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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳嘉文 | zh_TW |
| dc.contributor.advisor | Kevin C.-W. Wu | en |
| dc.contributor.author | 王御丞 | zh_TW |
| dc.contributor.author | Yu-Cheng Wang | en |
| dc.date.accessioned | 2023-08-08T16:12:31Z | - |
| dc.date.available | 2023-11-09 | - |
| dc.date.copyright | 2023-08-08 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-07-11 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/88080 | - |
| dc.description.abstract | 電致變色材料是一種在特定施加電壓下可以反復改變光學性質的物質。這類材料已廣泛應用於我們的日常生活中，例如智能鏡子、智能窗戶和各種可逆變色產品。含有電致變色材料的產品具備屏蔽外界過熱和輻射的能力，並可隨時切換。在近期的研究中，諸如紫精和導電聚合物等有機化合物因其易於調節顏色的特性而引起關注，成為了電致變色應用中最有前景的候選材料之一。
以呋喃為基底的電致色變材料長年在該領域被低估。這不僅是因為它們對光和氧氣的耐久性較低，而且在高氧化電位下不穩定，從而導致聚呋喃的合成困難與較不佳的色變性能。為了解決這個問題，我們實驗室開發了一種名為TriM的寡聚呋喃變色材料。除了其本身的可生物降解特性外, 寡聚呋喃在常溫常壓下相當穩定,而其較低的操作電壓也使得分子結構較不容易被破壞，從而擁有更長的使用壽命。然而，TriM在著色後並不能輕易恢復漂白狀態。為了提升性能，我們通過將寡聚呋喃與聯吡啶共軛，合成了一種名為TriMbpyPF6的新型單取代紫精。TriMbpyPF6不僅具備與TriM相似的特性，更利用作為官能基的聯吡啶得到了較高的褪色能力，並在施加還原電位的過程中了變出了第二種顏色。透過這項改動，TriMbpyPF6在解決TriM問題的基礎上，成為了一種具多變色能力的電致變色材料。 | zh_TW |
| dc.description.abstract | Electrochromic materials alter their optical properties back and forth under specific applied voltages. These kinds of materials have been widely utilized in our daily lives, such as smart mirrors, smart windows, and various color-changing products with reversibility. Those products that contain electrochromic materials possess the ability to shield excess heat and radiation from outside and can switch on and off at any time. In recent studies, organic compounds such as viologens and conducting polymers have aroused attention due to their easy color-tuning properties, which makes them one of the most promising candidates for electrochromic applications.
Furan-based materials are undervalued in the electrochromic field due to their low endurance to light and oxygen and their instability under high oxidation potentials, leading to the dismal performance of polyfurans. Therefore, our lab designed an electrochromic oligofuran called TriM. It is biodegradable and stable under ambient conditions and has a lower oxidation potential, resulting in fewer structural defects and longer life cycles. However, TriM exhibits a low bleaching ability after coloration. To circumvent this, we synthesized a novel monosubstituted viologen called TriMbpyPF6 by conjugating the oligofuran with the bipyridine moiety. TriMbpyPF6 shares similar electrochemical properties with TriM, but its bipyridine component not only provides higher decoloration ability but also introduces another color to the oligofuran system during the redox process. Through this modification, TriMbpyPF6 has become a multicolor electrochromic material, further enhancing the solution to the TriM problem. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-08-08T16:12:31Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-08-08T16:12:31Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | Table of Contents
Abstract i 摘要 iii Table of Contents iv List of Figures viii List of Tables xv 1.Introduction 1 1.1 Electrochromic device 4 1.2 Nickel hexacyanoferrate (III) (NiHCF) 6 1.3 Viologens 7 1.4 TriMbpyPF6 9 1.4.1. Hydroxyalkylation-alkylation (HAA) reaction 9 1.4.2. N-alkylation reaction 10 1.4.3. Anion exchange 11 2.Literature Review 13 3.Objective 15 4.Experimental 17 4.1. Chemicals and materials 17 4.2. Equipment 19 4.3. Electrochromic material synthesis 20 4.3.1. Synthesis of TriM 20 4.3.2. Synthesis of TriMbpyPF6 20 4.3.3. Synthesis of MvioPF6 24 4.4. Nanoparticled nickel hexacyanoferrarte (NiHCF) synthesis 24 4.4.1. Synthesis of NiHCF 24 4.4.2. Synthesis of nanoparticled NiHCF 25 4.5. ECD fabrication 25 4.5.1. Fabrication of the counter electrode 25 4.5.2. Fabrication of the working electrode 26 4.5.3. Fabrication of the whole electrochromic device 27 4.6. Three-electrode system 27 4.7. Two-electrode system 28 4.7.1. System set up 28 4.7.2. Spectrum absorbance and long-term optical change 28 4.7.3. Coloration efficiency measurement 29 4.8. Characterization of products 30 4.8.1. Nuclear magnetic resource (1H-NMR and 13C-NMR) spectroscopy 30 4.8.2. Gas Chromatography mass spectrometry (GC MS) 31 4.8.3. Electron spray ionization time of flight mass spectrometry (ESI-TOF MS) 31 5.Results and Discussion 32 5.1. Materials characterization 32 5.1.1. 1H-NMR and 13C-NMR 32 5.1.2. GC MS and ESI-TOF MS 35 5.2. Electrochemical properties of TriMbpyPF6 37 5.2.1. Plausible coloration mechanism of TriMbpyPF6 37 5.2.2. Electrochemical characterization of TriMbpyPF6 40 5.2.3. Diffusion of TriMbpyPF6 43 5.3. Factors affecting the performance of TriMbpyPF6 47 5.3.1. The solvent effect 47 5.3.2. The electrolyte effect 55 5.4. Performance optimization of TriMbpyPF6 65 5.4.1. Optical change (10 cycles) 65 5.4.2. Optical change (Higher cycles) 65 5.4.3. Coloration efficiency 71 5.3. Comparison between TriMbpyPF6 and TriM 74 6.Conclusion 81 7.Future Prospect 83 8.Reference 85 9.Appendix 96 9.1. 5-chloromethylfurfural characterization 96 | - |
| dc.language.iso | en | - |
| dc.subject | 多變色功能 | zh_TW |
| dc.subject | 生質能材料 | zh_TW |
| dc.subject | 呋喃寡聚物 | zh_TW |
| dc.subject | 紫精 | zh_TW |
| dc.subject | 電致色變元件 | zh_TW |
| dc.subject | 著色效率 | zh_TW |
| dc.subject | Furan oligomer | en |
| dc.subject | Biomass-derived | en |
| dc.subject | Multicolor | en |
| dc.subject | Coloration efficiency | en |
| dc.subject | Electrochromic device | en |
| dc.subject | Viologen | en |
| dc.title | 具多變色能力之新穎生質能材料-紫精修飾之呋喃寡聚物於電致變色元件之應用 | zh_TW |
| dc.title | A Novel Viologen-Functionalized Biomass-based Furan Oligomer for Electrochromic Device with Multicolor States | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 龔仲偉;陳林祈;葉禮賢;郭紹偉 | zh_TW |
| dc.contributor.oralexamcommittee | Chung-Wei Kung;Lin-Chi Chen;Li-Hsien Yeh;Shiao-Wei Kuo | en |
| dc.subject.keyword | 生質能材料,呋喃寡聚物,紫精,電致色變元件,著色效率,多變色功能, | zh_TW |
| dc.subject.keyword | Biomass-derived,Furan oligomer,Viologen,Electrochromic device,Coloration efficiency,Multicolor, | en |
| dc.relation.page | 96 | - |
| dc.identifier.doi | 10.6342/NTU202301414 | - |
| dc.rights.note | 未授權 | - |
| dc.date.accepted | 2023-07-13 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| 顯示於系所單位： | 化學工程學系 | |
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