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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 許麗 | zh_TW |
| dc.contributor.advisor | Li Xu | en |
| dc.contributor.author | 黃章栢 | zh_TW |
| dc.contributor.author | Zhang-Bo Huang | en |
| dc.date.accessioned | 2023-05-10T16:05:03Z | - |
| dc.date.available | 2023-11-09 | - |
| dc.date.copyright | 2023-05-10 | - |
| dc.date.issued | 2023 | - |
| dc.date.submitted | 2023-02-09 | - |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/87123 | - |
| dc.description.abstract | 置身於第三代太陽能電池領域技術發展中，鈣鈦礦太陽能電池已成為重要發展趨勢，在玻璃基板上於2009年首次製作出光電轉換效率3.8%的鈣鈦礦太陽能電池後，便在數十年間光電轉換效率即可達到25.7%，而鈣鈦礦太陽能電池的一大特性就是可以使用低溫製程，這使得可以製造於可撓性基板上，目前已達到22.4%的光電轉換效率。然而，這些高效率的元件都為小面積(＜0.1 cm2)，在朝往商業化模組開發的路上仍然有許多技術困難須克服，其中雷射雕刻的單片整合技術是關鍵環節之一。本實驗著重於研究在可撓性基板上，並通過旋塗法鍍膜，以雷射雕刻技術完成可撓性鈣鈦礦太陽能電池模組的製作。鈣鈦礦電池模組製作則是將電池以單片串聯模組的方式，藉由三條雷射切割線P1、P2和P3讓多顆電池互相串連。P1切割下電極用於定義單個子電池大小，P2讓上下電極能相互導通，最後P3切割上電極，重複此步驟完成電池串聯。我們使用波長為532 nm的奈秒脈衝雷射，在大氣環境下進行雷射雕刻，透過調整脈衝重疊率和雷射能量密度進行參數優化，探討P1切割線對後續鈣鈦礦電池鍍膜均勻性的影響，P2切割線所使用之雷射參數對接觸電阻的影響，以及P3切割線於上電極的效果。在提升鈣鈦礦電池的效率方面透過改變電洞傳輸層的方式，加入修飾層使得電壓與電流皆提升，在0.09 cm2的發電面積下讓玻璃與可撓性基板的鈣鈦礦電池效率從12.7%和7.9%提升至14.4%與10.8%，以此標準作為後續模組化製程的基礎。
最後，在2×2 cm2的玻璃基板與可撓性基板上，利用旋塗法的方式並串聯兩顆子電池形成模組，可做出有效發電面積1.0 cm2其光電轉換效率分別12.5%與10.1%的模組，填充因子都達到69.1%與60.1%，相比小面積的標準片只降低12%和6%，代表本實驗有效地以全雷射切割的方式完成模組，可應用於未來大面積塗佈法下使用相同雷射切割參數實現卷對卷或片對片的製程。 | zh_TW |
| dc.description.abstract | In the development of the third generation of solar cells, perovskite (PVSK) solar cells have become an important trend in research development. Since the first perovskite solar cell (PSC) was reported on the glass substrate in 2009, with a power conversion efficiency (PCE) of 3.81%, the power conversion efficiency (PCE) of perovskite solar cell (PSC) has increased to 25.7% in the last decade. The PSCs can be made at low-temperature processes, which means we can apply them on flexible substrates. The best PCE on flexible substrate is 22.4% so far. However, flexible perovskite solar cells (FPSCs) with high PCEs are all made in small areas (＜0.1 cm2) still difficulties to be overcome on the road toward commercialization, and monolithic integration is one of the key issues. In this study, we developed laser patterning technology based on a nanosecond pulsed laser to fabricate PVSK solar modules on the flexible substrate.
Perovskite solar modules are fabricated through a monolithic integration method, which is established by three scribing lines of P1, P2, and P3 by laser patterning method. P1 insulates the bottom electrode and defines the width of each sub-cell. P2 scribes absorber layer and allows top and back electrodes to connect and form a current flow path. P3 separates the top electrode, and finishes connection of sub‐cells in series. A nanosecond pulsed laser with a wavelength of 532 nm is used with the advantage of low cost compared with picosecond or femtosecond lasers. By adjusting the laser power density and pulse overlap ratio to optimize the scribing result, we investigated the effect of P1 scribing line on coating quality of PVSK layer and P2 scribing line on contact resistance between top and bottom electrodes. The wavelength of 532 nm is selected because of high absorption of PVSK layer and low absorption of TCO layer. To improve the PCE of PSCs, we add a modification layer on the hole transport layer. It shows that open circuit voltage and short circuit current are increased and the PCEs rise from 12.7% and 7.9% to 14.4% and 10.8% on the small area (0.09 cm2) glass substrate and flexible substrate, respectively. Therefore, we use these as control samples for comparison to subsequent module processes. Finally, a mini‐module with two sub-cells was fabricated on the 2×2 cm2 flexible substrate by a spin coating method. The module efficiency based on active area of 1.0 cm2 is 10.8% with the fill factor of 60.1% on flexible substrates. In conclusion, we have successfully demonstrated all laser patterning technology to fabricate flexible perovskite solar modules, and make possible the large-area and large‐scale flexible perovskite solar modules. | en |
| dc.description.provenance | Submitted by admin ntu (admin@lib.ntu.edu.tw) on 2023-05-10T16:05:03Z No. of bitstreams: 0 | en |
| dc.description.provenance | Made available in DSpace on 2023-05-10T16:05:03Z (GMT). No. of bitstreams: 0 | en |
| dc.description.tableofcontents | 口試委員審定書 i
誌謝 ii 摘要 iii Abstract iv 目錄 vi 圖目錄 x 表目錄 xviii 第一章 緒論 1 1.1 前言 1 1.2 鈣鈦礦太陽能電池介紹 5 1.2.1 鈣鈦礦太陽能電池的演進 5 1.2.2 鈣鈦礦材料結構 5 1.3 鈣鈦礦太陽能電池光電原理 7 1.4 鈣鈦礦太陽能電池元件結構 10 1.5 鈣鈦礦太陽能電池性質介紹 12 1.5.1 短路電流(Short Circuit Current, Jsc) 12 1.5.2 開路電壓(Open Circuit Voltage, Voc) 15 1.5.3 填充因子(Fill Factor, FF) 17 1.5.4 光電轉換效率(Photovoltaic Conversion Efficiency, PCE) 19 第二章 文獻回顧 20 2.1 可撓性鈣鈦礦太陽能電池介紹 20 2.1.1 可撓性鈣鈦礦太陽能電池基板與下電極的選擇 20 2.1.2 可撓性鈣鈦礦太陽能電池導電下電極 22 2.2 可撓性鈣鈦礦太陽能電池大面積製程介紹 27 2.3 可撓性鈣鈦礦太陽能電池模組性質介紹 29 2.3.1 串聯模組製程順序介紹 29 2.3.2 串聯模組設計介紹 31 2.3.3 模組雷射加工介紹 33 2.3.4 可撓性鈣鈦礦太陽能電池模組效率表現 35 2.4 研究動機 44 第三章 實驗流程與方法介紹 45 3.1 實驗方法 45 3.1.1 可撓性基板製備流程圖 45 3.1.2 可撓性鈣鈦礦電池模組製備流程圖 46 3.1.3 雷射製程開發流程圖 47 3.2 實驗用儀器列表 48 3.3 實驗雷射基台架設與介紹 50 3.3.1 脈衝雷射和光路設計 50 3.3.2 2D振鏡系統(2D Galvanometer Scanner) 53 3.3.3 精密微控定位走台 54 3.4 實驗用化學物質列表 55 3.5 實驗藥品製備方式 57 3.5.1 NiOx凝膠溶液(Sol‐gel) 57 3.5.2 PEDOT:PSS溶液 57 3.5.3 MeO-2PACz溶液 57 3.5.4 2PACz溶液 57 3.5.5 CH3NH3PbI3 鈣鈦礦前驅溶液 58 3.5.6 PC61BM溶液 58 3.5.7 PEI介面修飾層溶液 58 3.6 鈣鈦礦電池元件和模組製備流程 59 3.6.1 玻璃和柔性基材元件製程步驟 59 3.6.2 玻璃和柔性基材模組製程步驟 61 3.7 實驗分析設備介紹 62 3.7.1 積分球與光譜儀(Integrating & Sphere Spectrometer) 62 3.7.2 外部量子效率測量儀(External Quantum Efficiency, EQE) 63 3.7.3 掃描式電子顯微鏡(Scanning Electron Microscopy, SEM) 63 3.7.4 能量分散光譜儀(Energy Dispersive Spectroscopy, EDS) 64 3.7.5 膜厚分析儀(Surface Profiler) 64 3.7.6 太陽光模擬器(Solar Simulator) 65 3.8 模組實驗分析方法介紹 66 3.8.1 雷射參數定義與量測方法 66 3.8.2 波長532 nm奈秒脈衝雷射功率能量設定 71 3.8.3 傳輸線法分析(Transfer Line Method, TLM) 72 第四章 實驗結果與討論 73 4.1 硬質(玻璃)基板標準片與模組製作 73 4.1.1 小面積標準試片的製程方式 73 4.1.2 P1線雷射參數 77 4.1.3 兩電極間接觸電阻測量 81 4.1.4 P2線雷射參數 82 4.1.5 P3線雷射參數 86 4.1.6 玻璃基板模組之光電轉換效率表現 89 4.2 可撓性(PET)基板標準片與模組製作 92 4.2.1 小面積標準試片的製程對比 92 4.2.2 P1線雷射參數 99 4.2.3 P2線雷射參數 110 4.2.4 P3線雷射參數 118 4.2.5 可撓性基板模組之光電轉換效率表現 121 4.2.6 PET與玻璃基板對雷射切割影響比較 127 4.2.7 可撓性基板標準片與模組之彎曲測試 127 第五章 結論 131 第六章 建議與未來工作 133 參考文獻 134 | - |
| dc.language.iso | zh_TW | - |
| dc.subject | 奈秒脈衝雷射 | zh_TW |
| dc.subject | 可撓性鈣鈦礦太陽能電池 | zh_TW |
| dc.subject | 全雷射雕刻模組 | zh_TW |
| dc.subject | nanosecond pulse laser | en |
| dc.subject | all laser scribing | en |
| dc.subject | flexible perovskite solar module | en |
| dc.title | 奈秒脈衝雷射雕刻技術應用於可撓性鈣鈦礦太陽能電池模組的製造 | zh_TW |
| dc.title | Laser Patterning Technology Based on Nanosecond Pulsed Laser for Fabricating Flexible Perovskite Solar Modules | en |
| dc.type | Thesis | - |
| dc.date.schoolyear | 111-1 | - |
| dc.description.degree | 碩士 | - |
| dc.contributor.oralexamcommittee | 莊嘉揚;蔡豐羽 | zh_TW |
| dc.contributor.oralexamcommittee | Jia-Yang Juang;Feng-Yu Tsai | en |
| dc.subject.keyword | 可撓性鈣鈦礦太陽能電池,全雷射雕刻模組,奈秒脈衝雷射, | zh_TW |
| dc.subject.keyword | flexible perovskite solar module,all laser scribing,nanosecond pulse laser, | en |
| dc.relation.page | 141 | - |
| dc.identifier.doi | 10.6342/NTU202300227 | - |
| dc.rights.note | 同意授權(限校園內公開) | - |
| dc.date.accepted | 2023-02-10 | - |
| dc.contributor.author-college | 工學院 | - |
| dc.contributor.author-dept | 機械工程學系 | - |
| dc.date.embargo-lift | 2027-01-02 | - |
| 顯示於系所單位： | 機械工程學系 | |
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