸附,穩定性, | zh_TW |
| dc.subject.keyword | keto-enamine-based COFs,extremely condition,exfoliation,adsorption,stability, | en |
| dc.relation.page | 53 | - |
| dc.identifier.doi | 10.6342/NTU202301507 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2023-07-14 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| 顯示於系所單位： | 化學工程學系 | |
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