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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉貴生(Guey-Sheng Liou) | |
| dc.contributor.author | Yun-Chi Wang | en |
| dc.contributor.author | 王韻淇 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:15:37Z | - |
| dc.date.available | 2022-02-21 | |
| dc.date.available | 2022-11-24T03:15:37Z | - |
| dc.date.copyright | 2022-02-21 | |
| dc.date.issued | 2022 | |
| dc.date.submitted | 2022-02-09 | |
| dc.identifier.citation | (1) de Leon, A.; Chen, Q. Y.; Palaganas, N. B.; Palaganas, J. O.; Manapat, J.; Advincula, R. C. High performance polymer nanocomposites for additive manufacturing applications. React. Funct. Polym. 2016, 103, 141-155. (2) Hill, R. Some aspects of polymer constitution and fibre properties. Ind. Chem. 1949, (27), 443-443. (3) Garcia, J. M.; Garcia, F. C.; Serna, F.; de la Pena, J. L. High-performance aromatic polyamides. Prog. Polym. Sci. 2010, 35 (5), 623-686. (4) Krigbaum, W. R.; Kotek, R.; Mihara, Y.; Preston, J. Preparation of polyamides via the phosphorylation reaction. IX. Effect of reaction temperature on molecular weight on poly(p-phenylene terephthalamide). J. Polym. Sci. A. Polym. Chem. 1984, 22 (12), 4045-4047. (5) Iwakura, Y.; Izawa, S. I.; Hayano, F.; Kurita, K. Polyamides containing pendant hydroxyl groups and their derived polyoxazolines. Macromol. Chem. Phys. 1967, 104 (1), 66-76. (6) Platt, J. R. Electrochromism, a possible change of color producible in dyes by an Electric Field. J. Chem. Phys. 1961, 34 (3), 862-863. (7) Deb, S. A novel electrophotographic system. Appl. Opt. 1969, 8 (101), 192-195. (8) Yang, P.; Sun, P.; Mai, W. Electrochromic energy storage devices. Materials today 2016, 19 (7), 394-402. (9) Monk, P. M.; Mortimer, R. J.; Rosseinsky, D. R. Electrochromism: fundamentals and applications; John Wiley Sons, 2008, 9-18. (10) Somani, P. R.; Radhakrishnan, S. Electrochromic materials and devices: present and future. Mater. Chem. Phys. 2003, 77 (1), 117-133. (11) Jelle, B. P. Electrochromic smart windows for dynamic daylight and solar energy control in buildings. Electrochromic Materials and Devices, 2015, 419-502. (12) Weil, M.; Schubert, W.-D. The beautiful colours of tungsten oxides. International Tungsten Industry Association: London UK, 2013, 1-9. (13) Coe, B. J.; Harris, J. A.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Garín, J.; Orduna, J. Three-dimensional nonlinear optical chromophores based on metal-to-ligand charge-transfer from ruthenium (II) or iron (II) centers. J. Am. Chem. Soc. 2005, 127 (38), 13399-13410. (14) Neff, V. D. Electrochemical oxidation and reduction of thin films of Prussian Blue. J. Electrochem. Soc. 1978, 125 (6), 886. (15) Stargardt, J. F.; Hawkridge, F. M. Computer decomposition of the ultraviolet-visible absorption spectrum of the methyl viologen cation radical and its dimer in solution. Anal. Chim. Acta. 1983, 146, 1-8. (16) Rourke, F.; Crayston, J. A. Cyclic voltammetry and morphology of polyaniline-coated electrodes containing [Fe(CN)6]3-/4- ions. J. Chem. Soc. Faraday Trans. 1993, 89 (2), 295-302. (17) Seo, E. T.; Nelson, R. F.; Fritsch, J. M.; Marcoux, L. S.; Leedy, D. W.; Adams, R. N. Anodic oxidation pathways of aromatic amines. Electrochemical and electron paramagnetic resonance studies. J. Am. Chem. Soc. 1966, 88 (15), 3498-3503. (18) Yen, H. J.; Liou, G. S. Recent advances in triphenylamine-based electrochromic derivatives and polymers. Polym. Chem. 2018, 9 (22), 3001-3018. (19) Mortimer, R. J.; Rosseinsky, D. R.; Monk, P. M. Electrochromic materials and devices; John Wiley Sons, 2015, 42-50. (20) Frackowiak, E.; Beguin, F. Carbon materials for the electrochemical storage of energy in capacitors. Carbon 2001, 39 (6), 937-950. (21) Kickelbick, G. Hybrid materials: synthesis, characterization, and applications; John Wiley Sons, 2007, 3-49. (22) Pierre, A. C. Introduction to sol-gel processing; Springer Nature, 2020, 421-455. (23) Ebelmen, I. Untersuchungen über die Verbindungen der Borsäure und Kieselsäure mit Aether. Ann. Chem. Pharm. 1846, 57 (3), 319-355. (24) Danks, A. E.; Hall, S. R.; Schnepp, Z. The evolution of ‘sol–gel’chemistry as a technique for materials synthesis. Mater. Horiz. 2016, 3 (2), 91-112. (25) Tsai, C. L.; Yen, H. J.; Liou, G. S. Highly transparent polyimide hybrids for optoelectronic applications. React. Funct. Polym. 2016, 108, 2-30. (26) Montes, S.; Maleki, H. Aerogels and their applications. Colloidal Metal Oxide Nanoparticles, Elsevier, 2020, 337-399. (27) Guo, Q.; Ghadiri, R.; Weigel, T.; Aumann, A.; Gurevich, E. L.; Esen, C.; Medenbach, O.; Cheng, W.; Chichkov, B.; Ostendorf, A. Comparison of in situ and ex situ methods for synthesis of two-photon polymerization polymer nanocomposites. Polymers 2014, 6 (7), 2037-2050. (28) Tsai, C. L.; Liou, G. S. Highly transparent and flexible polyimide/ZrO2 nanocomposite optical films with a tunable refractive index and Abbe number. Chem. Comm. 2015, 51 (70), 13523-13526. (29) Liou, G. S.; Lin, P. H.; Yen, H. J.; Yu, Y. Y.; Chen, W. C. Flexible nanocrystalline‐titania/polyimide hybrids with high refractive index and excellent thermal dimensional stability. J. Polym. Sci. A Polym. Chem. 2010, 48 (6), 1433-1440. (30) Chiu, Y. W.; Pai, M. H.; Liou, G. S. Facile approach of porous electrochromic polyamide/ZrO2 films for enhancing redox switching behavior. ACS Appl. Mater. Interfaces. 2020, 12 (31), 35273-35281. (31) Chang, C. W.; Liou, G. S.; Hsiao, S. H. Highly stable anodic green electrochromic aromatic polyamides: synthesis and electrochromic properties. J. Mater. Chem. 2007, 17 (10), 1007-1015. (32) Park, K. H.; Kakimoto, M. A.; Imai, Y. Synthesis and properties of new soluble aromatic polybenzoxazoles from 4,4'-diamino-3,3'-dihydroxytriphenylamines and aromatic dicarboxylic acids. J. Polym. Sci. A Polym. Chem. 1998, 36 (12), 1987-1994. (33) Knölker, H.-J. Synthesis of biologically active carbazole alkaloids using selective transition-metal-catalyzed coupling reactions. Chem. Lett. 2009, 38 (1), 8-13. (34) Al Soom, N.; Thiemann, T. Hydrogenation of alkenes with NaBH4, CH3CO2H, Pd/C in the presence of O-and N-benzyl functions. Int. J. Org. Chem. 2016, 6 (1), 1-11. (35) Hsiao, S. H.; Wang, H. M.; Liao, S. H. Redox-stable and visible/near-infrared electrochromic aramids with main-chain triphenylamine and pendent 3,6-di-tert-butylcarbazole units. Polym. Chem. 2014, 5 (7), 2473-2483. (36) Ambrose, J. F.; Carpenter, L. L.; Nelson, R. F. Electrochemical and spectroscopic properties of cation radicals: III. Reaction pathways of carbazolium radical ions. J. Electrochem. Soc. 1975, 122 (7), 876. (37) Hsiao, S. H.; Wang, H. M.; Lin, J. W.; Guo, W. J.; Kung, Y. R.; Leu, C. M.; Lee, T. M. Synthesis and electrochromic properties of polyamides having pendent carbazole groups. Mater. Chem. Phys. 2013, 141 (2-3), 665-673. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80761 | - |
| dc.description.abstract | 本研究共分為四章。本論文分成四個章節：第一章為緒論，講述功能性高分子、電致變色的歷史與發展、電致變色材料中的奈米結構以及有機−無機複合材料的介紹；第二章實為實驗部分，講述新型含羥基芳香胺的合成，及三種聚醯胺膜及其與二氧化鋯形成混成薄膜的製備，研究其電致變色行為；第三章為實驗結果之探討，實驗表明帶有羥基的聚醯胺與二氧化鋯形成之混成薄膜可以在氧化還原過程中輔助電荷轉移，進一步改善電致變色材料的性能；第四章則為本論文的總結。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:15:37Z (GMT). No. of bitstreams: 1 U0001-0702202213250500.pdf: 6166229 bytes, checksum: 467e9b467611347656c3700fe7f11869 (MD5) Previous issue date: 2022 | en |
| dc.description.tableofcontents | 致謝 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ i ABSTRACT ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ ii 中文摘要 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ iii TABLE OF CONTENTS ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏiv LIST OF FIGURES ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ viii LIST OF SCHEMES ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ x LIST OF TABLESꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ xi CHAPTER 1 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 1 1.1 High-Performance Polymers 2 1.1.1 Preparation of Aromatic Polyamides 3 1.1.2 Functional Polyaimdes 5 1.2 Electrochromism 7 1.2.1 History And Development of Electrochromism 7 1.2.2 Important Parameters of EC 8 1.2.3 Electrochromic Materials 11 1.2.4 Electrochromic Devices (ECD) 21 1.3 Electrochromism With Nanostructures 24 1.3.1 Transition Metal Oxides (TMOs)………………………………24 1.3.2 Nanocomposites 25 1.3.3 Functional Organic-Inorganic Nanohybrids 26 1.3.4 Polymer Hybrids with Zirconia (ZrO2) 30 1.4 Research Motivation 32 CHAPTER 2 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 33 2.1 Materials 34 2.2 Synthesis of Monomer 35 2.3 Synthesis of Polyamides 37 2.4 Fabrication of Electrochromic Devices (ECDs) 41 2.5 Measurements 41 CHAPTER 3 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 43 3.1 Monomer Synthesis and Characterization 44 3.2 Polymer Synthesis and Characterization 54 3.3 Fundamental Properties of Polyamide Films 56 3.4 Electrochromic Properties of The Polymer 62 3.5 Electrochromic Properties of ECDs 75 CHAPTER 4 ꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 81 Conclusion ………………………………………………………………82 REFERENCEꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 83 APPENDIXꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏꞏ 87 | |
| dc.language.iso | en | |
| dc.subject | 電致變色裝置 | zh_TW |
| dc.subject | 電致變色聚醯胺膜 | zh_TW |
| dc.subject | 含羥基芳香胺 | zh_TW |
| dc.subject | 二氧化鋯混成材料 | zh_TW |
| dc.subject | 電致變色響應性能 | zh_TW |
| dc.subject | electrochromic polyamide film | en |
| dc.subject | hydroxy-containing arylamine | en |
| dc.subject | ZrO2 hybrid | en |
| dc.subject | EC response capability | en |
| dc.subject | ECD | en |
| dc.title | 新型含羥基芳香胺族高分子之合成及其電致變色性質研究 | zh_TW |
| dc.title | Synthesis and Electrochromic Properties of Novel Hydroxy-Containing Arylamine-Based Polymers | en |
| dc.date.schoolyear | 110-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 蕭勝輝(Hsueh-Fen Juan),龔宇睿(Huai-Kuang Tsai),張嘉文 | |
| dc.subject.keyword | 電致變色聚醯胺膜,含羥基芳香胺,二氧化鋯混成材料,電致變色響應性能,電致變色裝置, | zh_TW |
| dc.subject.keyword | electrochromic polyamide film,hydroxy-containing arylamine,ZrO2 hybrid,EC response capability,ECD, | en |
| dc.relation.page | 87 | |
| dc.identifier.doi | 10.6342/NTU202200326 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2022-02-10 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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