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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82092完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳乃立(Nae-Lih Wu) | |
| dc.contributor.author | Chi-Che Tsai | en |
| dc.contributor.author | 蔡其哲 | zh_TW |
| dc.date.accessioned | 2022-11-25T05:35:41Z | - |
| dc.date.available | 2025-02-15 | |
| dc.date.copyright | 2022-02-18 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-02-14 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82092 | - |
| dc.description.abstract | 鋰離子電池的發展至今已趨向成熟，然而電池自燃意外卻頻繁發生，為了使儲能裝置有更好的安全性，開發新型固態電解質是其中的關鍵。固態電解質對於液態電解質來說，有更好的電化學窗口、電化學穩定性、更高能量密度及不會有固態電解質界面膜產生之優點，然而固態材料本身之剛性導致與電極介面接觸之問題是使用上主要障礙。 於本研究中，新型鹵化物固態電解質合成是首先要達成的目標。對比氧化物固態電解質合成之鍛燒溫度動輒700℃以上高溫及硫化物固態電解質合成過程之硫化氫氣體排放問題，新型鹵化物鍛燒溫度只需200℃並且製程乾淨無污染排放，因此可做為新一代可商業化之固態電解質材料。在合成材料的過程中我們發現，此鹵化物具有高吸水性及機械強度較弱等問題，因此希望以添加高分子來進行改善，並增進鋰離子之傳導度。 首先，我們嘗試高分子材料-聚偏二氟乙烯(PVDF)-及水性高分子與新型鹵化物材料結合打造新型的固態電解質複合材料，然而鹵化物在這些高分子內結晶問題導致開發失敗，但發現之問題亦提供新材料選擇的方向，最終以具有熱可塑性之高分子polyethylene (PE) 及polyurethane (PU) 開發出新型固態電解質複合材料以及固態正極複合材料，進行電化學性能相關之測試，並發現相關問題進行分析。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T05:35:41Z (GMT). No. of bitstreams: 1 U0001-1002202213250300.pdf: 11526739 bytes, checksum: d92fed0b095cea7632127eab0327bf27 (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 致謝 I 中文摘要 III ABSTRACT IV List of Tables XI List of Figures XIII Introduction 1 1.1 Background 1 1.2 Motivations and Objetives 3 Chapter 2 Literature review 5 2.1 Rechargeable batteries 5 2.1.1 Introduction for rechargeable batteries 5 2.1.2 Introduction for liquid type electrolyte 8 2.2 Introduction for solid state electrolyte 11 2.2.1 NACICON-type electrolytes 13 2.2.2 Garnet-type electrolytes 14 2.2.3 Perovskite-type electrolytes 15 2.2.4 Polymer solid state electrolyte 17 2.3 Introduction to halide solid state electrolytes 18 2.3.1 Introduction to Li3InCl6 [41] 19 2.3.2 Ball-milling and annealing Li3InCl6 [42] 25 2.4 Introduction to polyethylene (PE) and polyurethane (PU) 30 Chapter 3 Experimental 32 3.1 Materials and Chemicals 32 3.2 Synthesis of Materials 33 3.2.1 Preparation of Li3InCl6 33 3.2.2 Water trap device of Li3InCl6 34 3.2.3 Preparation of Li3InCl6 and Polyvinylidene (PVDF) composite solid state electrolyte 34 3.2.4 Preparation of Li3InCl6 and Styrene Butadiene Rubber composite solid state electrolyte film 35 3.2.5 Preparation of Li3InCl6 and Poly(acrylic) elastomers rubber composite solid state electrolyte film 36 3.2.6 Preparation of low Li3InCl6 content with polyethylene composite solid state electrolyte film 37 3.2.7 Polymer particle coating on Li3InCl6 for high ceramic content composite solid state electrolyte film 38 3.2.8 Preparation of low solid content composite cathode film with Li3InCl6 39 3.2.9 Preparation of high solid content composite cathode film with Li3InCl6 40 3.2.10 Preparation of thin PEO type solid state electrolyte 41 3.2.11 Preparation of indium and lithium alloy 41 3.3 Material Characterizations and Analysis 42 3.3.1 Scanning Electron Microscopy 42 3.3.2 Thermal Analysis 43 3.3.3 X-ray Diffraction 43 3.3.4 Tensile Testing 44 3.3.5 Contact Angle Measurement 45 3.3.6 Powder Electrical Conductivity Measurement 46 3.4 Electrochemical Characterizations 47 3.4.1 Assembling Coin Cells 47 3.4.2 Charge/Discharge Test 48 3.4.3 Electrochemical Impedance Spectroscopy 48 Chapter 4 Water mediated halide solid state electrolyte synthesizing 51 4.1 Introduction 51 4.2 Over dose synthesis of Li3InCl6 52 4.2.1 Materials Characterization 52 4.2.2 Electrochemical Performance 53 4.3 Humidity resistance test for Li3InCl6 55 4.3.1 Materials Characterization 55 4.3.2 Eletrochemical Performance 57 4.4 Improved process for Li3InCl6 59 4.4.1 Introduction 59 4.4.2 Materials Characterization 60 4.4.3 Electrochemical Performance 61 4.5 Pressure impact for Li3InCl6 63 4.5.1 Electrochemical Performance 63 Chapter 5 Polyvinylidene Fluoride (PVDF) and Li3InCl6 composite solid state electrolyte 64 5.1 Introduction 64 5.2 Best composition for PVDF and Li3InCl6 composite material and making method 65 5.2.1 Electrochemical performance 65 5.2.2 Materials Characterization 67 5.3 Materials Characterization 74 Chapter 6 Li3InCl6 and Emulsion rubber composite solid state electrolyte 76 6.1 Introduction 76 6.2 E-SBR with Li3InCl6 composite solid state electrolyte 77 6.2.1 Materials Characterization 77 6.2.2 Electrochemical performance 83 6.2.3 Electrochemical performance after polishing by sandpaper 85 6.3 E-ACM with Li3InCl6 composite solid state electrolyte 88 6.3.1 Materials Characterization 88 6.3.2 Electrochemical performance 93 Chapter 7 Li3InCl6 and PE made hot melting composite solid state electrolyte 95 7.1 Introduction 95 7.2 High PE component composite films with Li3InCl6 96 7.2.1 Materials Characterization for hot melting gel 96 7.2.2 Materials Characterization for high PE component films 101 7.2.3 Electrochemical Performance 105 7.3 Optimization of PE and Li3InCl6 films 107 7.3.1 Material Characterization 107 7.3.2 Electrochemical performance 117 Chapter 8 Hot melting Cathode material with Li3InCl6 coated films 126 8.1 Introduction 126 8.2 Li3InCl6 coating on LFP composite cathode materials 127 8.2.1 Materials Characterization 127 8.2.2 Electrochemical performance 128 8.3 Composite cathode materials with hot melting gel films 130 8.3.1 Materials Characterization 130 8.3.2 Electrochemical performance 136 Chapter 9 All solid state cells with hot melting cathode and solid state electrolyte 148 9.1 Materials Characterization and electrochemical performance 148 Chapter 10 Conclusion and outlook 152 Reference 153 | |
| dc.language.iso | en | |
| dc.subject | 熱可塑性高分子 | zh_TW |
| dc.subject | 鹵化物 | zh_TW |
| dc.subject | 離子導電度 | zh_TW |
| dc.subject | 開發 | zh_TW |
| dc.subject | 固態電解質 | zh_TW |
| dc.subject | development | en |
| dc.subject | Soild state electrolyte | en |
| dc.subject | hot melting gel | en |
| dc.subject | ionic conductivity | en |
| dc.subject | halide | en |
| dc.title | 鹵化物固態電解質與熱塑性高分子複合材料之開發 | zh_TW |
| dc.title | Development of halide solid state electrolyte with thermoplastic polymer composite material | en |
| dc.date.schoolyear | 110-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 翁郁婷,方家振 | |
| dc.subject.keyword | 固態電解質,熱可塑性高分子,離子導電度,鹵化物,開發, | zh_TW |
| dc.subject.keyword | Soild state electrolyte,hot melting gel,ionic conductivity,halide,development, | en |
| dc.relation.page | 157 | |
| dc.identifier.doi | 10.6342/NTU202200521 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2022-02-14 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2025-02-15 | - |
| 顯示於系所單位： | 化學工程學系 | |
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| U0001-1002202213250300.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 11.26 MB | Adobe PDF |
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