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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張慕傑(Mu-Chieh Chang) | |
| dc.contributor.author | Chia-Hung Lin | en |
| dc.contributor.author | 林家弘 | zh_TW |
| dc.date.accessioned | 2022-11-25T03:07:08Z | - |
| dc.date.available | 2023-09-01 | |
| dc.date.copyright | 2021-11-12 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-31 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81943 | - |
| dc.description.abstract | " 在工業上，常用來達到經濟效益的方法是透過催化反應，對低成本的小分子進行活化應用。其中，將地球豐富的二氧化碳轉化為具有附加價值的化學物質就是一個實際例子。此外，氫氣的活化在哈伯法製氨中扮演著重要的角色。然而，地球豐富的卑金屬如鈷，並不容易對這類多質子或多電子的反應有良好的反應性。為了提高由卑金屬合成的催化劑，對多質子或多電子反應的活性，我們將金屬−配位基協同作用和金屬−金屬協同作用引入到我們的多功能鈷催化劑。根據文獻資料，這種在單一催化劑中使用多個功能的策略，可以有效穩定催化過程產生的中間體，進而提供卑金屬催化劑進行多質子和多電子轉移的能力。 在本篇論文中，我們首先完成了配位基H2L的合成與鑑定，接著再利用去質子化的配位基和CoX2 (X = Cl, Br, I)等鹽類起始物進行反應，合成混合價數的三鈷錯合物10-12。我們利用各種鑑定方式去了解10-12在固態和溶液狀態下的結構，以及他們的電子和電化學性質。我們發現可以使用錯合物12，催化二氧化碳與環氧丙烷的環加成反應，在常溫常壓的條件下以中等產率生成碳酸丙烯酯。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T03:07:08Z (GMT). No. of bitstreams: 1 U0001-3008202121140200.pdf: 18893596 bytes, checksum: 393e8514abebb07232b85c0310ebb034 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | "致謝 i 摘要 iii Abstract iv Contents v List of Figures viii List of Schemes xiv List of Tables xviii Chapter 1 Introduction 1 1.1 Based Metal Homogeneous Catalyst 1 1.2 Metal-Ligand Cooperation 3 1.2.1 Redox-Active Ligand 5 1.2.2 Pendant Proton Relay 13 1.3 Metal-Metal Cooperation 16 1.4 Motivation of Multifunctional Catalysts Designed 20 Chapter 2 Results and Discussions 27 2.1 Ligand Synthesis, Characterization and Reaction 27 2.1.1 Ligand Synthesis and Characterization 27 2.1.2 Deprotonation Tests of the Ligand 36 2.1.3 Electrochemical Properties of Ligand 42 2.1.4 H-Atom Abstraction Test of Ligand 44 2.2 Synthesis, Characterization and Application of Tricobalt Complexes 47 2.2.1 Synthesis and Structure Characterization of Complexes 47 2.2.2 Electronic Structure of Tricobalt Complexes 65 2.2.3 Electrochemical Properties of Tricobalt Complexes 68 2.2.4 Catalytic Cycloaddition of CO2 with Epoxypropane 75 Chapter 3 Conclusion and Future Work 79 Chapter 4 Experimental Section 81 General Information 81 Physical Measurement 82 Preparation 85 2,3-Dihydrophthalazine-1,4-dione (2) 85 1,4-Dichlorophthalazine (3) 86 1,1'-(Phthalazine-1,4-diyl)bis(ethan-1-one) (8) from 1,4-dichlorophthalazine (3) 88 1,4-Dihydrazineylphthalazine (6) 90 Phthalazine (7) 91 1,1'-(Phthalazine-1,4-diyl)bis(ethan-1-one) (8) from Phthalazine (7) 93 1,4-Bis((Z)-1-(2-phenylhydrazineylidene)ethyl)phthalazine (H2L) 95 [(HL)3CoII,III2X][CoIIX3(THF)] (X = Cl: 10; X = Br: 11; X = I: 12) 97 Purification Process after Catalytic Cycloaddition of CO2 with Epoxypropane 100 Reference 101 Appendix 135" | |
| dc.language.iso | en | |
| dc.subject | 多功能三鈷錯合物 | zh_TW |
| dc.subject | ligand-based reduction | zh_TW |
| dc.subject | 金屬−金屬協同作用 | zh_TW |
| dc.subject | 金屬−配位基協同作用 | zh_TW |
| dc.subject | 二氧化碳環化加成 | zh_TW |
| dc.subject | ligand-based reduction | en |
| dc.subject | cycloaddition of CO2 | en |
| dc.subject | multifunctional tricobalt complex | en |
| dc.subject | metal-metal cooperation | en |
| dc.subject | metal-ligand cooperation | en |
| dc.title | 混合價數多功能三鈷錯合物的合成、鑑定與應用 | zh_TW |
| dc.title | "Synthesis, Characterization and Application of Mix-Valence Multifunctional Tricobalt Complexes" | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 劉學儒(Hsin-Tsai Liu),林峻毅(Chih-Yang Tseng) | |
| dc.subject.keyword | 金屬−配位基協同作用,金屬−金屬協同作用,多功能三鈷錯合物,ligand-based reduction,二氧化碳環化加成, | zh_TW |
| dc.subject.keyword | metal-ligand cooperation,metal-metal cooperation,multifunctional tricobalt complex,ligand-based reduction,cycloaddition of CO2, | en |
| dc.relation.page | 196 | |
| dc.identifier.doi | 10.6342/NTU202102863 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-08-31 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-09-01 | - |
| 顯示於系所單位： | 化學系 | |
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| U0001-3008202121140200.pdf | 18.45 MB | Adobe PDF | 檢視/開啟 |
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