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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83427完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭如忠(Ru-Jong Jeng) | |
| dc.contributor.author | Chien-Jung Wang | en |
| dc.contributor.author | 王千榕 | zh_TW |
| dc.date.accessioned | 2023-03-19T21:07:20Z | - |
| dc.date.copyright | 2022-10-19 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-09-16 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/83427 | - |
| dc.description.abstract | 聚醯亞胺（Polyimide, PI）由於具優異的熱、電氣和機械性質，被廣泛受到高科技領域的應用，為當今重要的工程塑膠之一。本研究利用二胺（Diamine）與二酸酐（Dianhydride），以二步法先經加成反應（Addition Reaction）聚合成聚醯胺酸高分子（Polyamic Acid, PAA），接著，利用不同種類的有機鹼（Organic Base）與羧基（Carboxyl Group）反應，藉由離子化的過程使其具親水性，形成水性聚醯胺酸高分子（Polyamic Acid Salt, PAAS），最後，再經高溫環化（Imidization）形成聚醯亞胺高分子。後續將其應用在碳纖維上漿製程中，以上漿步驟將碳纖維表面改質成含有PI之界面層，來增強與碳纖維和後續耐高溫樹脂（PPS、PA6、PEEK、PEAK）之結合性，並利用界面剪切強度（IFSS）檢測方法評估，結果顯示以本研究之PI改質之碳纖維與耐高溫樹脂（PPS、PA6）的介面性能增加 50% 左右。除此之外，利用穩定性加速測試儀（LUMiSizer）測試水性漿液的性質，結果顯示出本研究之水性聚醯胺酸漿料有良好的安定性。藉由傅立葉式紅外線光譜儀（Fourier Transform Infrared Spectrometer, FT-IR）、核磁共振儀（Nuclear Magnetic Resonance Spectrometer, NMR）、熱重損失分析儀（Thermogravimetric Analyzer, TGA）、示差掃描熱量分析儀（Differential Scanning Calorimeter, DSC）、動態光散射粒徑分析儀（Dynamic Light Scattering Particle Size Distribution, DLS）、界面電位分析儀（Zeta Potential Analyzer, Zeta）和酸鹼度計（pH Meter）來鑑定聚合物之結構、熱性質和乳液性質。綜上所述，本實驗成功地藉由使用離子化試劑進行簡單的處理，製備出貯存穩定性高的耐熱水性漿液，可以與多種高階工程塑膠匹配，而且，此聚醯胺酸水性上漿劑製備過程簡單、生產效率高，方便實現工業化的製備與應用。 | zh_TW |
| dc.description.abstract | Polyimide (PI) is widely used in high-technology fields owing to its excellent thermal, electrical, and mechanical properties and is one of the most important engineering plastics nowadays. In this study, polyamic acid (PAA) solution was synthesized based on diamine and dianhydride monomers via addition reaction. The water dispersible PAA was achieved by using ionization process to obtain polyamic acid salt (PAAS) with the addition of different organic bases. In order to improve the interface properties of carbon fiber composites, water dispersible PAA was utilized as a coating layer on the carbon fiber surface. After modification with PAA, the interfacial shear strength (IFSS) of carbon fiber composites was significantly increased. In conclusion, this research has successfully developed a water-dispersible slurry with high temperature resistance and storage stability via the ionization process, making it a potential industrial application prospect in improving the interface performance of carbon fiber composites. | en |
| dc.description.provenance | Made available in DSpace on 2023-03-19T21:07:20Z (GMT). No. of bitstreams: 1 U0001-1409202216181300.pdf: 4342567 bytes, checksum: ecce2af4039b58afbf1628a305311f54 (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 誌謝 ii 摘要 iii Abstract iv 目錄 v 圖目錄 vii 表目錄 x 第一章、緒論 1 第二章、文獻回顧 4 2.1 聚醯胺酸簡介 4 2.2 聚醯亞胺簡介 8 2.2.1 聚醯亞胺的性質與應用 8 2.2.2 聚醯亞胺的合成 10 2.2.2.1 縮合法（Condensation Reaction） 10 2.2.2.2 加成法（Addition Reaction） 14 2.2.2.3 改質法 15 2.3 提升溶解性之策略 16 2.4 碳纖維強化聚合體複材 26 2.5 研究動機 29 第三章、實驗內容 32 3.1 藥品及溶劑 32 3.2 實驗儀器 40 3.3 實驗流程圖 43 3.4 合成步驟 46 3.4.1 全芳香族水性聚醯胺酸漿料之製備 46 3.4.2 半芳香族水性聚醯胺酸漿料之製備 47 第四章、結果與討論 49 4.1 不同主鏈結構的聚醯胺酸之合成與性質探討 50 4.1.1 溶解度測試 51 4.1.2 熱性質分析 52 4.2 全芳香族聚醯胺酸之性質探討 55 4.2.1 當量比對乳液和熱性質的影響 55 4.2.1.1 乳液性質分析 55 4.2.1.2 熱性質分析 56 4.2.2 對離子對乳液和熱性質的影響 59 4.2.2.1 乳液性質分析 61 4.2.2.2 熱性質分析 63 4.3 碳纖維之上漿測試 66 4.3.1 乳液性質分析 66 4.3.2 熱性質分析 67 4.3.3 表面張力測試 68 4.3.4 表面結合力測試 69 第五章、結論與未來展望 71 第六章、參考文獻 72 | |
| dc.language.iso | zh-TW | |
| dc.subject | 複合材料界面剪切強度 | zh_TW |
| dc.subject | 離子化 | zh_TW |
| dc.subject | 水性聚醯胺酸 | zh_TW |
| dc.subject | 表面改質劑 | zh_TW |
| dc.subject | Waterborne polyamic acid | en |
| dc.subject | Sizing agent | en |
| dc.subject | Interfacial shear strength | en |
| dc.subject | Ionization | en |
| dc.title | 水性聚醯胺酸之製備與應用 | zh_TW |
| dc.title | A Study on Synthesis and Application of Waterborne Polyamic acid | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 110-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 童世煌(Shih-Huang Tung),邱文英(Wen-Yen Chiu),吳建欣(Chien-Hsin Wu),黃英治(Ying-Chi Huang) | |
| dc.subject.keyword | 離子化,水性聚醯胺酸,表面改質劑,複合材料界面剪切強度, | zh_TW |
| dc.subject.keyword | Ionization,Waterborne polyamic acid,Sizing agent,Interfacial shear strength, | en |
| dc.relation.page | 76 | |
| dc.identifier.doi | 10.6342/NTU202203405 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-09-19 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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