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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83912完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 廖英志(Ying-Chih Liao) | |
| dc.contributor.author | Ting-Yu Cheng | en |
| dc.contributor.author | 鄭庭宇 | zh_TW |
| dc.date.accessioned | 2023-03-19T21:23:14Z | - |
| dc.date.copyright | 2022-07-22 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-07-11 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83912 | - |
| dc.description.abstract | 近年來，3D列印技術受到相當多關注，由於3D列印技術無須事先生產模具，可簡化製造程序、降低製作成本、減少材料浪費，常被應用在客製化製造、快速建模、航太引擎生產、藝術品創作中。黏著劑噴塗型3D列印，Binder-jetting 3D printing (又稱粉末式3D列印，Powder-bed 3D printing)的特色在於列印時可使用自材支撐，不須另物設計支撐結構，因此可以列印較為複雜的結構。另外，此技術也是少數可以列印全彩物件的技術，透過將彩色墨水添加於黏著劑中，列印過程中便可以透過CMYK的組合來噴塗彩色的成品。黏著劑噴塗型3D列印之成品由於孔隙較大，因此其機械強度較低，通常需要經過耗時的後處理程序，將成品浸潤到樹脂內並利用光或熱進行固化才能得到足夠的強度。因此本文將發展新的列印程序來縮短以及簡化此技術的製作時間，同時得到高強度的成品。 本研究中，開發了兩種嶄新的列印系統，以縮短或免去傳統粉末式3D列印中耗時的後處理程序。在第2章中，本研究中使用澱粉之糊化特性，配合微波的均勻快速加熱，發展出嶄新且迅速的後處理程序。在第3章、第4章開發反應性印刷噴墨的粉末式3D列印技術。在第3章中，透過計算流體力學提出使多成分液體在粉末床中混合效果大幅上升的策略，而在第4章當中，利用粉末式3D印表機的多噴頭，同時噴塗多種反應性墨水於石膏粉末床中，使成型過程中同時進行交聯黏合，不需要後處理便能得到高強度物件。此外，噴塗的墨水也能使粉體進行進一步的功能化反應。 最後，在第5章當中總結了本研究的成果，並對黏著劑噴塗成型3D列印的創新黏合程序進行評估。未來可應用於快速成型、牙模與醫療材料的商業化製造。 | zh_TW |
| dc.description.abstract | In recent years, 3D printing technology has received considerable attention. 3D printing technology can skip the molding process and has the advantages of simpler manufacturing procedure, lower cost, and reducing material waste. It is often used in customized manufacturing, rapid modeling, aerospace engine production, and art creation. Binder jetting 3D printing (also known as powder-bed 3D printing) is one of the few technologies that can print full color objects. The binder-jetting 3D printing products have low mechanical strength due to their large porosity, and usually require the time-consuming post-treatment to soak the green product into the resin and cure it with light or heat. Therefore, this study develops novel methods to reduce the manufacturing time, to simplify the processes, and to obtain high strength objects. In this study, two novel printing systems were developed to shorten or eliminate the time-consuming post-processing process in traditional powder-based 3D printing. In Chapter 2, a new and rapid post-processing process is developed using the gelatinization characteristic of starch with uniform and rapid microwave heating. In Chapters 3 and 4, a reactive binder jetting 3D printing technology is developed. In Chapter 3, a strategy to increase the mixing effect of multi-component liquids in the powder bed is proposed by calculating fluid mechanics, and in Chapter 4, the multiple nozzles of the binder-jetting 3D printer are used to simultaneously spray multiple reactive inks into the gypsum powder bed, allowing cross-linking and bonding during the molding process, resulting in high-strength objects without post-processing. In addition, the sprayed inks also enable further functionalization of the powder. Finally, in chapter 5, we conclude and summarize the achievements of this research. The innovative binding process of powder-bed 3D printing is evaluated and can be applied to business development of rapid prototyping, dental and medical applications in the future. | en |
| dc.description.provenance | Made available in DSpace on 2023-03-19T21:23:14Z (GMT). No. of bitstreams: 1 U0001-0807202216081800.pdf: 9243174 bytes, checksum: 1324d9fd5995ee60f7f7167ef2aad34d (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 口試委員審定書 i 誌謝 ii 中文摘要 iv Abstract v 目錄 vii 圖目錄 x 表目錄 xvi 第1章 緒論 1 1.1 前言 1 1.2 3D列印技術 2 1.2.1 材料擠製成型(Material Extrusion) 2 1.2.2 光固化技術(Vat PhotoPolymerization) 3 1.2.3 粉體熔融成型技術(Powder Bed Fusion) 4 1.2.4 黏著劑噴塗成型(Binder Jetting) 5 1.2.5 材料噴塗成型(Material Jetting) 6 1.2.6 疊層製造成型(Laminated Object Manufacturing，LOM) 7 1.2.7 指向性能量沉積技術(Directed Energy Deposition，DED) 8 1.3 影響黏著劑噴塗成型列印品質之因素 9 1.3.1 粉末性質 9 1.3.2 黏著劑 21 1.3.3 列印參數設置 32 1.3.4 後處理程序 41 1.4 論文組織架構 44 第2章 澱粉粉末式3D列印之快速後處理程序 46 2.1 介紹 46 2.2 材料與實驗方法 48 2.3 結果與討論 49 2.3.1 粉末配方 49 2.3.2 微波加熱澱粉糊化 51 2.3.3 戊二醛交聯澱粉改質 57 2.3.4 噴塗戊二醛黏著劑 61 2.3.5 列印樣品演示 64 2.4 結論 66 第3章 利用親疏水性差異之顆粒交替排列增進雙成分液滴於粉末床中之混合 68 3.1 介紹 68 3.2 數值方法 70 3.2.1 參數與模型設置 70 3.2.2 統御方程式與邊界條件 72 3.2.3 數值驗證 74 3.3 結果與討論 77 3.3.1 液滴撞擊顆粒的混合機制與階段 77 3.3.2 墨水性質對於液滴混和的影響 82 3.3.3 顆粒的堆疊模式與親疏水性 86 3.3.4 液滴的偏移撞擊 90 3.4 結論 94 第4章 粉末式3D列印之反應性黏著劑增進強度與功能化之應用 95 4.1 介紹 95 4.2 材料與實驗方法 98 4.3 結果與討論 98 4.3.1 海藻酸鈉黏著劑噴塗性測試 98 4.3.2 海藻酸鈉交聯之物理性質與反應當量 100 4.3.3 正離子價數對模造試樣之性質影響 106 4.3.4 機台噴印樣品與耐水度測試 109 4.3.5 石膏粉末材料試樣的功能化 111 4.4 結論 113 第5章 總結 115 第6章 建議與未來展望 117 參考文獻 119 附錄 157 | |
| dc.language.iso | zh-TW | |
| dc.subject | 黏著劑噴塗型3D列印 | zh_TW |
| dc.subject | 澱粉糊化 | zh_TW |
| dc.subject | 粉體堆疊 | zh_TW |
| dc.subject | 液體混合 | zh_TW |
| dc.subject | 反應性液滴 | zh_TW |
| dc.subject | Binder jetting 3D printing | en |
| dc.subject | reactive inks | en |
| dc.subject | liquid mixing | en |
| dc.subject | powder stacking | en |
| dc.subject | starch gelatinization | en |
| dc.title | 粉末式3D列印之創新黏合程序 | zh_TW |
| dc.title | Innovative Binding Processes of Powder-bed 3D Printing | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 110-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 陳立仁(Li-Jen Chen),郭修伯(Hsiu-Po Kuo),鍾添東(Tien-Tung Chung),葛明德(Ming-Der Ger),陳建樺(Chien-Hua Chen) | |
| dc.subject.keyword | 黏著劑噴塗型3D列印,澱粉糊化,粉體堆疊,液體混合,反應性液滴, | zh_TW |
| dc.subject.keyword | Binder jetting 3D printing,starch gelatinization,powder stacking,liquid mixing,reactive inks, | en |
| dc.relation.page | 160 | |
| dc.identifier.doi | 10.6342/NTU202201353 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-07-11 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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| U0001-0807202216081800.pdf 未授權公開取用 | 9.03 MB | Adobe PDF |
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