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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80346完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 韋文誠(Wen-Cheng Wei) | |
| dc.contributor.author | Meng-Ji Wu | en |
| dc.contributor.author | 吳孟輯 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:04:53Z | - |
| dc.date.available | 2022-06-20 | |
| dc.date.available | 2022-11-24T03:04:53Z | - |
| dc.date.copyright | 2021-08-06 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-06-21 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80346 | - |
| dc.description.abstract | 本研究包括兩個階段,一是在改進前李廷恩之碩士論文(7/2019)[1]提出含廢玻璃之澆注型複材結構件配方(T2-2)之強度,此配方目標為應用於中溫(650-800℃)固態燃料電池之結構件。研究中,選用與T2-2相同之原料系統,包含棕色廢棄玻璃顆粒、廢棄之封裝玻璃(G11A5)粉末,廢棄之碳化矽磨料及波特蘭Ⅰ型水泥作為原料。本研究為尋找更佳的原料配比,優化結構件之抗折強度。先以田口法(Taguchi method)作為實驗規劃之方法,透過L9直交表,選取四種控制因素,每個因素具有三個水準值,以優化其抗折強度為目標,在完成L9表設計之實驗後,透過信噪比分析(S/N ratio)分析實驗數據,確認四種控制因素對抗折強度之影響程度,並找出能改進強度的水準值。經過田口法之優化後,經800℃/1h燒結後樣品之抗折強度為2.43 MPa (T2-2為0.54 MPa),壓縮強度為3.22 MPa,雖有改善但不盡理想,觀察其微結構發現在800℃煅燒後有因燒結收縮的大裂縫而造成強度損失,在1000℃強度損失的原因則是多了粗顆粒玻璃,在高溫時會形成發泡(bubbling)結構。此外,若低熔點之G11A5玻璃含量過多會使樣品在1000℃熔化崩塌。為了改善前述缺點,在第二階段的優化實驗中,將澆注材分為骨材和漿料(細粉+水)兩部分討論,骨材選用廢棄之碳化矽磨料及有較高熔點之低鹼玻璃(GC),透過顆粒堆積理論決定澆注材中骨材的比例,以期在和漿料混合後有最好的流動性及最高800℃燒結後之強度。透過漿料黏塑性測試及乾燥並煅燒後之微結構決定漿料的成分,然後將已確定成分之骨材及漿料以不同比例混合、成型、煅燒後進行強度測試。將含75vol%骨材-25 vol%細粉之配方命名為N75,以此類推N65和N55。這三配方之800℃煅燒後抗折強度都在7~9 MPa之間,1000℃煅燒後抗折強度都在11~13 MPa之間,相較原T2-2配方及經過田口法優化後之T2-2配方皆有大幅提升。N系列之配方的抗壓強度均高於10 MPa,已達SOFC結構件所需的工程強度。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:04:53Z (GMT). No. of bitstreams: 1 U0001-2006202104345300.pdf: 12826563 bytes, checksum: acfcb5a7e39ffb1aaa708c2e347d9786 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員審定書 I 致謝 II 摘要 III Abstract IV Contents VI List of Figures X List of Tables XVI Chapter 1 Introduction 1 Research Goals 3 Chapter 2 Literature Review 7 2.1 Rheology of Fluid 7 2.2 Cementeous Composites 11 2.2.1 Rule of mixture 11 2.2.2 Particles Packing Theory 19 2.3 Cementeous Castables using Waste Materials 30 2.4 Waste Glass Addition in Concrete 34 Chapter 3 Experimental Procedure 46 3.1 Experimental materials 46 3.2 Preparation of Bulky Sample 47 3.2.1 Vibrating 47 3.2.2 Moisture Curing 47 3.2.3 Sintering 47 3.3 Experimental Design by Taguchi Method 48 3.3.1 Taguchi Method 48 3.4 Properties Characterization 51 3.4.1 Bending Strength Test 51 3.4.2 Thermal Conductivity Test 52 3.4.3 Compression Strength Test 52 3.4.4 Porosity Measurement 53 3.4.5 Microstructure Observation 53 3.4.6 Tapping Density Measurement 54 3.4.7 Rheology Test 54 Chapter 4 Results and Discussion 57 4.1 Strength Improvement by Taguchi Method 57 4.1.1 Confirmation of Processing Steps 57 4.1.2 Taguchi Experimental Design 58 4.1.3 Main Effect Analysis of Bending Strength 59 4.1.4 Confirmation Experiment of Bending Strength 60 4.1.5 Main Effect Analysis of Compressive Strength 60 4.1.6 Confirmation Test of Compression Strength 61 4.1.7 Overall Discussion of Taguchi Experiment Results 61 4.2 Microstructural Observation of Defects 70 4.2.1 Macro-Structure and -Defects 70 4.2.2 Microstructure and Microdefects 72 4.2.3 Summary 75 4.3 Proportioning Design of Castable Formulations 89 4.3.1 Preliminary Experiment 89 4.3.2 Proportioning Design of Aggregate 95 4.3.3 Proportioning Design of Flowable Slurry 95 4.3.4 Strength Tests of Castables 97 4.3.5 Observation of Microstructure 98 Chapter 5 Conclusions 126 References 129 A ppendix Properties of Waste Glass 135 A.1 Introduction 135 A.2 Experimental Procedure 135 A.2.1 Chemical compositions analysis 135 A.2.2 Thermal Analysis 136 A.2.3 Wetting angle test 136 A.2.4 CTE analysis 137 A.2.5 X-ray diffraction analysis 137 A.2.6 Fluidized bed device and testing 137 A.3 Test Results 138 References 152 | |
| dc.language.iso | en | |
| dc.subject | 廢棄玻璃 | zh_TW |
| dc.subject | 強度 | zh_TW |
| dc.subject | 田口法 | zh_TW |
| dc.subject | 快速成形 | zh_TW |
| dc.subject | 中溫固態燃料電池 | zh_TW |
| dc.subject | rapid prototyping | en |
| dc.subject | strength | en |
| dc.subject | IT SOFC | en |
| dc.subject | waste glass | en |
| dc.subject | Taguchi method | en |
| dc.title | 含廢玻璃之澆注型複材之強度改善研究 | zh_TW |
| dc.title | Study on Strength Improvement of Castable Composites Containing Waste Glass | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 薛承輝(Hsin-Tsai Liu),林永仁(Chih-Yang Tseng) | |
| dc.subject.keyword | 田口法,廢棄玻璃,快速成形,中溫固態燃料電池,強度, | zh_TW |
| dc.subject.keyword | Taguchi method,waste glass,rapid prototyping,IT SOFC,strength, | en |
| dc.relation.page | 152 | |
| dc.identifier.doi | 10.6342/NTU202101062 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-06-22 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位: | 材料科學與工程學系 | |
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