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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉貴生(Guey-Sheng Liou) | |
| dc.contributor.author | Min-Hao Pai | en |
| dc.contributor.author | 白旻昊 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:20:41Z | - |
| dc.date.available | 2021-10-04 | |
| dc.date.available | 2022-11-24T03:20:41Z | - |
| dc.date.copyright | 2021-10-04 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-09-26 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80890 | - |
| dc.description.abstract | 本論文分為四大章節，第一章為總體緒論，介紹功能性高分子、電致變色的歷史及發展、含有奈米結構的電致變色材料以及固有微孔高分子的歷史及發展；第二章實驗部分，分別講述兩種新型含有苯荑之電活性三苯胺二胺單體及四種具電致變色性能的聚醯胺的合成，並以正子湮滅壽命光譜儀、氮氣等溫吸脫附線、廣角X射線繞射儀、電化學阻抗譜及循環伏安法等，探討材料中固有孔洞對於電致變色性能的影響；第三章結果討論部分，實驗表明固有孔洞的導入可以有效的提升氧化還原過程電解質中反離子的擴散速率，進而優化電致變色材料的性能；第四章則總結本論文的實驗結果。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:20:41Z (GMT). No. of bitstreams: 1 U0001-2209202119161300.pdf: 11196565 bytes, checksum: 262fecbd21138089c374df32b62b0a4c (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | Table of Contents 致謝 I ABSTRACT II 中文摘要 III CHAPTER 1 1 1.1 High-Performance Polymer 2 1.1.1 Preparation of Aromatic Polyamides 3 1.1.2 Modification of Aromatic Polyamides 6 1.1.3 Applications of Aromatic Polyamides 7 1.2 Electrochromism 9 1.2.1 A Brief History and Development of Electrochromism 9 1.2.2 Important Criteria and Terminology for Electrochromism 10 1.2.3 Common Electrochromic Materials 13 1.2.4 Structure of Electrochromic Devices (ECDs) 29 1.3 Electrochromic Materials with Nanostructures 32 1.3.1 Transition Metal Oxides (TMOs) with Nanostructures 34 1.3.2 Conjugated Polymers with Nanostructures 37 1.4 Polymers of Intrinsic Microporosity (PIMs) 40 1.4.1 The Development of PIMs 41 1.4.2 Designing Concept for PIMs 43 1.4.3 The common structure utilized for PIMs 43 1.5 Research Motivation 53 CHAPTER 2 56 2.1 Materials 57 2.1.1 Commercial chemicals and basic monomers 57 2.1.2 Synthesis of pentiptycene-derived TPA diamine monomers (Provided by Prof. Jye-Shane Yang) 58 2.1.3 Synthesis of Polyamides 62 2.2 Fabrication of Electrochromic Devices (ECDs) 64 2.3 Measurements 64 CHAPTER 3 67 3.1 Basic Characterization 68 3.1.1 Synthesis and Characterization of Monomer 68 3.1.2 Synthesis of Polyamides 83 3.2 Novel Pentiptycene-Incorporated Intrinsic Porous Redox-active Polyamides 86 3.2.1 Relationship between energy and dihedral angle of diamine monomers 86 3.2.2 Basic Properties of Polyamide 87 3.2.3 Characteristic of intrinsic microporosity in polyamides 91 3.2.4 Optical Properties of Polyamide Films 94 3.2.5 Electrochromic Properties of Polyamide Films 97 3.2.6 Electrochromic Properties of ECDs 106 3.3 Tröger’s Base-derived Intrinsic Microporous Polyamide Films 110 3.3.1 Basic Properties of Polyamide 110 3.3.2 Characteristic of intrinsic microporosity in polyamides 112 3.3.3 Optical Properties of Polyamide Films 115 3.3.4 Electrochromic Properties of Polyamide Films 117 3.3.5 Electrochromic Properties of ECDs 122 CHAPTER 4 126 References 129 APPENDIX 145 LIST OF PUBLICATIONS 146 | |
| dc.language.iso | en | |
| dc.subject | 電致變色響應性能 | zh_TW |
| dc.subject | 電致變色聚醯胺膜 | zh_TW |
| dc.subject | 固有微孔洞 | zh_TW |
| dc.subject | 五苯荑 | zh_TW |
| dc.subject | 特羅格爾鹼 | zh_TW |
| dc.subject | pentiptycene | en |
| dc.subject | Tröger’s Base | en |
| dc.subject | electrochromic polyamide film | en |
| dc.subject | intrinsic microporosity | en |
| dc.subject | EC response capability | en |
| dc.title | 藉固有微孔洞聚醯胺提升電致變色應答性能之研究 | zh_TW |
| dc.title | Study of Redox-active Polyamides with Intrinsic Microporosity for Enhancing Electrochromic Response Capability | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 胡蒨傑(Hsin-Tsai Liu),楊吉水(Chih-Yang Tseng),蕭勝輝,龔宇睿 | |
| dc.subject.keyword | 電致變色聚醯胺膜,固有微孔洞,五苯荑,特羅格爾鹼,電致變色響應性能, | zh_TW |
| dc.subject.keyword | electrochromic polyamide film,intrinsic microporosity,pentiptycene,Tröger’s Base,EC response capability, | en |
| dc.relation.page | 147 | |
| dc.identifier.doi | 10.6342/NTU202103294 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-09-27 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| U0001-2209202119161300.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 10.93 MB | Adobe PDF |
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