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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 徐振哲(Cheng-Che Hsu) | |
| dc.contributor.author | Wei-Cheng Yen | en |
| dc.contributor.author | 顏偉丞 | zh_TW |
| dc.date.accessioned | 2022-11-25T07:29:06Z | - |
| dc.date.available | 2023-08-09 | |
| dc.date.copyright | 2021-11-09 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-09 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82313 | - |
| dc.description.abstract | 微電漿是任一維度在毫米尺度以下的電漿系統，常壓下的微電漿具不需真空設備、體積小、低耗能、高反應性、常溫下運作等優點，微電漿種類眾多，本文所使用的自製微電漿裝置屬於介電質微電漿系統，介電質微電漿於分析化學的應用廣泛，在質譜儀、樣品分解、放光光譜等領域都有它的蹤跡，然而，在其中的放光光譜領域，鮮少有團隊發展在空氣環境中檢測揮發性有機物的技術，其其挑戰有二，一是空氣電漿中氧氣會和有機物反應生成水氣、二氧化碳等較為安定的物種，減少產生有機物特徵放光的來源；二是大氣電漿的放光光譜被氮氣所主宰，與揮發性有機物相關的訊號可能因此被屏蔽於氮氣的放光底下而無法被觀測到。本研究透過適當調控電漿行為成功在大氣環境下測得揮發性有機物的訊號並將偵測極限自104 ppm等級推進到102 ppm等級，從微電漿裝置消耗功率的量測結果提出CN特徵放光訊號與消耗功率之間的關聯和趨勢，接著探討本研究自製的微電漿裝置在連續多個週期的放電行為與浮動電極的設計。 為了暫時排除複雜有機物含有多種官能基與元素的影響，於實際應用層面的測試，本研究使用乙醇做為被感測的揮發性有機物，藉由實驗設計說明本感測系統在空氣環境中的檢測能力與穩定性，此外，從回歸的結果得知本系統在200 ~ 3000 ppm具有良好的線性響應。氣體感測器的最終目標是能達到即時即地的監測目標環境，本研究使用自行組裝的升壓模組取代體積龐大的放大器，能夠於空氣環境下穩定的感測到3000 ppm的乙醇蒸氣。 未來本系統除了可以往更低濃度的偵測極限努力外，尚可以往探討空氣中水氣含量對於放光光譜的影響以及在檢測的揮發性有機物中添加干擾物，讓實驗室中模擬的感測環境更合乎現實的需求。 | zh_TW |
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| dc.description.tableofcontents | 致謝 i 中文摘要 iii ABSTRACT iv 目錄 v 圖目錄 viii 表目錄 xiii 第 1 章 緒論 1 1.1 前言 1 1.2 研究動機與目標 2 1.3 論文總覽 2 第 2 章 文獻回顧 3 2.1 電漿簡介 3 2.1.1 電漿產生機制與反應 3 2.1.2 崩潰電壓與帕刑定律 5 2.1.3 低壓與常壓電漿系統 6 2.2 微電漿系統 8 2.2.1 微電漿系統簡介 8 2.2.2 微電漿系統種類 10 2.2.3 微電漿系統應用 14 2.2.4 電漿放光光譜 16 2.3 常見氣體檢測技術 18 2.3.1 常見氣體檢測裝置及原理 18 2.3.2 常壓電漿有機物放射光譜 23 2.4 介電質微電漿裝置及其應用 28 2.4.1 介電質微電漿裝置 28 2.4.2 介電質微電漿應用 30 第 3 章 實驗設備與架構 33 3.1 大氣微電漿揮發性有機物感測系統 33 3.1.1 可撓式微電漿裝置製備 33 3.1.2 微電漿裝置：浮動電極設計 35 3.1.3 微電漿裝置驅動電源 38 3.1.4 揮發性有機物感測系統 40 3.2 電漿檢測方法 42 3.2.1 電性檢測 42 3.2.2 光學檢測 45 3.2.3 電漿模擬軟體 46 第 4 章 實驗結果與討論 47 4.1 空氣環境揮發性有機物光譜特性分析 47 4.1.1 基本參數 47 4.1.2 浮動電極設計 50 4.1.3 電漿放射光譜 54 4.1.4 揮發性有機物光譜 56 4.1.5 電漿電性檢測 61 4.2 自製微電漿裝置揮發性有機物感測表現 64 4.2.1 升壓模組感測表現 64 4.2.2 放大器感測表現 69 第 5 章 結論與未來展望 75 第 6 章 參考文獻 77 第 7 章 附錄 83 7.1 自製微電漿產生裝置穩定性研究 83 7.2 交流電脈衝 86 | |
| dc.language.iso | zh-TW | |
| dc.title | 以微電漿產生裝置結合放射光譜偵測空氣中揮發性有機物之研究 | zh_TW |
| dc.title | Detection of Volatile Organic Compounds in Air by Microplasma Generation Device Using Optical Emission Spectroscopy | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李明蒼(Hsin-Tsai Liu),盧彥文(Chih-Yang Tseng),陳嘉晉 | |
| dc.subject.keyword | 微電漿,分子放光光譜,揮發性有機物,空氣氣氛, | zh_TW |
| dc.subject.keyword | microplasma,molecular emission spectrum,volatile organic compound,air environment, | en |
| dc.relation.page | 89 | |
| dc.identifier.doi | 10.6342/NTU202102106 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-08-11 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-08-09 | - |
| 顯示於系所單位： | 化學工程學系 | |
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