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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80369完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 薛承輝(Chun-Hway Hsueh) | |
| dc.contributor.author | Pin-Jie Chen | en |
| dc.contributor.author | 陳品潔 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:05:17Z | - |
| dc.date.available | 2021-08-06 | |
| dc.date.available | 2022-11-24T03:05:17Z | - |
| dc.date.copyright | 2021-08-06 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-28 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80369 | - |
| dc.description.abstract | 本研究的目的是製造出不同結晶度、具週期性奈米結構的金基金屬玻璃薄膜(TFMG)，並應用於表面增強拉曼散射(SERS)。為了實現這一目標，我們先採用磁控共濺鍍的方式製備出完全非晶的金-銅-矽金屬玻璃薄膜，並在薄膜之過冷液相區中採用熱壓印法將商用陽極氧化鋁模板壓印在鍍製的薄膜上，以形成週期性的奈米結構於薄膜上。最後再對壓印後的金-銅-矽金屬玻璃薄膜進行不同溫度的熱處理來達到不同結晶度。薄膜之表面形貌、結晶性、介電性質、光學性質以及表面增強拉曼散射效應將會分別由掃描式電子顯微鏡、X射線繞射儀(以及穿透式電子顯微鏡)、橢圓偏光儀、紫外光–可見光–近紅外光分光光譜儀以、及拉曼光譜儀來進行量測。同時也進行時域有限差分法模擬壓印薄膜之反射率，並與實驗結果進行比較。本研究發現熱處理非晶薄膜將會造成薄膜之結晶化，並由於晶界處的散射降低了拉曼強度。然而，在較高的熱處理溫度下，薄膜會開始晶粒成長並減少晶界面積，進而造成拉曼強度的增加。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:05:17Z (GMT). No. of bitstreams: 1 U0001-1306202115150300.pdf: 2792273 bytes, checksum: cfde86001401ec5bebc07bd4a7b0a798 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員會審定書 # 誌謝 i 中文摘要 iii ABSTRACT iv CONTENTS v LIST OF FIGURES vii Chapter 1 Motivation 1 Chapter 2 Literature Review 2 2.1 Surface Plasmon Resonance (SPR) 2 2.1.1 Localized Surface Plasmon Resonance (LSPR) 4 2.1.2 Surface-Enhanced Raman Scattering (SERS) 7 2.2 Metallic Glasses (MGs) 10 2.2.1 Criteria of Metallic Glass Formation 13 2.2.2 Critical Cooling Rate of Metallic Glass 15 2.2.3 Thermoplastic Behavior of Metallic Glass 17 2.2.4 Thin Film Metallic Glasses (TFMGs) 19 Chapter 3 Introduction 20 3.1 Experimental Details 24 3.1.1 Synthesis of Au-Cu-Si TFMGs 24 3.1.2 Thermal Imprint and Heat Treatment 25 3.1.3 Characterization 26 Chapter 4 Results and Discussion 28 4.1 Sputtering and Nanoimprint 28 4.2 Structure 30 4.3 Dielectric and Optical Properties 35 4.4 Simulations 39 4.5 Raman Spectra 41 4.6 Conclusions 45 References 46 Appendix 61 | |
| dc.language.iso | en | |
| dc.subject | 表面增強拉曼散射 | zh_TW |
| dc.subject | 金属玻璃 | zh_TW |
| dc.subject | 薄膜 | zh_TW |
| dc.subject | 熱壓印 | zh_TW |
| dc.subject | 結晶度 | zh_TW |
| dc.subject | crystallinity | en |
| dc.subject | thin film | en |
| dc.subject | metallic glass | en |
| dc.subject | SERS | en |
| dc.subject | thermal imprint | en |
| dc.title | 不同結晶度之可壓印金基金屬玻璃薄膜對表面增強拉曼散射之效應 | zh_TW |
| dc.title | Imprintable Au-based Thin-Film Metallic Glasses with Different Crystallinities for Surface-Enhanced Raman Scattering | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李佳翰(Hsin-Tsai Liu),李志偉(Chih-Yang Tseng) | |
| dc.subject.keyword | 金属玻璃,薄膜,熱壓印,結晶度,表面增強拉曼散射, | zh_TW |
| dc.subject.keyword | metallic glass,thin film,thermal imprint,crystallinity,SERS, | en |
| dc.relation.page | 70 | |
| dc.identifier.doi | 10.6342/NTU202101005 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-07-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| U0001-1306202115150300.pdf 授權僅限NTU校內IP使用（校園外請利用VPN校外連線服務） | 2.73 MB | Adobe PDF |
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