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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81832完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 梁文傑(Man-kit Leung) | |
| dc.contributor.author | Chun-Han Hsieh | en |
| dc.contributor.author | 謝鈞瀚 | zh_TW |
| dc.date.accessioned | 2022-11-25T03:04:37Z | - |
| dc.date.available | 2026-10-25 | |
| dc.date.copyright | 2021-11-02 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-10-27 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81832 | - |
| dc.description.abstract | "藉由等電子體的概念，我們將硼、氮原子引入吲哚結構，硼原子的低電負度特性去調整有機分子的電性質，並整合成10個π電子共軛系統的1,3,2-苯並二氮雜硼分子，並將其作為研究之主架構。硼原子的空pz軌域同時可做為陰離子的受體，因此可產生化合物螢光性質的改變。因此，我們在主架構中不同的位置上引入有高量子產率、具TTA-UC特性的藍光基團10-苯蒽，以利運用於藍光材料中，並同時探討其和離子間的反應與變化，運用於離子辨識材料上。 透過光物理分析，可知這系列化合物之螢光落在藍光至藍綠光範圍；在熱性質分析中，所合成之化合物的熱裂解溫度皆高於元件蒸鍍所需溫度 (200 ℃)，且玻璃轉移溫度皆高於110 ℃，符合元件所需的熱性質要求。本系列化合物皆可於以Pd(OEP)作為敏料的Xylene溶液中，以低能量的綠光激發並產生高能量的藍光，而此現象可以和光物理分析圖譜的結果相呼應。 於元件表現部分，我們將五個化合物作為主發光層之非摻混材料，其中以材料NAn與dmBA表現最佳，最大亮度達1418 cd/m2與780 cd/m2，最大電流效率分別為3.78 cd/A與1.60 cd/A，外部量子效率達2.06%與2.79%。此外，材料BdpA與dmBA製作元件後具有深藍色螢光表現，也同具有穩定的放光波長。其中以TrEL光譜可以發現材料pABIZ具有良好的TTA-UC現象。 於離子辨識實驗部分中，我們發現化合物在不同離子的溶液中，會改變其光物理性質。此系列化合物對於F-與OH-的顏色變化最為快速且明顯，化合物的吸收紅移，使溶液顏色由透明轉到可見光區；螢光強度也會大幅減弱，這些變化此皆能以肉眼辨識。此外，化合物也會在加入H2PO4-與H2P2O72-後隨時間改變常溫螢光光譜曲線的現象，而這些化合物對陰離子的顏色變化顯示了此系列硼氮化合物具有作為多陰離子辨識的應用潛力。 " | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-25T03:04:37Z (GMT). No. of bitstreams: 1 U0001-2207202103102600.pdf: 14189938 bytes, checksum: 80f503f9d237e4a228e7dfbc612ae683 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 目錄 I 化合物結構與編號命名 III 摘要 VI Abstract VII 致謝 IX 圖目錄 X 表目錄 XVII 流程目錄 XIX 第一章 緒論 1 1.1 有機發光二極體之發展歷史 1 1.2 有機分子發光機制 4 1.3 有機發光二極體之工作原理 6 1.4 有機發光二極體各層材料之介紹 10 1.5 離子辨識材料介紹 15 第二章 研究動機 19 2.1 文獻回顧 19 2.1.1 有機硼化學 19 2.1.2 分子間TTA-UC之特性 31 2.2 分子設計 38 2.3 合成策略與方法 42 第三章 結果與討論 50 3.1 熱性質分析 50 3.2 晶體結構分析 53 3.3 光物理性質分析 62 3.4 電化學分析 69 3.5 有機電致發光元件表現 76 3.6 陰離子偵測實驗 84 3.6.1 多重陰離子偵測 84 3.6.2 氟離子滴定實驗 92 3.6.3 陰離子時間追蹤 97 3.7 摩擦變色現象 (Mechanochromic luminescence) 105 第四章 結論 106 第五章 實驗部分 107 5.1 實驗儀器及試劑 107 5.2 合成步驟 109 第六章 參考資料 138 第七章 附錄 147 7.1 化合物之1H與13C核磁共振光譜 147 7.2 化合物TGA與DSC圖 195 7.3 化合物薄膜態之UV-Vis、FL光譜、ACII圖譜與參考物之電化學分析 198 7.4 陰離子時間追蹤詳細數據 201 7.5 化合物X-ray晶體參數表、鍵長與鍵角數據 207 | |
| dc.language.iso | zh-TW | |
| dc.subject | 陰離子偵測 | zh_TW |
| dc.subject | 硼氮吲哚 | zh_TW |
| dc.subject | 有機含硼化合物 | zh_TW |
| dc.subject | 2-苯並二氮雜硼 | zh_TW |
| dc.subject | 蒽 | zh_TW |
| dc.subject | 藍色螢光有機發光二極體 | zh_TW |
| dc.subject | 三重態-三重態湮滅光子上轉換 | zh_TW |
| dc.subject | B-N indoles | en |
| dc.subject | Anion detection | en |
| dc.subject | Anthracene | en |
| dc.subject | TTA-UC | en |
| dc.subject | Blue fluorescent OLED | en |
| dc.subject | 2-benzodiazaborole | en |
| dc.subject | Organoboron | en |
| dc.title | "1,3,2-苯並二氮雜硼引入蒽之合成、性質探討及其在藍色有機發光二極體與陰離子偵測之應用" | zh_TW |
| dc.title | "Synthesis and Characterization of 1,3,2-Benzodiazaboroles Substituted 10-phenylanthracene and Their Applications in Blue Fluorescent Organic Light Emitting Diodes and Anion Detection" | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李君浩(Hsin-Tsai Liu),邱天隆(Chih-Yang Tseng) | |
| dc.subject.keyword | 硼氮吲哚,有機含硼化合物,1,3,2-苯並二氮雜硼,蒽,藍色螢光有機發光二極體,三重態-三重態湮滅光子上轉換,陰離子偵測, | zh_TW |
| dc.subject.keyword | B-N indoles,Organoboron,1,3,2-benzodiazaborole,Blue fluorescent OLED,TTA-UC,Anthracene,Anion detection, | en |
| dc.relation.page | 261 | |
| dc.identifier.doi | 10.6342/NTU202101652 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-10-28 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| dc.date.embargo-lift | 2026-10-25 | - |
| 顯示於系所單位： | 化學系 | |
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