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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳林祈(Lin-Chi Chen) | |
| dc.contributor.author | Wei-Li Shih | en |
| dc.contributor.author | 史唯里 | zh_TW |
| dc.date.accessioned | 2021-05-20T00:51:39Z | - |
| dc.date.available | 2025-07-31 | |
| dc.date.available | 2021-05-20T00:51:39Z | - |
| dc.date.copyright | 2020-08-25 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-08-07 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/8301 | - |
| dc.description.abstract | 離子選擇微電極常與掃描式電化學顯微術合併使用，進行特定離子訊號的變化以及其於空間中分布的偵測。傳統的離子選擇微電極是採用玻璃製的micropipette來製作。玻璃製的micropipette相對較為脆弱並且需要特殊製程來製作。本研究藉由直接修飾微電極表面來製作固態接觸式鉀離子選擇微電極，並驗證其對於鉀離子通量監測的應用性。首先，本研究針對微電極表面的聚 (3,4-乙烯二氧噻吩) (PEDOT) 薄膜的修飾與調控進行探討，作為固態接觸式離子選擇微電極的基礎。本研究在白金微電極 (直徑10 µm) 上電鍍摻雜了過氯酸根離子的PEDOT薄膜，作為離子與電子訊號之間的轉換層。接著，對鉀離子具有選擇性響應薄膜被浸鍍到其上，作為擷取離子訊號的一層。此固態接觸式離子選擇微電極展現出近乎理論值 (59.1 mV/dec) 的靈敏度 (59.45 mV/dec) 並擁有10-5 M的偵測濃度下限。相對地，沒有PEDOT薄膜的鉀離子選擇微電極在只達到約70%的理論靈敏度 (41.39 mV/dec) 並只有10-4 M的偵測濃度下限。另外，本研究所製作的固態接觸式鉀離子選擇微電極的響應時間約為0.5秒，並且可以成功偵測到普魯士藍薄膜表面在多階段計時電流法以及循環伏安法下進行氧化還原反應時鉀離子吞吐的訊號。可見本研究所提出的固態接觸式離子選擇微電極將可實際作為掃描式電化學顯微術的探針使用，用以監測材料表面離子通量的訊號，也可以整合電化學石英微量天秤作為探討電化學材料表面離子進出機制的基本技術。 | zh_TW |
| dc.description.abstract | Ion-selective microelectrodes (ISMEs) are usually utilized to detect the variation and the spatial distribution of specific ions in corporation with the scanning electrochemical microscopy (SECM). Conventional ISMEs are made with glass micropipette. The glass micropipette is relatively fragile and some special fabrication procedures are needed. In this work, the solid-contact K+ ISMEs were made by directly modifying the microelectrode surface, and its application on the monitoring K+ flux by the them was verified. First, the modification and tuning of PEDOT thin film on the microelectrode was investigated, which is the basis of solid-contact K+ ISMEs. Next, the perchloride-doped poly(3,4-ethylenedioxythiophene) (PEDOT:ClO4) was electrodeposited on the platinum microelectrode (diameter = 10 µm) as the convertor for ion and electric signal. Next, a membrane with a selective response for K+ was dip-coated as a layer capturing the ion signal. The solid-contact ISME showed a sensitivity of 59.45 mV/dec, which was close to the theoretical value of 59.1 mV/dec, and had a detection limit of 10-5 M. However, the K+ ISMEs without PEDOT thin film showed a sensitivity of only 70% of the theoretical value (41.39 mV/dec) and had a detection limit of 10-4 M. The solid-contact K+ ISMEs has a response time of 0.5 seconds and successfully detected the surface K+ when a Prussian blue thin film conducts redox reaction under chronoamperometry and cyclic voltammetry operations. Thus, the solid-contact K+ ISMEs in this work can be utilized as the probe for SECM to monitor the ion flux on the material surface, or integrated with electrochemical quartz microbalance as the basic technique for investigation of ion flux. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-20T00:51:39Z (GMT). No. of bitstreams: 1 U0001-0708202012064100.pdf: 13172397 bytes, checksum: 402cebdd57d542e186b4a81758e12714 (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 致謝 i 摘要 ii Abstract iii 目錄 iv 圖目錄 v 表目錄 x 符號說明 xi 第一章 緒論 1 1.1 研究背景 1 1.2 研究動機 3 1.3 研究目的 5 1.4 研究架構 6 第二章 文獻探討 7 2.1 掃描式電化學顯微術的簡介 8 2.2 離子進出的監測技術的近年發展 9 2.3 離子選擇微電極的近年發展 11 2.3.1 離子選擇微電極的應用 12 2.3.2 鉀離子選擇微電極 14 2.4 聚 (3,4-乙烯二氧噻吩) 的結構與簡介 15 2.4.1 PEDOT的製程 16 2.4.2 PEDOT的優勢 18 2.5 固態接觸式離子選擇電極 19 2.5.1 離子選擇電極的發展 19 2.5.2 離子選擇電極的感測原理 21 2.5.3 離子電子傳導層的機制 23 2.5.4 離子選擇薄膜的構成 25 2.6 離子選擇電極的感測性能、優化策略與評價方法 26 2.6.1 電位再現性 27 2.6.2 電位穩定性 28 2.6.3 偵測極限 33 2.7 普魯士藍的氧化還原特性 34 第三章 材料與實驗方法 36 3.1 設備與材料 36 3.1.1 實驗設備 36 3.1.2 實驗材料 37 3.2 實驗儀器架設 38 3.2.1 電極夾具之設計 38 3.2.2 電極高度定位 40 3.2.3 電化學反應槽架設 41 3.3 離子選擇微電極製備 42 3.3.1 在白金微電極上進行PEDOT之電鍍 44 3.3.2 PEDOT傳導層的預處理以及鉀離子選擇薄膜的浸鍍與調整 45 3.4 電極修飾的確認 46 3.4.1 PEDOT 46 3.4.2 ISM 46 3.5 鉀離子選擇微電極性能測試 47 3.5.1 校正曲線 47 3.5.2 電位穩定性 48 3.5.3 電位飄移與電位躍遷 48 3.5.4 選擇性 49 3.5.5 響應時間之量測與估計 50 3.6 應用固態接觸式離子選擇微電極於掃描式電化學顯微術之實驗 51 3.6.1 普魯士藍表面鉀離子通量之初步監測實驗 51 3.6.2 普魯士藍表面鉀離子在循環伏安法下之離子通量監測實驗 54 第四章 結果與討論 55 4.1 微電極狀態與基本行為之檢測 55 4.1.1 微電極循環伏安法測試 55 4.1.2 微電極approach curve測試 56 4.2 調控PEDOT電鍍製程以控制電鍍面積與電鍍電量 58 4.2.1 PEDOT初步電鍍嘗試 58 4.2.2 微電極上PEDOT薄膜之調控以及離子選擇微電極製備成果 64 4.2.3 離子選擇微電極之製備流程小結 75 4.3 離子選擇微電極的量測性能之測試與比較 78 4.3.1 有無離子電子傳導層的離子選擇微電極的檢量線之比較 78 4.3.2 有無離子電子傳導層的離子選擇微電極的電位穩定性比較 80 4.3.3 離子選擇微電極之選擇性測量與比較 84 4.3.4 micropipette 與固態接觸式離子選擇微電極感測性能比較 85 4.3.5 固態接觸式離子選擇微電極之響應時間測量 87 4.4 普魯士藍之鉀離子通量即時監測實驗 88 4.4.1 待掃描基材之普魯士藍製備與測試 88 4.4.2 普魯士藍表面鉀離子通量之初步監測實驗的訊號確認 90 4.4.3 普魯士藍表面鉀離子通量之初步監測實驗的訊號量化分析 94 4.4.4 循環伏安法下普魯士藍表面鉀離子通量之即時監測實驗 104 第五章 5.1 結論與建議 109 結論 109 建議 110 5.2 參考文獻 111 附錄 115 附錄一 離子選擇微電極對量測系統振動的抵抗能力 115 附錄二 定電流模式下的離子選擇微電極量測 117 附錄三 裸微電極以普魯士藍為基材的高度定位嘗試 119 | |
| dc.language.iso | zh-TW | |
| dc.title | 基於聚乙烯二氧噻吩固態接觸式鉀離子選擇微電極之製備 | zh_TW |
| dc.title | On the Fabrication of a PEDOT-based Solid-contact Potassium Ion-Selective Microelectrode | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 林正嵐(Cheng-Lan Lin) | |
| dc.contributor.oralexamcommittee | 何國川(Kuo-Chuan Ho),陳力騏(Li-Ci Chen) | |
| dc.subject.keyword | 掃描式電化學顯微術,離子選擇微電極,聚 (3,4-乙烯二氧噻吩),普普士藍,離子通量, | zh_TW |
| dc.subject.keyword | scanning electrochemical microscopy (SECM),ion-selective microelectrode (ISME),poly(3,4-ethylenedioxythiophene) (PEDOT),Prussian Blue,ion flux, | en |
| dc.relation.page | 120 | |
| dc.identifier.doi | 10.6342/NTU202002614 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2020-08-10 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物機電工程學系 | zh_TW |
| dc.date.embargo-lift | 2025-07-31 | - |
| 顯示於系所單位： | 生物機電工程學系 | |
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