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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 蔣本基(Pen-Chi Chiang) | |
| dc.contributor.author | Chia-Yu Yonny Chang | en |
| dc.contributor.author | 章家語 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:30:24Z | - |
| dc.date.available | 2021-08-24 | |
| dc.date.available | 2022-11-24T03:30:24Z | - |
| dc.date.copyright | 2021-08-24 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-23 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/81097 | - |
| dc.description.abstract | "隨著經濟的快速增長，生產過程中使用了許多不同的化學物質，這導致化學和電子工業產生了大量的揮發性有機化合物（Volatile Organic Compounds, VOCs）。因此，這項研究以親水性高，濃度高的氣相揮發性有機化合物作為本研究的方向，然後使用不同的化學藥品和不同的操作參數去找出理想的條件。期望達到低成本、佔地少，並能高效率去除VOCs，本研究以四種方法去設計，例如：吸收、氧化、先氧化再吸收和先吸收後氧化。發現三甲胺(Trimethylamine, TMA)的去除效率受氣液比的顯著影響。例如，當氣液比低於 20 時，觀察到三甲胺的去除效率為 80-85%。其中，最佳實踐是通過引入二氧化氯作為三甲胺高達99.96%，其中超重力因子為9.56、氣液比為14.29。另外，本研究將會以半導體常使用有機溶劑-異丙醇(Isopropyl alcohol, IPA) 摸擬實場的排放約10000ppm的濃度系統的空氣流量為15 LPM，並透過超重力旋轉填充床進行吸收和氧化.並達到煙道排放標準400ppm以下為目標。並發現異丙醇透過吸收法，該去除效率在80-92%的範圍內。加入氣相氧化劑後，去除效率高達96.52%，可達到400 PPM的排放標準。異丙醇和三甲胺總傳質係數都可以利用無因次分析，建立經驗公式，預估誤差分別約為 ±25% 和 ±12%。最後本研究提出 Pcap 針對能源消耗和去除效率做鏈結，並以其實驗計做出成本分析。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:30:24Z (GMT). No. of bitstreams: 1 U0001-1808202117004400.pdf: 9150528 bytes, checksum: d2b638cb1b871c9cd1b92ad466d81731 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 致謝 III 中文摘要 V Abstract VI List of Content VIII List of Figure XI List of Table XIV Comment for Oral Defense XVI Nomenclature XX Chapter 1 Introduction 1-1 1-1 Background 1-1 1-2 Objective 1-3 Chapter 2 Literature Review 2-1 2-1 Volatile Organic Compounds and Odor 2-1 2-2 Trimethylamine 2-3 2-3 Removal of Trimethylamine – Absorption and Oxidation 2-4 2-3-1 Chlorine Dioxide Oxidation/Absorption 2-5 2-3-2 Ozone Oxidation/Absorption 2-6 2-3-3 Hydrogen Peroxide Oxidation/Absorption 2-8 2-4 Isopropanol 2-9 2-5 Rotating Packed Bed (HiGee) 2-10 Chapter 3 Materials and Methods 3-1 3-1 Research Framework 3-1 3-2 Materials 3-2 3-3 Experiments 3-6 3-3-1 Experimental Design 3-6 3-3-2 TMA Removal Efficiency 3-9 3-4 Analytical Techniques 3-11 3-4-1 Cost Benefit Analysis 3-13 Chapter 4 Results and Discussion 4-1 4-1 Performance Evaluation of TMA Removal 4-1 4-1-1 TMA Removal by Oxidation 4-1 4-1-2 Effects of Operating Parameter for TMA Absorption 4-3 4-1-3 Enhancement of TMA Removal 4-8 4-1-4 Summary 4-10 4-2 Performance Evaluation of IPA Removal 4-10 4-2-1 IPA Removal by Absorption 4-11 4-2-2 IPA Removal by Oxidation and Absorption 4-16 4-2-3 Summary 4-18 4-3 Determination of Overall Mass Transfer Coefficient 4-19 4-3-1 Mass transfer model in the TMA removal process 4-20 4-3-2 Mass transfer model in the IPA removal process 4-25 4-4 Energy Consumption and Cost Analysis 4-28 4-4-1 Energy Consumption for VOCs Removal Process 4-29 4-4-2 Cost Analysis 4-34 4-4-3 Summary 4-41 Chapter 5 Conclusions and Recommendations 5-1 5-1 Conclusions 5-1 5-2 Recommendations 5-2 References R-1 Appendix A-1 | |
| dc.language.iso | en | |
| dc.subject | 二氧化氯 | zh_TW |
| dc.subject | 超重力技術 | zh_TW |
| dc.subject | 異丙醇去除 | zh_TW |
| dc.subject | 三甲胺去除 | zh_TW |
| dc.subject | 臭味控制 | zh_TW |
| dc.subject | Odor control | en |
| dc.subject | Rotating packed bed | en |
| dc.subject | Trimethylamine removal | en |
| dc.subject | Isopropyl alcohol removal | en |
| dc.subject | Chlorine dioxide | en |
| dc.title | 利用氧化及吸收法處理三甲胺和異丙醇結合超重力旋轉床之研究 | zh_TW |
| dc.title | Trimethylamine and Isopropanol Control by Oxidation and Absorption in a Rotating Packed Bed | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 顧洋(Hsin-Tsai Liu),陳奕宏(Chih-Yang Tseng),潘述元,林逸彬 | |
| dc.subject.keyword | 超重力技術,三甲胺去除,異丙醇去除,二氧化氯,臭味控制, | zh_TW |
| dc.subject.keyword | Rotating packed bed,Trimethylamine removal,Isopropyl alcohol removal,Chlorine dioxide,Odor control, | en |
| dc.relation.page | 85 | |
| dc.identifier.doi | 10.6342/NTU202102482 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-08-23 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| Appears in Collections: | 環境工程學研究所 | |
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| U0001-1808202117004400.pdf Access limited in NTU ip range | 8.94 MB | Adobe PDF |
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