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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉如熹(Ru-Shi Liu) | |
| dc.contributor.author | Hsi-Ping Hsueh | en |
| dc.contributor.author | 薛希平 | zh_TW |
| dc.date.accessioned | 2022-11-24T09:26:01Z | - |
| dc.date.available | 2022-11-24T09:26:01Z | - |
| dc.date.copyright | 2022-02-21 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-01-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81706 | - |
| dc.description.abstract | 隨環保議題之日漸重要，白光發光二極體不僅普及於照明市場，亦逐漸擴展至其他領域，如醫療電子裝置與光醫療等領域。因發光二極體具壽命長、耐衝撞與光譜可調性，故逐漸應用於該領域。而螢光粉作為發光二極體之光轉換材料為提供調控光譜至適合放光波長之關鍵。現今於螢光粉之研究大多著重於氧化物、氮化物與氮氧化物，其中氮磷化物(nitridophosphate)，因其結構多樣性故具獨特之放光性質，並藉熱等靜壓燒結爐(hot isostatic press; HIP)改善以往製備之困難，故氮磷化物為冉冉升起之新螢光粉材料。本研究於高溫高壓下藉化學取代法開發此二氮磷化物系統Ca2−xSrxPN3:Eu2+與Sr3−xBaxP5N10Cl:Eu2+。第一部分為調控氮磷化物Ca2−xSrxPN3:Eu2+之化學組成。本研究發現於紅光與近紅外光之雙重峰之放射光譜，並隨Sr2+摻雜比例提高，於近紅外光區放射譜帶之相對放射強度上升且藍移，然於紅光區則具紅移之現象，故藉結構精修得知其局部配位環境之演變，揭示且詳細解釋摻入Sr2+時紅光與近紅外光之變化。此外，藉氮磷化物Ca2−xSrxPN3:Eu2+之紅光與近紅外光應用於光生物調節之示範。第二部分為探討氮磷化物Sr3−xBaxP5N10Cl:Eu2+化學取代下之獨特發光特性與內部量子效率變化，並發現Sr2+/Ba2+混合化合物比無取代之化合物效率提升達1.7倍，故藉微結構分析與X光近緣吸收光譜探索Sr2+與Ba2+於陽離子取代之協同效應，並藉變溫光譜與衰變時間瞭解其熱特性。本研究於合成與分析氮磷化物螢光粉，為發展發光二極體用螢光材料重要之參考。 | zh_TW |
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| dc.description.tableofcontents | 口試委員會審定書 I 誌謝 II 摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XII 第一章 緒論 1 1.1 光之起源 1 1.2 光 1 1.2.1 發光之簡介 3 1.3 固態照明(solid-state lighting; SSL) 4 1.3.1 發光二極體之發展 4 1.3.2 發光二極體之工作原理 5 1.3.3 白光發光二極體(white light-emitting diode; WLED) 6 1.3.4 發光二極體於光生物調節之應用 7 1.4 螢光粉(phosphor) 8 1.4.1 螢光粉之組成 8 1.5 螢光粉發光機制 12 1.5.1 賈布朗斯基圖(Jabłoński diagram) 12 1.5.2 法蘭克-康頓原理(Franck-Condon principle) 13 1.5.3 黃昆因子(Huang - Rhys factor)與斯托克斯位移(Stokes shift) 14 1.6 主體晶格影響活化劑之因素 15 1.6.1 電子雲散效應(nephelauxetic effect) 16 1.6.2 晶體場理論(crystal field theory) 17 1.6.3 淬滅效應(quenching effect) 18 1.7 氮磷化物(nitridophosphate)螢光粉之歷史 20 1.7.1 氮磷化物之分類 21 1.8 動機與目的 22 1.8.1 Ca2PN3:Eu2+雙重放射之氮磷化物螢光粉 22 1.8.2 Sr3P5N10Cl:Eu2+氮磷化物螢光粉之協同效應 23 第二章 樣品合成與儀器分析原理 25 2.1 化學藥品 25 2.2氮磷化物螢光粉之合成方法 26 2.2.1 熱等靜壓燒結爐(hot isostatic pressing; HIP) 26 2.2.2 Ca1.94−xSrxPN3:0.06Eu2+氮磷化物螢光粉之合成 28 2.2.3 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之合成 28 2.3 儀器分析 29 2.3.1 結構鑑定 29 2.3.1.1 粉末X光繞射(powder X-ray diffractometer; XRD) 30 2.3.1.2 同步輻射X光繞射(synchrotron X-ray diffraction) 32 2.3.1.3結構精修(structure refinement) 33 2.3.1.4 掃描式電子顯微鏡(scanning electron microscope; SEM) 35 2.3.1.5 庫爾特粒徑分析儀(Coulter particle size analyzer) 36 2.3.1.6 X光吸收光譜(X-ray absorption spectroscopy; XAS) 37 2.3.1.6 固態核磁共振(solid-state nuclear magnetic resonance; ss-NMR) 40 2.3.2 發光性質分析 42 2.3.2.1 光激發光譜儀(photoluminescence spectrometer; PL spectrometer) 42 2.3.2.2 絕對量子效率儀(absolute quantum yield spectrometer) 44 2.3.2.3變溫與變壓光激發光譜(temperature-dependent and pressure-dependent photoluminescence spectrometer; TDPL and PDPL) 45 第三章 結果與討論 47 3.1 Ca2PN3:Eu2+雙重放射之氮磷化物螢光粉 47 3.1.1 Ca1.94−xSrxPN3:0.06Eu2+氮磷化物螢光粉之結構分析 48 3.1.2 Ca1.94−xSrxPN3:0.06Eu2+氮磷化物螢光粉之放光特性 54 3.1.3 Ca1.94−xSrxPN3:0.06Eu2+氮磷化物螢光粉之熱特性 56 3.1.4 Ca1.94−xSrxPN3:0.06Eu2+之變壓光譜 62 3.2 Sr3P5N10Cl:Eu2+氮磷化物螢光粉之協同效應 63 3.2.1 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之結構分析 63 3.2.2 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之放光特性 72 3.2.3 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之協同作用 74 3.2.4 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之熱特性 78 3.2.5 Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之變壓光譜 83 3.3 Ca1.94−xSrxPN3:0.06Eu2+與Sr2.91−xBaxP5N10Cl:0.09Eu2+氮磷化物螢光粉之綜合探討 84 第四章 結論 87 參考文獻 89 | |
| dc.language.iso | zh-TW | |
| dc.subject | 氮磷化物 | zh_TW |
| dc.subject | 螢光粉 | zh_TW |
| dc.subject | phosphor | en |
| dc.subject | Nitridophosphate | en |
| dc.title | 以化學取代調控氮磷化物螢光粉之放光特性 | zh_TW |
| dc.title | Control Luminescence on Nitridophosphate Phosphors by Chemical Substitution | en |
| dc.date.schoolyear | 110-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 楊吉水(Jeng-Wei Lin),廖秋峯(Her-Bert Chang),汪建民(Chia-Hui Wang),陳錦明 | |
| dc.subject.keyword | 螢光粉,氮磷化物, | zh_TW |
| dc.subject.keyword | phosphor,Nitridophosphate, | en |
| dc.relation.page | 96 | |
| dc.identifier.doi | 10.6342/NTU202200094 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2022-01-21 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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| U0001-1801202219292800.pdf 未授權公開取用 | 7.23 MB | Adobe PDF |
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