請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82039完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 牟中原(Chung-Yuan Mou) | |
| dc.contributor.author | Chiao-Chun Chang | en |
| dc.contributor.author | 張巧君 | zh_TW |
| dc.date.accessioned | 2022-11-25T05:34:34Z | - |
| dc.date.available | 2023-08-31 | |
| dc.date.copyright | 2021-11-17 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-18 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/82039 | - |
| dc.description.abstract | "無陽極鋰金屬電池(Anode Free Lithium Metal Battery, AFLMB)具有潛力成為下一代的電池系統；其組裝時不添加過量的鋰金屬，利用有限的鋰金屬離子進行充放電，AFLMB不僅提升能量密度、降低成本還能增加安全性。然而鋰金屬在陽極端電鍍與剝除的過程中，高活性的枝晶狀鋰金屬的形成容易與電解液發生不可逆反應並產生氣體，造成鋰金屬的損耗，使得AFLMB面臨庫倫效率衰退快速的問題。1因此開發線上氣相層析系統分析反應過程的氣體能進一步提供電池反應中的關鍵訊息。 在本研究工作中，將具有規則孔洞的中孔洞矽薄膜 (Mesoporous Silica Thin Film, MSTF) 修飾於不鏽鋼集流板上作為AFLMB的陽極，使鋰金屬電鍍於陽極表面的形貌更加平整，避免枝晶狀鋰金屬的生成。在醚類電解液系統中，透過MSTF修飾的負極應用在AFLMB，電池庫倫效率有20% 的提升，及負極上的電鍍鋰金屬形貌平整圓潤。2為了進一步提高AFLMB的能量密度，我們將具有更高比電容的三元鋰金屬氧化物 (NMC) 正極材料與MSTF修飾的負極組裝，在具有更高操作電壓的碳酸酯類電解液中進行效能測試。由於鋰金屬先天在碳酸酯類電解液中的電鍍/剝除行為可逆性較差，在碳酸酯類電解液中MSTF薄膜無法透過調節鋰金屬的電鍍形貌來改善AFLMB的充放電循環的表現。由於AFLMB在碳酸酯類溶液中的充放電循環表現較差，我們進一步將富含鋰的層狀鋰金屬氧化物正極材料組裝於AFLMB中，此正極材料能夠在第一圈充電過程中提供多餘鋰金屬，儲存於在負極材料上形成，提供多餘的鋰存量彌補鋰金屬於反覆電鍍剝除過程中所消耗的鋰金屬，藉此提升AFLMB充放電循環的表現。 為了近一步了解鋰金屬電鍍形貌及電解液分解之間的關係，在研究過程中，同時利用掃描式電子顯微鏡及線上氣體分析技術觀察鋰金屬形貌的變化並了解不同形貌之鋰金屬與電解液之間的分解反應活性。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T05:34:34Z (GMT). No. of bitstreams: 1 U0001-0807202120405300.pdf: 16334711 bytes, checksum: 6cebe55a187f3d0226f7c5ae8b6cc3b7 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員審定書 i 謝誌 ii 摘要 iii Abstract iv Table of Contents vi List of Figures ix List of Tables xiv List of Schemes xv Abbreviation xvi Chapter 1 Introduction 1 1.1 Background 1 1.2 Electrodes of Li-ion battery 4 1.2.1 Cathode materials 5 1.2.2 Anode materials 9 1.3 The concept of Anode-free lithium metal battery 11 1.3.1 Optimization of the Electrolyte 12 1.3.2 Modification of current collector 14 1.4 Electrolyte decomposition 16 1.5 Motivation 18 Chapter 2 Material and Methods 19 2.1 Chemical 19 2.2 Instruments 21 2.2.1 Scanning electron microscopy (SEM) 21 2.2.2 Nitrogen adsorption-desorption isotherm 21 2.2.3 Cyclic voltammetry (CV) 22 2.2.4 Galvanostatic charge/discharge measurements 22 2.2.5 Grazing incidence X-ray scattering 23 2.2.6 On-line gas chromatography (on-line GC) 25 2.3 Synthetic procedures 28 2.3.1 Synthesis of pore-expanded mesoporous silica nanoparticles (ex-MSNs) 28 2.3.2 Synthesis of mesoporous silica thin films (MSTFs) on stainless steel 29 2.4 Battery preparation 30 2.4.1 Cathode electrode preparation 30 2.4.2 Conventional electrolyte preparation 31 2.4.3 CR2032 coin cell 31 2.4.4 GIWAXS sample preparation 33 2.4.5 Gas analysis battery cell assembly 34 2.5 On-line gas analysis system 35 Chapter 3 Gas Evolution Behaviors of MSTF Modified Anode on AFLMB 37 3.1 Characterization of MSTF on stainless steel 37 3.1.1 Scanning electron microscopy 37 3.1.2 Nitrogen adsorption-desorption isotherm 39 3.1.3 Grazing incidence small-angle X-ray scattering 40 3.2 LFP cathode of AFLMB 42 3.2.1 Battery performance 42 3.2.2 Li deposition morphology on anode 46 3.2.3 Gas evolution during charge/discharge process 48 3.3 Li(Ni1-x-yCoxMny)O2 cathode of AFLMB 54 3.3.1 Carbonate-based electrolyte 55 3.3.2 NMC532 cathode of AFLMB 57 3.3.3 NMC811 cathode of AFLMB 69 3.3.4 MSTF structure after cycling 77 3.4 Li-rich cathode of AFLMB 80 3.4.1 Battery performance 81 3.4.2 MSTF modified anode 85 3.4.3 Li deposition behavior during cycling 91 3.5 Comparison of different cathode in AFLMB 97 3.5.1 Cyclic voltammogram and battery performance 97 3.5.2 Li deposition morphology on anode 100 3.5.3 Gas evolution during charge/discharge process 101 Chapter 4 Conclusion 103 Reference 105 | |
| dc.language.iso | en | |
| dc.subject | 富鋰金屬氧化物 | zh_TW |
| dc.subject | 無陽極鋰金屬電池 | zh_TW |
| dc.subject | 中孔洞矽薄膜 | zh_TW |
| dc.subject | 線上層析氣體分析 | zh_TW |
| dc.subject | anode-free Li metal battery | en |
| dc.subject | mesoporous silica thin film | en |
| dc.subject | on-line gas chromatography | en |
| dc.subject | Li-rich cathodes | en |
| dc.title | 利用線上層析系統分析中孔洞矽薄膜修飾之無陽極鋰金屬電池 | zh_TW |
| dc.title | On-line Gas Chromatography Studies of Mesoporous Silica Thin Film Modified Anode Free Li-Metal Battery | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.author-orcid | 0000-0002-9817-4628 | |
| dc.contributor.oralexamcommittee | 吳恆良(Hsin-Tsai Liu),黃炳照(Chih-Yang Tseng) | |
| dc.subject.keyword | 無陽極鋰金屬電池,中孔洞矽薄膜,線上層析氣體分析,富鋰金屬氧化物, | zh_TW |
| dc.subject.keyword | anode-free Li metal battery,mesoporous silica thin film,on-line gas chromatography,Li-rich cathodes, | en |
| dc.relation.page | 112 | |
| dc.identifier.doi | 10.6342/NTU202101354 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-08-19 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-08-31 | - |
| 顯示於系所單位： | 化學系 | |
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