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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/85426完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 康敦彥(Dun-Yen Kang) | |
| dc.contributor.author | Han-Lun Hung | en |
| dc.contributor.author | 洪漢倫 | zh_TW |
| dc.date.accessioned | 2023-03-19T23:16:28Z | - |
| dc.date.copyright | 2022-07-26 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-07-20 | |
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Sci. 2015, 490, 354-363. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/85426 | - |
| dc.description.abstract | 金屬有機骨架(Metal-organic frameworks, MOFs)因具有結構多樣性、化學功能性以及良好的吸附性質等特性，在薄膜分離領域被廣泛利用並具有高度發展潛力，尤其是在薄膜氣體分離與薄膜滲透蒸發等應用領域中。根據分子篩理論，具有氣體分離效能的MOF，其孔徑大小理想上將會介於兩種氣體的動態直徑之間，只要成功將其製備成為薄膜，便可有效對此氣體混合物進行分離。對於孔洞過大的MOF來說，其薄膜則難以對氣體混合物產生分子篩效應。本研究參考先前文獻，提出利用高分子嵌入MOF孔洞的方法來縮小其孔洞大小，盼利用此方法來提高薄膜氣體分離選擇性。在本論文研究中，我們選擇了名為Zn-BDC-TED的MOF(ZnMOF)材料來進行研究，其孔徑大小為0.75 nm。並將其製備為薄膜進行研究。接著我們使用分子量20,000 Da的聚乙二醇(PEG)摻入此ZnMOF薄膜，並利用傅立葉轉換紅外線光譜以及X光繞射技術來檢測PEG在ZnMOF中的分布情形。從臨場X光分析中，我們觀測到PEG在ZnMOF中吸、脫附的可逆變化。此外，我們得知PEG在ZnMOF不同軸向孔洞間的分布情形。透過薄膜氣體滲透的實驗，我們發現摻入PEG的ZnMOF薄膜具有良好的氫氣滲透率以及氫氣/二氧化碳選擇率。摻入PEG後選擇率從4提高到了18。 | zh_TW |
| dc.description.abstract | Metal-organic frameworks (MOFs) are promising materials for membrane gas separation due to their structural diversity, chemical functionality, and good adsorption properties. Base on the concept of size exclusion, an ideal MOF structure for membrane gas separation should possess an aperture size in between the dimensions of the two gas molecules to be separated. Therefore, MOFs with a pore size beyond the ultramicropore region (i.e. > 0.7 nm) is not ideal for for membrane gas separations. Herein we propose a method to narrow the pore size of MOFs via polymer insertion. Specifically, Zn-BDC-TED (ZnMOF) with a pore size of about 0.75 nm is investigated in this work. Polyethylene glycol (PEG) with molecular weight of 20,000 Da is inserted into ZnMOF membranes for the pore engineering. The resulting ZnMOF membranes with PEG were characterized via Fourier Transform Infrared Spectroscopy (FT-IR) and X-ray Diffractometer (XRD). The reversibility of PEG adsorption in ZnMOF was assessed by the in situ XRD analysis with a synchrotron X-ray source. The gas permeation results show that the insertion of PEG can effectively improve the gas separation performance of the ZnMOF membranes, especially for the mixture of H2/CO2. The optimized ZnMOF membrane achieves an ideal H2/CO2 selectivity of 18 with a high H2 permeability of about 3×105 barrer. | en |
| dc.description.provenance | Made available in DSpace on 2023-03-19T23:16:28Z (GMT). No. of bitstreams: 1 U0001-2007202212400500.pdf: 5641132 bytes, checksum: 27b0e84df99ce2088447f7d063d6d4f4 (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 口試委員審定書 i 致謝 ii 摘要 iii Abstract iv 目錄 v 圖目錄 vii 表目錄 x 第1 章 緒論及文獻回顧 1 1.1. 金屬有機骨架 1 1.2. 薄膜氫氣純化技術 2 1.3. 金屬有機骨架氣體分離膜 5 1.4. 金屬有機骨架薄膜於氫氣/二氧化碳分離之發展現況 7 1.5. 高分子嵌入金屬有機骨架孔洞的過往研究 9 1.6. 研究動機及架構 12 第2章 實驗方法 14 2.1. 合成Zn-BDC-TED之化學品 14 2.2. 合成Zn-BDC-TED粉體 14 2.3. Zn-BDC-TED薄膜生長 14 2.4. PEG嵌入Zn-BDC-TED薄膜之製備 16 2.6 Zn-BDC-TED樣品鑑定 17 2.7. 薄膜效能檢測及計算方法 19 第3章 高分子嵌入MOF之粉體及薄膜樣品鑑定與分析 22 3.1. ZnMOF粉體之合成與鑑定 22 3.2. 乙醇進入MOF孔洞中所造成之結構改變 23 3.3. 高分子嵌入MOF孔洞中所造成之結構改變 25 3.4. 高分子嵌入MOF孔洞中之晶面特徵峰強度變化 26 3.5. 高分子嵌入MOF薄膜之形貌與官能基鑑定 29 3.6. 高分子嵌入MOF薄膜之結構鑑定 33 第4章 金屬有機骨架薄膜效能測試及討論 35 4.1. 薄膜氣體滲透性質 35 4.2. 薄膜氣體分離選擇率 37 4-3. 薄膜之穩定性探討及測試 46 第5章 結論與未來展望 48 參考文獻 49 | |
| dc.language.iso | zh-TW | |
| dc.subject | 薄膜氣體分離 | zh_TW |
| dc.subject | 金屬有機骨架 | zh_TW |
| dc.subject | 金屬有機骨架薄膜 | zh_TW |
| dc.subject | Membrane gas separation | en |
| dc.subject | Metal-organic framework membrane | en |
| dc.subject | Metal-organic framework | en |
| dc.title | 利用嵌入高分子調控金屬有機骨架薄膜之孔洞特性與氣體分離效能 | zh_TW |
| dc.title | Pore Engineering of Metal-organic Frameworks via Polymer Insertion for Membrane Gas Separation | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 110-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林嘉和(Chia-Her Lin),羅世強(Shyh-Chyang Luo),林立強(Li-Chiang Lin) | |
| dc.subject.keyword | 金屬有機骨架,金屬有機骨架薄膜,薄膜氣體分離, | zh_TW |
| dc.subject.keyword | Metal-organic framework,Metal-organic framework membrane,Membrane gas separation, | en |
| dc.relation.page | 57 | |
| dc.identifier.doi | 10.6342/NTU202201571 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2022-07-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2022-07-26 | - |
| 顯示於系所單位： | 化學工程學系 | |
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