請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/87972完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉懷勝 | zh_TW |
| dc.contributor.advisor | Hwai-Shen Liu | en |
| dc.contributor.author | 李承勳 | zh_TW |
| dc.contributor.author | Cheng-Hsun Li | en |
| dc.date.accessioned | 2023-08-01T16:09:46Z | - |
| dc.date.available | 2023-11-09 | - |
| dc.date.copyright | 2023-08-01 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-07-03 | - |
| dc.identifier.citation | Abanades, J. C. (2002). The maximum capture efficiency of CO2 using a carbonation/calcination cycle of CaO/CaCO3. Chemical Engineering Journal, 90(3), 303-306.
Adewole, J. K., Ahmad, A. L., Ismail, S., & Leo, C. P. (2013). Current challenges in membrane separation of CO2 from natural gas: A review. International Journal of Greenhouse Gas Control, 17, 46-65. Alper, E. (1990). Reaction mechanism and kinetics of aqueous solutions of 2-amino-2-methyl-1-propanol and carbon dioxide. Industrial & Engineering Chemistry Research, 29(8), 1725-1728. Anwar, M. N., Fayyaz, A., Sohail, N. F., Khokhar, M. F., Baqar, M., Yasar, A., Rasool, K., Nazir, A., Raja, M. U. F., Rehan, M., Aghbashlo, M., Tabatabaei, M., & Nizami, A. S. (2020). CO2 utilization: Turning greenhouse gas into fuels and valuable products. Journal of Environmental Management, 260, 110059. Arabi, N., Jauberthie, R., Chelghoum, N., & Molez, L. (2015). Formation of CSH in calcium hydroxide–blast furnace slag–quartz–water system in autoclaving conditions. Advances in Cement Research, 27(3), 153-162. Aschenbrenner, O., & Styring, P. (2010a). Comparative study of solvent properties for carbon dioxide absorption. Energy & Environmental Science, 3(8), 1106-1113. Aschenbrenner, O., & Styring, P. (2010b). Comparative study of solvent properties for carbon dioxide absorption. Energy & Environmental Science, 3(8). Athanassiadis, B., & Walsh, L. J. (2017). Aspects of solvent chemistry for calcium hydroxide medicaments. Materials, 10(10), 1219. Baciocchi, R., Carnevale, E., Costa, G., Gavasci, R., Lombardi, L., Olivieri, T., Zanchi, L., & Zingaretti, D. (2013). Performance of a biogas upgrading process based on alkali absorption with regeneration using air pollution control residues. Waste Management, 33(12), 2694-2705. Baciocchi, R., Corti, A., Costa, G., Lombardi, L., & Zingaretti, D. (2011). Storage of carbon dioxide captured in a pilot-scale biogas upgrading plant by accelerated carbonation of industrial residues. Energy Procedia, 4, 4985-4992. Baena-Moreno, F. M., Rodríguez-Galán, M., Vega, F., Reina, T., Vilches, L. F., & Navarrete, B. (2018). Regeneration of sodium hydroxide from a biogas upgrading unit through the synthesis of precipitated calcium carbonate: an experimental influence study of reaction parameters. Processes, 6(11), 205. Bates, E. D., Mayton, R. D., Ntai, I., & Davis, J. H. (2002). CO2 capture by a task-specific ionic liquid. Journal of the American Chemical Society, 124(6), 926-927. Bishnoi, S., & Rochelle, G. T. (2002). Absorption of carbon dioxide in aqueous piperazine/methyldiethanolamine. AIChE journal, 48(12), 2788-2799. Chandra, A., Goswami, P., & Rao, D. (2005). Characteristics of flow in a rotating packed bed (HIGEE) with split packing. Industrial & Engineering Chemistry Research, 44(11), 4051-4060. Chang, Y.-C., Leron, R. B., & Li, M.-H. (2013). Equilibrium solubility of carbon dioxide in aqueous solutions of (diethylenetriamine+ piperazine). The Journal of Chemical Thermodynamics, 64, 106-113. Chen, H., Tsai, T.-C., & Tan, C.-S. (2018). CO2 capture using amino acid sodium salt mixed with alkanolamines. International Journal of Greenhouse Gas Control, 79, 127-133. Chen, J.-F., Wang, Y.-H., Guo, F., Wang, X.-M., & Zheng, C. (2000). Synthesis of Nanoparticles with Novel Technology: High-Gravity Reactive Precipitation. Industrial & Engineering Chemistry Research, 39(4), 948-954. Chen, Z. (2022). A Review of Pre-combustion Carbon Capture Technology. 2022 7th International Conference on Social Sciences and Economic Development (ICSSED 2022), Cheng, H.-H., & Tan, C.-S. (2009). Carbon dioxide capture by blended alkanolamines in rotating packed bed. Energy Procedia, 1(1), 925-932. Chu, G.-W., Luo, Y., Shan, C.-Y., Zou, H.-K., Xiang, Y., Shao, L., & Chen, J.-F. (2014). Absorption of SO2 with Ammonia-Based Solution in a Cocurrent Rotating Packed Bed. Industrial & Engineering Chemistry Research, 53(40), 15731-15737. Cortes, G., E, G., van der Schaaf, J., & Kiss, A. A. (2017). A review on process intensification in HiGee distillation. Journal of Chemical Technology & Biotechnology, 92(6), 1136-1156. Dashti, M. S. A., & Abolhasani, M. (2020). Intensification of CO₂ capture by monoethanolamine solution containing TiO2 nanoparticles in a rotating packed bed. International Journal of Greenhouse Gas Control, 94, 102933. Dinul, F. I., Nurdin, H., Rahmadiawan, D., Laghari, I. A., & Elshaarani, T. (2023). Comparison of NaOH and Na2CO3 as absorbents for CO2 absorption in carbon capture and storage technology. Journal of Engineering Researcher and Lecturer, 2(1), 28-34. Du, Y., Wang, L., Guo, D., Ma, Z., & Shen, L. (2015). Preparation of Basic Copper Carbonate Microspheres by Precipitation Method. 2015 6th International Conference on Manufacturing Science and Engineering, Duchesne, J., & Reardon, E. J. (1995). Measurement and prediction of portlandite solubility in alkali solutions. Cement and Concrete Research, 25(5), 1043-1053. Fowler, R. (1989). Higee-a status report. Chemical Engineer, 35-37. Freeman, S. A., Davis, J., & Rochelle, G. T. (2010). Degradation of aqueous piperazine in carbon dioxide capture. International Journal of Greenhouse Gas Control, 4(5), 756-761. Ghg, I. (2004). Improvement in power generation with post-combustion capture of CO2. Report PH4/33. IEA Greenhouse Gas R&D Programme. Girnus, I., Jancke, K., Vetter, R., Richter-Mendau, J., & Caro, J. (1995). Large AlPO4-5 crystals by microwave heating. Zeolites, 15(1), 33-39. Gomes, J., Santos, S., & Bordado, J. (2015). Choosing amine-based absorbents for CO2 capture. Environmental technology, 36(1), 19-25. Gondal, S., Asif, N., Svendsen, H. F., & Knuutila, H. (2015). Kinetics of the absorption of carbon dioxide into aqueous hydroxides of lithium, sodium and potassium and blends of hydroxides and carbonates. Chemical Engineering Science, 123, 487-499. Grunewald, N., & Martinez-Zarzoso, I. (2016). Did the Kyoto Protocol fail? An evaluation of the effect of the Kyoto Protocol on CO2 emissions. Environment and Development Economics, 21(1), 1-22. Guo, F., Zheng, C., Guo, K., Feng, Y., & Gardner, N. C. (1997). Hydrodynamics and mass transfer in cross-flow rotating packed bed. Chemical Engineering Science, 52(21-22), 3853-3859. Hattori, Y., Haruna, Y., & Otsuka, M. (2013). Dissolution process analysis using model-free Noyes–Whitney integral equation. Colloids and Surfaces B: Biointerfaces, 102, 227-231. Heda, P. K., Dollimore, D., Alexander, K. S., Chen, D., Law, E., & Bicknell, P. (1995). A method of assessing solid state reactivity illustrated by thermal decomposition experiments on sodium bicarbonate. Thermochimica acta, 255, 255-272. Hikita, H., Asai, S., Katsu, Y., & Ikuno, S. (1979). Absorption of carbon dioxide into aqueous monoethanolamine solutions. AIChE journal, 25(5), 793-800. Jagannathan, T., Chandramouli, A., Ramachandran, K., Shlok Dev, E. L. D., Sharma, K., & Rajamani, C. (2021). Use of drone with sodium hydroxide carriers to absorb carbon dioxide from ambient air. J Emerg Invest. Jassim, M. S., Rochelle, G., Eimer, D., & Ramshaw, C. (2007). Carbon dioxide absorption and desorption in aqueous monoethanolamine solutions in a rotating packed bed. Industrial & Engineering Chemistry Research, 46(9), 2823-2833. Johnston, J., & Grove, C. (1931). The solubility of calcium hydroxide in aqueous salt solutions. Journal of the American Chemical Society, 53(11), 3976-3991. Kar, S., Goeppert, A., Galvan, V., Chowdhury, R., Olah, J., & Prakash, G. K. S. (2018). A Carbon-Neutral CO2 Capture, Conversion, and Utilization Cycle with Low-Temperature Regeneration of Sodium Hydroxide. J Am Chem Soc, 140(49), 16873-16876. Keyvani, M. (1989). Operating characteristics of rotating beds. Case Western Reserve University. Konno, H., Nanri, Y., & Kitamura, M. (2002). Crystallization of aragonite in the causticizing reaction. Powder Technology, 123(1), 33-39. Kucka, L., Kenig, E. Y., & Górak, A. (2002). Kinetics of the Gas−Liquid Reaction between Carbon Dioxide and Hydroxide Ions. Industrial & Engineering Chemistry Research, 41(24), 5952-5957. Lerner, E., Sarig, S., & Azoury, R. (1991). Enhanced maturation of hydroxyapatite from aqueous solutions using microwave irradiation. Journal of Materials Science: Materials in Medicine, 2, 138-141. Li, J., Zeng, T., Kobayashi, N., Xu, H., Bai, Y., Deng, L., He, Z., & Huang, H. (2019). Lithium hydroxide reaction for low temperature chemical heat storage: hydration and dehydration reaction. Energies, 12(19), 3741. Li, Y., Chu, G., Sun, B., Chen, J., & Shao, L. (2015). Absorption of ammonia into water-in-oil microemulsion in a rotor-stator reactor. Chemical Engineering and Processing: Process Intensification, 87, 68-74. Li, Y., Ji, J., Xu, Z., Wang, G., Li, X., & Liu, X. (2013). Pressure drop model on rotating zigzag bed as a new high-gravity technology. Industrial & Engineering Chemistry Research, 52(12), 4638-4649. Li, Y., Wang, S., Sun, B., Arowo, M., Zou, H., Chen, J., & Shao, L. (2015). Visual study of liquid flow in a rotor-stator reactor. Chemical Engineering Science, 134, 521-530. Lima, E. C., Gomes, A. A., & Tran, H. N. (2020). Comparison of the nonlinear and linear forms of the van't Hoff equation for calculation of adsorption thermodynamic parameters (∆S° and ∆H°). Journal of Molecular Liquids, 311, 113315. Lin, C.-C., & Chen, B.-C. (2007). Carbon dioxide absorption into NaOH solution in a cross-flow rotating packed bed. Journal of Industrial and Engineering Chemistry, 13(7), 1083-1090. Lin, C.-C., & Chen, B.-C. (2011). Carbon dioxide absorption in a cross-flow rotating packed bed. Chemical Engineering Research and Design, 89(9), 1722-1729. Lin, C.-C., & Chen, Y.-W. (2011). Performance of a cross-flow rotating packed bed in removing carbon dioxide from gaseous streams by chemical absorption. International Journal of Greenhouse Gas Control, 5(4), 668-675. Lin, C.-C., Liu, W.-T., & Tan, C.-S. (2003). Removal of carbon dioxide by absorption in a rotating packed bed. Industrial & Engineering Chemistry Research, 42(11), 2381-2386. Lin, P.-H., & Wong, D. S. H. (2014). Carbon dioxide capture and regeneration with amine/alcohol/water blends. International Journal of Greenhouse Gas Control, 26, 69-75. Liu, H., & Azimi, G. (2022). Production of Battery Grade Lithium Hydroxide Monohydrate Using Barium Hydroxide Causticizing Agent. Resources, Conservation and Recycling, 179, 106115. Liu, H.-S., Chen, K.-A., & Tai, C. Y. (2012). Droplet stability and product quality in the Higee-assisted microemulsion process for preparing CaCO3 particles. Chemical Engineering Journal, 197, 101-109. Liu, R. S., Shi, X. D., Wang, C. T., Gao, Y. Z., Xu, S., Hao, G. P., Chen, S., & Lu, A. H. (2021). Advances in post‐combustion CO2 capture by physical adsorption: from materials innovation to separation practice. ChemSusChem, 14(6), 1428-1471. Liu, W., McKibbin, W. J., Morris, A. C., & Wilcoxen, P. J. (2020). Global economic and environmental outcomes of the Paris Agreement. Energy Economics, 90, 104838. Liu, Y., Gu, D., Xu, C., Qi, G., & Jiao, W. (2015). Mass transfer characteristics in a rotating packed bed with split packing. Chinese Journal of Chemical Engineering, 23(5), 868-872. Liu, Z., Esmaeili, A., Zhang, H., Wang, D., Lu, Y., & Shao, L. (2022). Modeling and Experimental Studies on Carbon Dioxide Absorption with Sodium Hydroxide Solution in a Rotating Zigzag Bed. Processes, 10(3), 614. Lombardia, L., Corti, A., Carnevale, E., Baciocchi, R., & Zingaretti, D. (2011). Carbon dioxide removal and capture for landfill gas up-grading. Energy Procedia, 4, 465-472. Luo, Y., Chu, G., Sang, L., Zou, H., Xiang, Y., & Chen, J. (2016). A two-stage blade-packing rotating packed bed for intensification of continuous distillation. Chinese Journal of Chemical Engineering, 24(1), 109-115. Luo, Y., Chu, G.-W., Zou, H.-K., Xiang, Y., Shao, L., & Chen, J.-F. (2012). Characteristics of a two-stage counter-current rotating packed bed for continuous distillation. Chemical Engineering and Processing: Process Intensification, 52, 55-62. Ma'mun, S., Dindore, V. Y., & Svendsen, H. F. (2007). Kinetics of the reaction of carbon dioxide with aqueous solutions of 2-((2-aminoethyl) amino) ethanol. Industrial & Engineering Chemistry Research, 46(2), 385-394. Madejski, P., Chmiel, K., Subramanian, N., & Kuś, T. (2022). Methods and techniques for CO2 capture: Review of potential solutions and applications in modern energy technologies. Energies, 15(3), 887. Mahmoudkhani, M., & Keith, D. W. (2009). Low-energy sodium hydroxide recovery for CO2 capture from atmospheric air—Thermodynamic analysis. International Journal of Greenhouse Gas Control, 3(4), 376-384. Maloney, J. O. (2008). Perry Chemical Engineers Handbook. In: The McGraw-Hill Companies, Inc. Mandal, B., Guha, M., Biswas, A., & Bandyopadhyay, S. (2001). Removal of carbon dioxide by absorption in mixed amines: modelling of absorption in aqueous MDEA/MEA and AMP/MEA solutions. Chemical Engineering Science, 56(21-22), 6217-6224. Manzano Martínez, A. N., van Eeten, K. M. P., Schouten, J. C., & van der Schaaf, J. (2017). Micromixing in a Rotor–Stator Spinning Disc Reactor. Industrial & Engineering Chemistry Research, 56(45), 13454-13460. Mao, X., ren, W., & Tran, H. (2015). measurement of free lime content in lime mud. Tappi Journal, 14(7), 481-489. Mason, T. J. (1997). Ultrasound in synthetic organic chemistry. Chemical Society Reviews, 26(6), 443-451. Mihai, M., Turtoi, D., Mateescu, C., & Chilibon, I. (2009). Calcium carbonate synthesis in ultrasonic field. Revista De Chimie, 60(6), 626-631. Morales, J., Sánchez, L., Martín, F., Ramos-Barrado, J. R., & Sánchez, M. (2005). Use of low-temperature nanostructured CuO thin films deposited by spray-pyrolysis in lithium cells. Thin Solid Films, 474(1), 133-140. Nagano, T., Miyao, S., & Niimi, N. (1976). Method of recovering sodium hydroxide from sulfur free pulping or bleaching waste liquor by mixing ferric oxide with condensed waste liquor prior to burning. In: Google Patents. Nascimento, J., Ravagnani, T., & Pereira, J. (2009). Experimental study of a rotating packed bed distillation column. Brazilian journal of chemical engineering, 26, 219-226. Notidis, E. (1995). The Formation of Guarded Sodium in Lime Mud. National Library of Canada= Bibliothèque nationale du Canada, Ottawa. Nourredine, A., Jauberthie, R., Nourredine, C., & Molez, L. (2014). Formation of C-S-H in calcium hydroxide-blast furnace slag-Quartz-water system In autoclaving conditions. Advances in Cement Research, 27. Olajire, A. A. (2010). CO2 capture and separation technologies for end-of-pipe applications – A review. Energy, 35(6), 2610-2628. Ottani, S., Vitalini, D., Comelli, F., & Castellari, C. (2002). Densities, viscosities, and refractive indices of poly (ethylene glycol) 200 and 400+ cyclic ethers at 303.15 K. Journal of Chemical & Engineering Data, 47(5), 1197-1204. Ozkan, M. (2021). Direct air capture of CO2: A response to meet the global climate targets. MRS Energy & Sustainability, 8(2), 51-56. Pallagi, A., Tasi, Á., Gácsi, A., Csáti, M., Pálinkó, I., Peintler, G., & Sipos, P. (2012). The solubility of Ca(OH)2 in extremely concentrated NaOH solutions at 25°C. Open Chemistry, 10(2), 332-337. Pani, F., Gaunand, A., Cadours, R., Bouallou, C., & Richon, D. (1997). Kinetics of absorption of CO2 in concentrated aqueous methyldiethanolamine solutions in the range 296 K to 343 K. Journal of Chemical & Engineering Data, 42(2), 353-359. Price, G. J., Mahon, M. F., Shannon, J., & Cooper, C. (2011). Composition of calcium carbonate polymorphs precipitated using ultrasound. Crystal Growth & Design, 11(1), 39-44. Puranik, S. (2020). Solubility of Ca (OH) 2 in glycerol-water solutions at various temperatures. Int J Grid Distrib Comput, 13, 28-34. Purba, E., Yogia, C., & Sari, P. (2021). Biogas Purification by CO₂ Reduction in Bubble Column Using Ca (OH) ₂ and NaOH. International Conference on Sustainable Biomass (ICSB 2019), Ramshaw, C., & Mallinson, R. H. (1981). Mass transfer process. In: Google Patents. Rodríguez-Clemente, R., & Gómez-Morales, J. (1996). Microwave precipitation of CaCO3 from homogeneous solutions. Journal of Crystal Growth, 169(2), 339-346. Rogers, E. S., Iris. (2000). Fundamentals of Chemistry: Solubility. Department of Chemistry. University of Wisconsin. Archived from the original. Rydin, S. (1978). THE KINETICS OF THE CAUSTICIZING REACTION. S. Dzuhri1, N. Y. Y., O. Anuar, I. Nasharudin, O. Rohaya (2014). Synthesis of Precipitated Calcium Carbonate from Industrial Waste Carbide Lime by Using Sucrose as Promoter. International Journal of the Institute of Material Malaysia 204-210. Sawistowski, H. (1957). Flooding velocities in packed columns operating at reduced pressures. Chemical Engineering Science, 6(3), 138-140. Sayari, A., Belmabkhout, Y., & Serna-Guerrero, R. (2011). Flue gas treatment via CO2 adsorption. Chemical Engineering Journal, 171(3), 760-774. Schrödle, S., Buchner, R., & Kunz, W. (2004). Effect of the chain length on the inter-and intramolecular dynamics of liquid oligo (ethylene glycol) s. The Journal of Physical Chemistry B, 108(20), 6281-6287. Shen, J.-F., Yang, Y.-M., & Maa, J.-R. (2000). Chemical enhancement for CO2 absorption into dilute aqueous amine solutions. Journal of the Chinese Institute of Chemical Engineers, 31(1), 11-18. Shim, J.-G., Lee, D. W., Lee, J. H., & Kwak, N.-S. (2016). Experimental study on capture of carbon dioxide and production of sodium bicarbonate from sodium hydroxide. Environmental Engineering Research, 21(3), 297-303. Siriwardane, R. V., Robinson, C., Shen, M., & Simonyi, T. (2007). Novel regenerable sodium-based sorbents for CO2 capture at warm gas temperatures. Energy & Fuels, 21(4), 2088-2097. Stankiewicz, A., & Moulijn, J. A. (2000). Process Intensification- Transforming Chemical Engineering. Chemical Engineering Progress 96(1), 22-33. Su, M., Han, J., Li, Y., Chen, J., Zhao, Y., & Chadwick, K. (2015). Ultrasonic Crystallization of Calcium Carbonate in Presence of Seawater Ions. Desalination, 369, 85-90. Sun, B.-C., Wang, X.-M., Chen, J.-M., Chu, G.-W., Chen, J.-F., & Shao, L. (2011). Synthesis of nano-CaCO3 by simultaneous absorption of CO2 and NH3 into CaCl2 solution in a rotating packed bed. Chemical Engineering Journal, 168(2), 731-736. Tan, C.-S., & Chen, J.-E. (2006). Absorption of carbon dioxide with piperazine and its mixtures in a rotating packed bed. Separation and purification technology, 49(2), 174-180. Tavan, Y., & Hosseini, S. H. (2017). A novel rate of the reaction between NaOH with CO2 at low temperature in spray dryer. Petroleum, 3(1), 51-55. Teoh, Y.-Y., Athanassiadis, B., & Walsh, L. J. (2016). The influence of aqueous and PEG 400 solvent vehicles on hydroxyl ion release from calcium hydroxide medicaments. International Dentistry (Australasian Edition), 11(4), 42-50. Thomas, C., Loodts, V., Rongy, L., & De Wit, A. (2016). Convective dissolution of CO2 in reactive alkaline solutions: Active role of spectator ions. International Journal of Greenhouse Gas Control, 53, 230-242. Tran, H. N., Bair, C. M., & McBroom, R. B. (2002). Method of increasing the causticizing efficiency of alkaline pulping liquor by borate addition. In: Google Patents. Trisnaliani, L., Pranata, D. E., Ridwan, K., Alfarizi, M. N., & Lumbantoruan, M. P. (2020). The Effect of flowrate and NaOH concentration to CO2 reduction in biogas products using absorber. Journal of Physics: Conference Series, Ünveren, E. E., Monkul, B. Ö., Sarıoğlan, Ş., Karademir, N., & Alper, E. (2017). Solid amine sorbents for CO2 capture by chemical adsorption: A review. Petroleum, 3(1), 37-50. Vaidya, P. D., & Kenig, E. Y. (2007). CO2‐alkanolamine reaction kinetics: a review of recent studies. Chemical Engineering & Technology: Industrial Chemistry‐Plant Equipment‐Process Engineering‐Biotechnology, 30(11), 1467-1474. Wang, G., Xu, O., Xu, Z., & Ji, J. (2008). New HIGEE-rotating zigzag bed and its mass transfer performance. Industrial & Engineering Chemistry Research, 47(22), 8840-8846. Wang, G., Xu, Z., Yu, Y., & Ji, J. (2008). Performance of a rotating zigzag bed—A new HIGEE. Chemical Engineering and Processing: Process Intensification, 47(12), 2131-2139. Wang, L., Jiang, W., & Fan, Z. (2018). Study on causticizing process of sewage discharged from wet reclamation of waste sodium silicate sand. IOP Conference Series: Earth and Environmental Science, Wang, L., Tessier, P. C., & Englezos, P. (1994). Thermodynamics and kinetics of the kraft causticizing reaction. The Canadian Journal of Chemical Engineering, 72(2), 314-320. Wang, M., Lawal, A., Stephenson, P., Sidders, J., & Ramshaw, C. (2011). Post-combustion CO2 capture with chemical absorption: A state-of-the-art review. Chemical Engineering Research and Design, 89(9), 1609-1624. Wang, Y. M., & Chen, Y. S. (2019). Capture of CO2 by highly concentrated alkanolamine solutions in a rotating packed bed. Environmental Progress & Sustainable Energy, 38(6), e13263. Wang, Z., Yang, T., Liu, Z., Wang, S., Gao, Y., & Wu, M. (2019). Mass Transfer in a Rotating Packed Bed: A Critical Review. Chemical Engineering and Processing - Process Intensification, 139, 78-94. Wu, S., Zhang, L., Sun, B., Zou, H., Zeng, X., Luo, Y., Li, Q., & Chen, J. (2017). Mass-transfer performance for CO2 absorption by 2-(2-aminoethylamino) ethanol solution in a rotating packed bed. Energy & Fuels, 31(12), 14053-14059. Xiao, J., Li, C.-W., & Li, M.-H. (2000). Kinetics of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1-propanol+ monoethanolamine. Chemical Engineering Science, 55(1), 161-175. Xie, P., Lu, X., Yang, X., Ingham, D., Ma, L., & Pourkashanian, M. (2017). Characteristics of liquid flow in a rotating packed bed for CO2 capture: A CFD analysis. Chemical Engineering Science, 172, 216-229. Yoo, M., Han, S.-J., & Wee, J.-H. (2013). Carbon dioxide capture capacity of sodium hydroxide aqueous solution. Journal of Environmental Management, 114, 512-519. Yu, C.-H., Huang, C.-H., & Tan, C.-S. (2012). A Review of CO2 Capture by Absorption and Adsorption. Aerosol and Air Quality Research, 12(5), 745-769. Yu, C.-H., Wu, T.-W., & Tan, C.-S. (2013). CO2 capture by piperazine mixed with non-aqueous solvent diethylene glycol in a rotating packed bed. International Journal of Greenhouse Gas Control, 19, 503-509. Yuan, B., Wang, J., Cai, W., Yang, Y., Yi, M., & Xiang, L. (2017). Effects of temperature on conversion of Li2CO3 to LiOH in Ca(OH)2 suspension. Particuology, 34, 97-102. Zhao, H., Shao, L., & Chen, J.-F. (2010). High-gravity process intensification technology and application. Chemical Engineering Journal, 156(3), 588-593. 陳昱劭, 彭筱涵, & 劉子雯. (2016). 以超重力技術製備粉粒體. 化工, 63(2), 3-14. 李德威 (2016)。旋轉填充床中氫氧化鈉/甘油水溶液吸收二氧化碳. 臺灣大學化學工程學研究所學位論文 黃微雅 (2020)。旋轉填充床中氫氧化鈉/氫氧化鈣吸收二氧化碳之程序-原位吸收劑再生及循環. 臺灣大學化學工程學研究所學位論文 蔡宗熹 (2021).旋轉填充床中以氫氧化鈉吸收二氧化碳及吸收劑再生.臺灣大學化學工程學研究所學位論文. 張雯媛 (2022). 結合旋轉填充床中以氫氧化鈉捕捉二氧化碳及沈澱法後處理程序開發.臺灣大學化學工程學研究所學位論文. | - |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/87972 | - |
| dc.description.abstract | 由於工業發展致使大量排放二氧碳，進而導致溫室效應，這是近年不可忽視的議題，現今工業上最常用的吸收二氧化碳方法為透過醇胺吸收劑進行化學吸收，其優點在於吸收容量大以及反應速率快；而缺點則是吸收劑高黏度造成操作不易、所需設備體積龐大以及再生所需能耗較大，因此，除了吸收的效率外再生成本、效率也是一項考量因素。
故本實驗利用可以於室溫再生的氫氧化鈉為吸收劑，並使用旋轉填充床高質傳特性來提升吸收二氧化碳之能力，再利用氫氧化鈣來進行吸收劑之再生，達成RPB循環吸收/再生系統。本研究首先進行再生方法的改進，找出最佳的再生條件，再調整吸收條件，使吸收程序可以良好的搭配再生程序，設計出一個最佳的反應流程。在再生階段的研究分別進行再生溫度、氫氧化鈉濃度 、氫氧化鈣添加比例、 吸收時間 、 分次再生、調整溶劑、程序強化；而吸收方面分別進行吸收溫度 、 氫氧化鈉吸收劑濃度、 調整吸收劑、 液體流量 、氫氧根離子濃度與吸收百分比關係、Na2CO3濃度、吸收次數。 研究結果顯示，通過將旋轉填充床和旋轉盤相連，我們可以實現更高效的RPB循環吸收/再生系，使用旋轉填充床進行吸收，而旋轉盤進行再生。在此系統中，選擇了1L、0.9M濃度的氫氧化鈉作為吸收劑以維持80%吸收率以上為目標，在每次吸收20分鐘後進行再生有最佳的效果，同時，研究還顯示在55度的溫度下適量添加氫氧化鈣可獲得最佳的再生反應效果。在這樣的操作條件下，再生時間可以縮短至10分鐘，並且轉化率可以達到90%。 此外，通過這項研究還發現，Na2CO3的累積對吸收二氧化碳的效果具有負面影響。當氫氧化鈉重複循環15次後，二氧化碳的吸收百分比會降至80%以下。此時引入了硫酸銅作為添加物，將Na2CO3完全轉化為鹼式碳酸銅和二氧化碳，從而實現了商業應用的可能性。 這樣的操作流程實現了吸收劑的循環利用，不僅節省了資源和成本，同時也達到了低耗能、低污染、低水耗並有效捕捉二氧化碳的目標。這項研究為實現氫氧化鈉循環吸收和再生系統的優化，為未來的碳捕獲和利用技術的發展做出了貢獻。 | zh_TW |
| dc.description.abstract | Due to industrial development in recent years, a large amount of carbon dioxide emission causes the greenhouse effect that cannot be ignored. Currently, the most commonly used method to absorb carbon dioxide is by using alkanol amine solvents as the chemical absorbent. It has the advantages of high absorption efficiency and fast reaction rate; However, it also has drawbacks, including the high viscosity of the absorbent, large equipment size and high energy consumption required for absorbent regeneration.
Therefore, in this study, a Rotating Packed Bed (RPB) of high mass transfer performance was adopted to capture CO2 with sodium hydroxide in a circulating mode. Then, the Ca(OH)2 was added for the absorbent regeneration, also called causticization. The research aimed to optimize the regeneration method by identifying the optimal process conditions of both absorption and regeneration. In the regeneration, the study was focused on the parameters of temperature, NaOH concentration, Ca(OH)2 addition ratio, absorption time, two-staged regeneration, solvent aditives, and process intensification by ultrasound or centeifual force. In the absorption, temperature, NaOH concentration, absorbent additves, liquid flow rate, the relationship between absorption percentage and hydroxide ion concentration, the concentration of Na2CO3, and absorption cycles. The results showed that by connecting the rotating packed bed and rotating disc, we could achieve an efficient RPB Circulating Absorption/Regeneration System. Absorption is performed using a rotating packed bed, while regeneration is carried out using a rotating disc. In this system, we selected 1L, 0.9M concentration of sodium hydroxide as the absorbent to ensure 80% and up absorption performance, and found that the optimal regeneration was achieved by regenerate the absorbent after 20 minutes absorption. The study also revealed that the best regeneration temperature was 55oC at which 90% conversion was obtained in 10 mins. Furthermore, it was observed that the accumulation of sodium carbonate had a negative impact on CO2 absorption efficiency. After 15 cycles of sodium hydroxide circulation, the CO2 absorption percentage could not maintain above 80%. To address this issue, copper sulfate was added as it to fully convert Na2CO3 into Cu2(OH)2CO3 that could be serve as a precursor for CuO. In this study, an absorption/regeneration process incorporating RPB/SDR was presented and investigated. It could successfully capture CO2 emission and achieve the goals of low energy consumption, low pollution, low water consumption. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-08-01T16:09:46Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-08-01T16:09:46Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 摘要 I
Abstract III 目錄 V 圖目錄 VIII 表目錄 XVI 第一章 緒論 1 第二章 文獻回顧 2 2-1 全球對全球暖化策略 2 2-2 CO2捕捉技術 3 2-2.1 化學吸收法 6 2-2.2 不同氫氧化物化學吸收 9 2-2.3 氫氧化鈉化學吸收 10 2-2.4 溶劑的選擇 11 2-3 吸收劑的再生 13 2-3.1 苛化反應 14 2-3.2 苛化反應不完全探討 14 2-3.3 加強苛化反應轉化率 15 2-3.4 提升Ca(OH)2的溶解度 16 2-3.5 程序強化 19 2-4 旋轉填充床 22 2-4.1 旋轉填充床的構造與設計 23 2-4.2 旋轉填充床之應用及其優點 28 2-4.3 旋轉填充床吸收CO2 29 第三章 實驗設備與分析方法 34 3-1 實驗裝置 34 3-2 實驗藥品、儀器與實驗流程 35 3-2.1 實驗藥品 35 3-2.2 實驗儀器 35 3-2.3 實驗流程 36 3-3 實驗分析 39 3-3.1 吸收百分比A (absorption percentage) 39 3-3.2 轉化率X(conversion) 39 3-4 化學反應 40 3-5 物性資料 42 第四章 實驗結果與討論 43 4-1 控制再生條件來提升轉化率 43 4-1.1 再生溫度 43 4-1.2 NaOH濃度 51 4-1.3 Ca(OH)2添加比例 55 4-1.4 吸收時間 57 4-1.5 分次再生 61 4-1.6 調整溶劑 64 4-1.7 程序強化 77 4-2 研究吸收系統 86 4-2.1 吸收溫度 86 4-2.2 NaOH吸收劑濃度 87 4-2.3 調整吸收劑 90 4-2.4 吸收劑液體流量 92 4-2.5 氫氧根離子與吸收百分比的關係 94 4-2.6 Na2CO3濃度 96 4-3 循環系統研究 99 4-3.1 對於吸收再生循環系統之最佳溫度 101 4-3.2 加入蔗糖於循環系統 102 4-3.3 細胞破碎機進行吸收再生循環系統 104 4-3.4 旋轉盤進行吸收再生循環 106 4-3.5 再生影響的條件(細胞破碎機+溫度 ) 108 4-3.6 再生影響的條件(旋轉盤+溫度 ) 109 4-3.7 循環次數對吸收百分比的影響 110 4-3.8 再生系統中的過濾 113 4-3.9 旋轉盤進行吸收 115 4-3.10 最終產物變換 120 4-4 最終設計 123 第五章 結論 126 符號說明 129 參考資料 131 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 吸收百分比 | zh_TW |
| dc.subject | 旋轉填充床 | zh_TW |
| dc.subject | CO2捕捉 | zh_TW |
| dc.subject | 吸收劑再生 | zh_TW |
| dc.subject | 苛化反應 | zh_TW |
| dc.subject | causticization | en |
| dc.subject | absorbent regeneration | en |
| dc.subject | carbon dioxide capture | en |
| dc.subject | rotating packed bed | en |
| dc.subject | absorption percentage | en |
| dc.title | 旋轉填充床中氫氧化鈉吸收二氧化碳 及苛化再生反應之改善 | zh_TW |
| dc.title | Carbon Dioxide Capture by Sodium Hydroxide in a Rotating Packed Bed and Improvement of Causticizing Regeneration Reaction | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-2 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 陳昱劭;江佳穎 | zh_TW |
| dc.contributor.oralexamcommittee | Yu-Shao Chen ;Chia-Ying Chiang | en |
| dc.subject.keyword | 旋轉填充床,CO2捕捉,吸收劑再生,吸收百分比,苛化反應, | zh_TW |
| dc.subject.keyword | rotating packed bed,carbon dioxide capture,absorbent regeneration,absorption percentage,causticization, | en |
| dc.relation.page | 140 | - |
| dc.identifier.doi | 10.6342/NTU202300981 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2023-07-05 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 化學工程學系 | - |
| dc.date.embargo-lift | 2025-07-03 | - |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-111-2.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 12.64 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。